(a) Interpretation: The alkyl halide and nucleophile needed to prepare given compound is to be predicted. Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron rich chemical species that contains negative charge or lone pair of electrons are known as a nucleophile. In a nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking the electron deficient carbon atom.

Question

. Each of the following compounds can be prepared by a mixed aldol condensation reaction. Give the Cructures of the aldehyde and/or ketone precursors for each aldol product and formulate the reaction. 0 CH=CHCCH 3. Ph 1

Answer 1

Question

Chapter 7, Problem 7.38P

Interpretation Introduction

(a)

Interpretation: The alkyl halide and nucleophile needed to prepare given compound is to be predicted.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron rich chemical species that contains negative charge or lone pair of electrons are known as a nucleophile. In a nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking the electron deficient carbon atom.

Interpretation Introduction

(b)

Interpretation: The alkyl halide and nucleophile needed to prepare given compound is to be predicted.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron rich chemical species that contains negative charge or lone pair of electrons are known as a nucleophile. In a nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking the electron deficient carbon atom.

Interpretation Introduction

(c)

Interpretation: The alkyl halide and nucleophile needed to prepare given compound is to be predicted.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron rich chemical species that contains negative charge or lone pair of electrons are known as a nucleophile. In a nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking the electron deficient carbon atom.

Interpretation Introduction

(d)

Interpretation: The alkyl halide and nucleophile needed to prepare given compound is to be predicted.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron rich chemical species that contains negative charge or lone pair of electrons are known as a nucleophile. In a nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking the electron deficient carbon atom.

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. Each of the following compounds can be prepared by a mixed aldol condensation reaction. Give the Cructures of the aldehyde and/or ketone precursors for each aldol product and formulate the reaction. 0 CH=CHCCH 3. Ph 1

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Answer 2

Question

Chapter 7, Problem 7.38P

Interpretation Introduction

(a)

Interpretation: The alkyl halide and nucleophile needed to prepare given compound is to be predicted.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron rich chemical species that contains negative charge or lone pair of electrons are known as a nucleophile. In a nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking the electron deficient carbon atom.

Interpretation Introduction

(b)

Interpretation: The alkyl halide and nucleophile needed to prepare given compound is to be predicted.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron rich chemical species that contains negative charge or lone pair of electrons are known as a nucleophile. In a nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking the electron deficient carbon atom.

Interpretation Introduction

(c)

Interpretation: The alkyl halide and nucleophile needed to prepare given compound is to be predicted.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron rich chemical species that contains negative charge or lone pair of electrons are known as a nucleophile. In a nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking the electron deficient carbon atom.

Interpretation Introduction

(d)

Interpretation: The alkyl halide and nucleophile needed to prepare given compound is to be predicted.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron rich chemical species that contains negative charge or lone pair of electrons are known as a nucleophile. In a nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking the electron deficient carbon atom.

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Answer 3

Question

Chapter 7, Problem 7.38P

Interpretation Introduction

(a)

Interpretation: The alkyl halide and nucleophile needed to prepare given compound is to be predicted.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron rich chemical species that contains negative charge or lone pair of electrons are known as a nucleophile. In a nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking the electron deficient carbon atom.

Interpretation Introduction

(b)

Interpretation: The alkyl halide and nucleophile needed to prepare given compound is to be predicted.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron rich chemical species that contains negative charge or lone pair of electrons are known as a nucleophile. In a nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking the electron deficient carbon atom.

Interpretation Introduction

(c)

Interpretation: The alkyl halide and nucleophile needed to prepare given compound is to be predicted.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron rich chemical species that contains negative charge or lone pair of electrons are known as a nucleophile. In a nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking the electron deficient carbon atom.

Interpretation Introduction

(d)

Interpretation: The alkyl halide and nucleophile needed to prepare given compound is to be predicted.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron rich chemical species that contains negative charge or lone pair of electrons are known as a nucleophile. In a nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking the electron deficient carbon atom.

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Answer 4

Question

Chapter 7, Problem 7.38P

Interpretation Introduction

(a)

Interpretation: The alkyl halide and nucleophile needed to prepare given compound is to be predicted.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron rich chemical species that contains negative charge or lone pair of electrons are known as a nucleophile. In a nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking the electron deficient carbon atom.

Interpretation Introduction

(b)

Interpretation: The alkyl halide and nucleophile needed to prepare given compound is to be predicted.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron rich chemical species that contains negative charge or lone pair of electrons are known as a nucleophile. In a nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking the electron deficient carbon atom.

