Biology (MindTap Course List)
10th Edition
ISBN: 9781285423586
Author: Eldra Solomon, Charles Martin, Diana W. Martin, Linda R. Berg
Publisher: Cengage Learning
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Chapter 7, Problem 5TYU
Summary Introduction
Introduction: Under the conditions of a biochemical reaction, free energy (G) is defined as the amount of energy available to perform work. The spontaneity of any reaction depends upon the value of change in free energy.
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A spontaneous reaction is one in which the change in free energy (ΔG) has a _______ value. (a) positive (b) negative (c) positive or negative (d) none of the preceding (ΔG has no measurable value)
Which of the following statements is true? (a) The largerthe Q, the larger the ΔG°. (b) If Q = 0, the system is at equilibrium.(c) If a reaction is spontaneous under standardconditions, it is spontaneous under all conditions. (d) Thefree-energy change for a reaction is independent of temperature.(e) If Q > 1, ΔG > ΔG°.
Label the following statements true or false: (c) A nonspontaneous reaction will proceed spontaneously in the reverse direction. (d) A spontaneous process can occur with a large decrease in entropy.
Chapter 7 Solutions
Biology (MindTap Course List)
Ch. 7.1 - Define energy, emphasizing how it is related to...Ch. 7.1 - Use examples to contrast potential energy and...Ch. 7.1 - Prob. 1CCh. 7.2 - Prob. 3LOCh. 7.2 - Prob. 1CCh. 7.2 - Life is sometimes described as a constant struggle...Ch. 7.3 - Prob. 4LOCh. 7.3 - Prob. 5LOCh. 7.3 - Prob. 6LOCh. 7.3 - Prob. 1C
Ch. 7.3 - Prob. 2CCh. 7.4 - Explain how the chemical structure of ATP allows...Ch. 7.4 - Prob. 1CCh. 7.4 - Prob. 2CCh. 7.5 - Relate the transfer of electrons (or hydrogen...Ch. 7.5 - PREDICT Which has the most energy, the oxidized...Ch. 7.6 - Explain how an enzyme lowers the required energy...Ch. 7.6 - Describe specific ways enzymes are regulated.Ch. 7.6 - Prob. 1CCh. 7.6 - How does the function of the active site of an...Ch. 7.6 - How are temperature and pH optima of an enzyme...Ch. 7.6 - Prob. 4CCh. 7 - Which of the following can do work in a cell? (a)...Ch. 7 - Prob. 2TYUCh. 7 - Prob. 3TYUCh. 7 - Test Your Understanding 4. Diffusion is an (a)...Ch. 7 - Prob. 5TYUCh. 7 - Prob. 6TYUCh. 7 - Prob. 7TYUCh. 7 - Test Your Understanding 8. Induced fit means that...Ch. 7 - Prob. 9TYUCh. 7 - Prob. 10TYUCh. 7 - PREDICT In the following reaction series, which...Ch. 7 - Test Your Understanding 12. EVOLUTION link All...Ch. 7 - EVOLUTION LINK Some have argued that evolution is...Ch. 7 - Prob. 14TYUCh. 7 - Prob. 15TYUCh. 7 - Prob. 16TYU
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- Figure 6.8 Look at each of the processes shown, and decide if it is endergonic or exergonic. In each case, does enthalpy increase or decrease, and does entropy increase or decrease?arrow_forwardWhat terms would best describe the above coupled reaction?A. it is non-spontaneous and endothermic (because the overall Go is positive)B. it is spontaneous and exothermic (because the overall Go is positive)C. it is non-spontaneous and exothermic (because the overall Go is positive)D. it is spontaneous and exothermic (because the overall Go is negative)E. it is non-spontaneous and endothermic (because the overall Go is negative)arrow_forwardFor the reaction A → B at 298 K, the change in enthalpy is −7 kJ · mol−1and the change in entropy is −25 J · K−1 · mol−1. Is the reaction spontaneous? If not, should the temperature be increased or decreased to make the reaction spontaneous?arrow_forward
- infarrow_forwardWhich answers apply. (There could be more than one) Hydrolysis of ATP into ADP and inorganic phosphate releases energy because the reaction... a.) oxidizes ATP b.) reduces ATP c.) increases resonance d.) decreases resonance e.) increases entropy f.) decreases entropyarrow_forwardImagine you are working in a lab, and you are performing two chemical reactions. You notice that Reaction A occurs much faster than Reaction B, and that both reactions release the same amount of heat. Which of the following conclusions can be made from your observation? Reaction A has the same activation energy as Reaction B, and the AG of Reaction A is more negative (i.e., a larger negative number) than the AG for Reaction B. Reaction A has a lower activation energy than Reaction B, and the AG of Reaction A is the same as the AG of Reaction B. Reaction A has a higher activation energy than Reaction B, and the AG of Reaction A is the same as the AG of Reaction B. Reaction A has the same activation energy as Reaction B, and the AG of Reaction A is less negative (i.e., a smaller negative number) than the AG for Reaction B.arrow_forward
- Which one of the following statements is completely TRUE? O When AG > 0, the reaction is BOTH product-favored (spontaneous) AND endergonic. When AG 0, the reaction is BOTH reactant-favored (nonspontaneous) AND endergonic. When AG > 0, the reaction is BOTH product-favored (spontaneous) AND exergonic. When AG > 0, the reaction is BOTH reactant-favored (nonspontaneous) AND exergonic. When AG < 0, the reaction is BOTH reactant-favored (nonspontaneous) AND exergonic.arrow_forwardDefine the following terms. (i) Rate constant (k) (ii) Activation energy (Ea)arrow_forwardTrue or falsearrow_forward
- What do the following indicators tell you about whether a reaction can proceed as written? (a) The standard free-energy change is positive. (b) The free-energy change is positive. (c) The reaction is exergonicarrow_forwardChoose the best description of an enzyme: (a) It allows a chemical reaction to proceed extremely fast. (b) It increases the rate at which a chemical reaction approaches equilibrium relative to its uncatalyzed rate. (c) It makes a reaction thermodynamically favorable.arrow_forwardConsider the generic reaction2A+3B→2C,ΔHrxn=−100kJIf a reaction mixture initially contains 5 mol of A and 6 mol of B, how much heat (in kJ) will have evolved once the reaction has occurred to the greatest extent possible? 150kj 200kj 300kj 100kJarrow_forward
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