(a) Interpretation: The alkyl halide , from the given pair, that reacts faster in an S N 1 reaction is to be identified. Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron rich chemical species that contains negative charge or lone pair of electrons are known as a nucleophile. In unimolecular nucleophilic substitution reaction, formation of carbocation takes place by removal of halide from the compound. The increasing order of stability of carbocation is 1 ° < 2 ° < 3 ° .

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Answer 1

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Chapter 7, Problem 7.28P

Interpretation Introduction

(a)

Interpretation: The alkyl halide, from the given pair, that reacts faster in an SN1 reaction is to be identified.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron rich chemical species that contains negative charge or lone pair of electrons are known as a nucleophile. In unimolecular nucleophilic substitution reaction, formation of carbocation takes place by removal of halide from the compound. The increasing order of stability of carbocation is 1°<2°<3°.

Interpretation Introduction

(b)

Interpretation: The alkyl halide, from the given pair, that reacts faster in an SN1 reaction is to be identified.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron rich chemical species that contains negative charge or lone pair of electrons are known as a nucleophile. In unimolecular nucleophilic substitution reaction, formation of carbocation takes place by removal of halide from the compound. The increasing order of stability of carbocation is 1°<2°<3°.

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MISSED THIS? Read Section 19.9 (Pages 878-881); Watch IWE 19.10 Consider the following reaction: CH3OH(g) CO(g) + 2H2(g) (Note that AG,CH3OH(g) = -162.3 kJ/mol and AG,co(g)=-137.2 kJ/mol.) Part A Calculate AG for this reaction at 25 °C under the following conditions: PCH₂OH Pco PH2 0.815 atm = 0.140 atm 0.170 atm Express your answer in kilojoules to three significant figures. Ο ΑΣΦ AG = -150 Submit Previous Answers Request Answer □? kJ × Incorrect; Try Again; 2 attempts remaining Calculate the free energy change under nonstandard conditions (AGrxn) by using the following relationship: AGrxn = AGrxn + RTInQ, AGxn+RTInQ, where AGxn is the standard free energy change, R is the ideal gas constant, T is the temperature in kelvins, a is the reaction quotient. Provide Feedback Next >

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Answer 2

Question

Chapter 7, Problem 7.28P

Interpretation Introduction

(a)

Interpretation: The alkyl halide, from the given pair, that reacts faster in an SN1 reaction is to be identified.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron rich chemical species that contains negative charge or lone pair of electrons are known as a nucleophile. In unimolecular nucleophilic substitution reaction, formation of carbocation takes place by removal of halide from the compound. The increasing order of stability of carbocation is 1°<2°<3°.

Interpretation Introduction

(b)

Interpretation: The alkyl halide, from the given pair, that reacts faster in an SN1 reaction is to be identified.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron rich chemical species that contains negative charge or lone pair of electrons are known as a nucleophile. In unimolecular nucleophilic substitution reaction, formation of carbocation takes place by removal of halide from the compound. The increasing order of stability of carbocation is 1°<2°<3°.

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Answer 3

Question

Chapter 7, Problem 7.28P

Interpretation Introduction

(a)

Interpretation: The alkyl halide, from the given pair, that reacts faster in an SN1 reaction is to be identified.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron rich chemical species that contains negative charge or lone pair of electrons are known as a nucleophile. In unimolecular nucleophilic substitution reaction, formation of carbocation takes place by removal of halide from the compound. The increasing order of stability of carbocation is 1°<2°<3°.

Interpretation Introduction

(b)

Interpretation: The alkyl halide, from the given pair, that reacts faster in an SN1 reaction is to be identified.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron rich chemical species that contains negative charge or lone pair of electrons are known as a nucleophile. In unimolecular nucleophilic substitution reaction, formation of carbocation takes place by removal of halide from the compound. The increasing order of stability of carbocation is 1°<2°<3°.