Interpretation Introduction

(c)

Interpretation: The alkyl halide and nucleophile needed to prepare given compound is to be predicted.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron rich chemical species that contains negative charge or lone pair of electrons are known as a nucleophile. In a nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking the electron deficient carbon atom.

Interpretation Introduction

(d)

Interpretation: The alkyl halide and nucleophile needed to prepare given compound is to be predicted.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron rich chemical species that contains negative charge or lone pair of electrons are known as a nucleophile. In a nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking the electron deficient carbon atom.

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Answer 5

Chapter 7, Problem 7.38P

Interpretation Introduction

(a)

Interpretation: The alkyl halide and nucleophile needed to prepare given compound is to be predicted.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron rich chemical species that contains negative charge or lone pair of electrons are known as a nucleophile. In a nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking the electron deficient carbon atom.

Interpretation Introduction

(b)

Interpretation: The alkyl halide and nucleophile needed to prepare given compound is to be predicted.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron rich chemical species that contains negative charge or lone pair of electrons are known as a nucleophile. In a nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking the electron deficient carbon atom.

Interpretation Introduction

(c)

Interpretation: The alkyl halide and nucleophile needed to prepare given compound is to be predicted.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron rich chemical species that contains negative charge or lone pair of electrons are known as a nucleophile. In a nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking the electron deficient carbon atom.

Interpretation Introduction

(d)

Interpretation: The alkyl halide and nucleophile needed to prepare given compound is to be predicted.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron rich chemical species that contains negative charge or lone pair of electrons are known as a nucleophile. In a nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking the electron deficient carbon atom.

Answer 6

Chapter 7, Problem 7.38P

Interpretation Introduction

(a)

Interpretation: The alkyl halide and nucleophile needed to prepare given compound is to be predicted.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron rich chemical species that contains negative charge or lone pair of electrons are known as a nucleophile. In a nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking the electron deficient carbon atom.

Answer 7

Chapter 7, Problem 7.38P

Interpretation Introduction

(a)

Interpretation: The alkyl halide and nucleophile needed to prepare given compound is to be predicted.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron rich chemical species that contains negative charge or lone pair of electrons are known as a nucleophile. In a nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking the electron deficient carbon atom.

Answer 8

Interpretation Introduction

(b)

Interpretation: The alkyl halide and nucleophile needed to prepare given compound is to be predicted.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron rich chemical species that contains negative charge or lone pair of electrons are known as a nucleophile. In a nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking the electron deficient carbon atom.

Answer 9

Interpretation Introduction

(b)

Interpretation: The alkyl halide and nucleophile needed to prepare given compound is to be predicted.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron rich chemical species that contains negative charge or lone pair of electrons are known as a nucleophile. In a nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking the electron deficient carbon atom.

Answer 10

Interpretation Introduction

(c)

Interpretation: The alkyl halide and nucleophile needed to prepare given compound is to be predicted.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron rich chemical species that contains negative charge or lone pair of electrons are known as a nucleophile. In a nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking the electron deficient carbon atom.

Answer 11

Interpretation Introduction

(c)

Interpretation: The alkyl halide and nucleophile needed to prepare given compound is to be predicted.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron rich chemical species that contains negative charge or lone pair of electrons are known as a nucleophile. In a nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking the electron deficient carbon atom.

Answer 12

Interpretation Introduction

(d)

Interpretation: The alkyl halide and nucleophile needed to prepare given compound is to be predicted.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron rich chemical species that contains negative charge or lone pair of electrons are known as a nucleophile. In a nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking the electron deficient carbon atom.

Answer 13

Interpretation Introduction

(d)

Interpretation: The alkyl halide and nucleophile needed to prepare given compound is to be predicted.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron rich chemical species that contains negative charge or lone pair of electrons are known as a nucleophile. In a nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking the electron deficient carbon atom.

Answer 14

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Answer 15

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Answer 25

Ch. 7 - Problem 7.1 Telfairine, a naturally occurring...Ch. 7 - Give the IUPAC name for each compound. a. b. c. d.Ch. 7 - Prob. 7.3P Ch. 7 - An sp3 hybridized CCl bond is more polar than an...Ch. 7 - Prob. 7.5P Ch. 7 - Problem 7.6 Identify the nucleophile and leaving...Ch. 7 - Prob. 7.7P Ch. 7 - Prob. 7.8P Ch. 7 - What neutral nucleophile is needed to convert...Ch. 7 - Prob. 7.10P

Solution Summary: The author explains that the alkyl halide and nucleophile needed to prepare given compound is butyl bromide and cyanide ion.

Chapter 7 Solutions