EBK ORGANIC CHEMISTRY
8th Edition
ISBN: 8220102744127
Author: Bruice
Publisher: PEARSON
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Textbook Question
Chapter 7, Problem 41P
What is each compound’s systematic name?
- a. CH3CH2C≡CCH2CH2C≡CH
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CONH₂
CH3
CH3
H₂C=CHCHCH₂CO₂CH3
1. LiAlH4
2. H₂O
1. LiAlH4
2. H3O+
Reagents
a. C6H5CHO
b. NaOH, ethanol
h. BrCH2CH=CH2
i.
Na* OEt, ethanol
j. Br2, H*
k. K* t-BuO
c. Pyrrolidine, cat. H*
d. H2C=CHCN
e. H3O*
f.
I. CH2(CO2ET)2
-CH2CH2CN
LDA
m. heat
g. ELOC(=0)CO2ET
Select reagents from the table to synthesize this compound from cyclopentanone.
Enter the letters of the chosen reagents, in the order that you wish to use them, without spaces or punctuation (i.e. geda).
Chapter 7 Solutions
EBK ORGANIC CHEMISTRY
Ch. 7.1 - Prob. 1PCh. 7.1 - Name the following:Ch. 7.1 - What is the molecular formula for a monocyclic...Ch. 7.1 - Draw the condensed and skeletal structures for...Ch. 7.1 - Draw the structure and give the common and...Ch. 7.2 - Prob. 6PCh. 7.2 - Name the following:Ch. 7.3 - What orbitals are used to form the carbon-carbon ...Ch. 7.4 - Prob. 9PCh. 7.4 - Why does cis-2-butene have a higher boiling point...
Ch. 7.6 - Prob. 12PCh. 7.6 - Prob. 13PCh. 7.7 - Prob. 14PCh. 7.7 - Which alkyne should be used for the synthesis of...Ch. 7.7 - Prob. 16PCh. 7.8 - Prob. 17PCh. 7.8 - Only one alkyne forms an aldehyde when it...Ch. 7.9 - Describe the alkyne you should start with and the...Ch. 7.9 - Prob. 20PCh. 7.10 - Prob. 21PCh. 7.10 - Prob. 22PCh. 7.10 - Prob. 23PCh. 7.10 - Rank the following from strongest base to weakest...Ch. 7.10 - Prob. 26PCh. 7.12 - Prob. 28PCh. 7 - What is the major product obtained from the...Ch. 7 - Draw a condensed structure for each of the...Ch. 7 - A student was given the structural formula of...Ch. 7 - Prob. 32PCh. 7 - What is each compounds systematic name?Ch. 7 - What reagents should be used to carry out the...Ch. 7 - Prob. 35PCh. 7 - Draw the mechanism for the following reaction:Ch. 7 - Prob. 37PCh. 7 - Prob. 38PCh. 7 - What is the major product of the reaction of 1 mol...Ch. 7 - Answer Problem 39, parts a-b, using 2-butyne as...Ch. 7 - What is each compounds systematic name? a....Ch. 7 - What is the molecular formula of a hydrocarbon...Ch. 7 - a. Starting with 3-methyl 1-butyne, how can you...Ch. 7 - Prob. 44PCh. 7 - Which of the following pairs are keto-enol...Ch. 7 - Prob. 46PCh. 7 - Do the equilibria of the following acid-base...Ch. 7 - What is each compounds systematic name?Ch. 7 - What stereoisomers are obtained when 2-butyne...Ch. 7 - Prob. 50PCh. 7 - Draw the keto tautomer for each of the following:Ch. 7 - Show how each of the following compounds can be...Ch. 7 - A chemist is planning to synthesize 3-octyne by...Ch. 7 - Prob. 54PCh. 7 - What stereoisomers are obtained from the following...Ch. 7 - Prob. 56PCh. 7 - Prob. 57PCh. 7 - Prob. 58PCh. 7 - Show how the following compound can be prepared...Ch. 7 - Prob. 60P
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- Draw the products formed when CH3CH2C ≡ C−Na+reacts with each compound. a. CH3CH2CH2Brb. (CH3)2CHCH2CH2Clc. (CH3CH2)3CCld. BrCH2CH2CH2CH2OHe. ethylene oxide followed by H2Of. propene oxide followed by H2Oarrow_forwardWhat is each compound’s systematic name?arrow_forward1. Provide proper IUPAC names for the following compounds. a. CH3 | CH3C CCHCH2CH2CH3 CH3 Br b. H₂C=CH-C-CH-CC-H | CH3 C.arrow_forward
- A : B :arrow_forwardWhich structure below shows the same compound as the following? NH₂ CH₂ CO₂H H HNH, C CH3 CO₂H b. CO₂H H₂N H CH3 Oc. CO₂H H -NH2 CH3 NH2 CH CH3 CO₂H Tiarrow_forward5. Which of these two compounds has a higher boiling point? Cyclopentanol The phenomenon responsible for that compound's higher boiling point is: cyclohexane 6. The electrophile in this reaction is: CH3CI benzene AICI3 a) CI* b) Cr c) CH,E- d) CH3*arrow_forward
- a. The following compounds have the same molecular formula as benzene. How many monobrominated products could each form? 1. HC‚CC‚CCH2CH3 2. CH2“CHC‚CCH“CH2 b. How many dibrominated products could each of the preceding compounds form? (Do not include stereoisomers.) c. How many dibrominated products could each of the compounds form if stereoisomers are included?arrow_forwardDoes the equilibrium favor the reactants or products in each substitution reaction? a. CH;CH2-NH2 Br CH;CH2-Br + "NH2 b. "CN CN + I-arrow_forwardDraw the missing structural formulas (A,C,D,E and F), and the isomer of B. Also explain which would be the major product and why for B.arrow_forward
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