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Answer 4

Question

Chapter 7, Problem 7.28P

Interpretation Introduction

(a)

Interpretation: The alkyl halide, from the given pair, that reacts faster in an SN1 reaction is to be identified.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron rich chemical species that contains negative charge or lone pair of electrons are known as a nucleophile. In unimolecular nucleophilic substitution reaction, formation of carbocation takes place by removal of halide from the compound. The increasing order of stability of carbocation is 1°<2°<3°.

Interpretation Introduction

(b)

Interpretation: The alkyl halide, from the given pair, that reacts faster in an SN1 reaction is to be identified.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron rich chemical species that contains negative charge or lone pair of electrons are known as a nucleophile. In unimolecular nucleophilic substitution reaction, formation of carbocation takes place by removal of halide from the compound. The increasing order of stability of carbocation is 1°<2°<3°.

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Answer 5

Chapter 7, Problem 7.28P

Interpretation Introduction

(a)

Interpretation: The alkyl halide, from the given pair, that reacts faster in an SN1 reaction is to be identified.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron rich chemical species that contains negative charge or lone pair of electrons are known as a nucleophile. In unimolecular nucleophilic substitution reaction, formation of carbocation takes place by removal of halide from the compound. The increasing order of stability of carbocation is 1°<2°<3°.

Interpretation Introduction

(b)

Interpretation: The alkyl halide, from the given pair, that reacts faster in an SN1 reaction is to be identified.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron rich chemical species that contains negative charge or lone pair of electrons are known as a nucleophile. In unimolecular nucleophilic substitution reaction, formation of carbocation takes place by removal of halide from the compound. The increasing order of stability of carbocation is 1°<2°<3°.

Answer 6

Chapter 7, Problem 7.28P

Interpretation Introduction

(a)

Interpretation: The alkyl halide, from the given pair, that reacts faster in an SN1 reaction is to be identified.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron rich chemical species that contains negative charge or lone pair of electrons are known as a nucleophile. In unimolecular nucleophilic substitution reaction, formation of carbocation takes place by removal of halide from the compound. The increasing order of stability of carbocation is 1°<2°<3°.

Answer 7

Chapter 7, Problem 7.28P

Interpretation Introduction

(a)

Interpretation: The alkyl halide, from the given pair, that reacts faster in an SN1 reaction is to be identified.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron rich chemical species that contains negative charge or lone pair of electrons are known as a nucleophile. In unimolecular nucleophilic substitution reaction, formation of carbocation takes place by removal of halide from the compound. The increasing order of stability of carbocation is 1°<2°<3°.

Answer 8

Interpretation Introduction

(b)

Interpretation: The alkyl halide, from the given pair, that reacts faster in an SN1 reaction is to be identified.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron rich chemical species that contains negative charge or lone pair of electrons are known as a nucleophile. In unimolecular nucleophilic substitution reaction, formation of carbocation takes place by removal of halide from the compound. The increasing order of stability of carbocation is 1°<2°<3°.

Answer 9

Interpretation Introduction

(b)

Interpretation: The alkyl halide, from the given pair, that reacts faster in an SN1 reaction is to be identified.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron rich chemical species that contains negative charge or lone pair of electrons are known as a nucleophile. In unimolecular nucleophilic substitution reaction, formation of carbocation takes place by removal of halide from the compound. The increasing order of stability of carbocation is 1°<2°<3°.

Answer 10

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Answer 13

Ch. 7 - Problem 7.1 Telfairine, a naturally occurring...Ch. 7 - Give the IUPAC name for each compound. a. b. c. d.Ch. 7 - Prob. 7.3P Ch. 7 - An sp3 hybridized CCl bond is more polar than an...Ch. 7 - Prob. 7.5P Ch. 7 - Problem 7.6 Identify the nucleophile and leaving...Ch. 7 - Prob. 7.7P Ch. 7 - Prob. 7.8P Ch. 7 - What neutral nucleophile is needed to convert...Ch. 7 - Prob. 7.10P

Solution Summary: The author explains that in unimolecular nucleophilic substitution reaction, formation of carbocation takes place by removal of halide from the compound.

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