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(a)
Interpretation:
The way by which given compound is synthesized from ethyne should be given.
Concept Introduction:
Lindlar catalyst: The catalyst is used for the hydrogenation of
Sodium in liquid ammonia: The catalyst is used for the formation of trans
Erythro isomer: In a Fischer Projection formula, if identical substituents are on the same side, then the isomer can be called as erythro.
Threo isomer: In a Fischer projection formula, if identical substituents are on the different side, then the isomer can be called as threo.
Meso compound: It is a symmetric compound which has the plane of symmetry. If there are two chirality centres and same set of four groups are attached on each chirality centre, then it can be called as meso compound.
(b)
Interpretation:
The way by which given compound is synthesized from ethyne should be given.
Concept Introduction:
Lindlar catalyst: The catalyst is used for the hydrogenation of alkynes in a syn manner. This means both hydrogen are added on the same side across the triple bond and the product obtained will be a cis product.
Sodium in liquid ammonia: The catalyst is used for the formation of trans alkenes from alkynes. Because of its more reactivity towards triple bonds, the reaction will stop at the formation of alkenes.
Erythro isomer: In a Fischer Projection formula, if identical substituents are on the same side, then the isomer can be called as erythro.
Threo isomer: In a Fischer Projection formula, if identical substituents are on the different side, then the isomer can be called as threo.
Meso compound: It is a symmetric compound which has the plane of symmetry. If there are two chirality centres and same set of four groups are attached on each chirality centre, then it can be called as meso compound.
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Chapter 7 Solutions
EBK ORGANIC CHEMISTRY
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- I have a excitation/emission spectra of a quinine standard solution here, and I'm having trouble interpreting it. the red line is emission the blue line is excitation. i'm having trouble interpreting properly. just want to know if there is any evidence of raman or rayleigh peaks in the spectra.arrow_forwardGive the major product of the following reaction. excess 1. OH, H₂O 1.OH H CH3CH2CH21 H 2. A.-H₂O Draw the molecule on the canvas by choosing buttons from the Tools (for bonds), Atoms, and Advanced Template toolbars. The single bond is active by default.arrow_forward2. Use Hess's law to calculate the AH (in kJ) for: rxn CIF(g) + F2(g) → CIF 3 (1) using the following information: 2CIF(g) + O2(g) → Cl₂O(g) + OF 2(g) AH = 167.5 kJ ΔΗ 2F2 (g) + O2(g) → 2 OF 2(g) 2C1F3 (1) + 202(g) → Cl₂O(g) + 3 OF 2(g) о = = -43.5 kJ AH = 394.1kJarrow_forward
- The combustion of 28.8 g of NH3 consumes exactly _____ g of O2. 4 NH3 + 7 O2 ----> 4 NO2 + 6 H2Oarrow_forwardWhat is the molecular formula of the bond-line structure shown below OH HO ○ C14H12O2 ○ C16H14O2 ○ C16H12O2 O C14H14O2arrow_forwardCheck all molecules that are acids on the list below. H2CO3 HC2H3O2 C6H5NH2 HNO3 NH3arrow_forward
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