Chemistry for Engineering Students
4th Edition
ISBN: 9781337398909
Author: Lawrence S. Brown, Tom Holme
Publisher: Cengage Learning
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Textbook Question
Chapter 7, Problem 12CO
• identify sigma and pi bonds in a molecule and explain the difference between them.
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In the solid state, oxalic acid occurs as
a dihydrate with the formula H2C2O4
C+2H2O. Use this formula to
calculate the formula weight of oxalic
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weight and the number of moles
(0.00504mol)
of oxalic acid in each titrated
unknown sample recorded in Table
6.4 to calculate the number of grams
of pure oxalic acid dihydrate
contained in each titrated unknown
sample.
1.
Consider a pair of elements with 2p and 4p valence orbitals (e.g., N and Se). Draw their
(2p and 4p AO's) radial probability plots, and sketch their angular profiles. Then, consider these
orbitals from the two atoms forming a homonuclear л-bond. Which element would have a
stronger bond, and why?
(4 points)
Write the reaction and show the mechanism of the reaction. Include the mechanism
for formation of the NO2+
2. Explain, using resonance structures, why the meta isomer is formed. Draw possible
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Chapter 7 Solutions
Chemistry for Engineering Students
Ch. 7 - List some factors influencing the biocompatibility...Ch. 7 - • use electron configurations to explain why...Ch. 7 - • describe die energy changes in the formation of...Ch. 7 - • define electronegativity and state how...Ch. 7 - • identify or predict polar, nonpolar, and ionic...Ch. 7 - • write Lewis electron structures for molecules or...Ch. 7 - • describe chemical bonding using a model based on...Ch. 7 - • explain how hybridization reconciles observed...Ch. 7 - • predict the geometry of a molecule from its,...Ch. 7 - • use models (real or software) to help visualize...
Ch. 7 - • explain the formation of multiple bonds in terms...Ch. 7 - • identify sigma and pi bonds in a molecule and...Ch. 7 - Define the term biocompatibility.Ch. 7 - List some properties associated with biomaterials...Ch. 7 - Prob. 7.3PAECh. 7 - Prob. 7.4PAECh. 7 - Prob. 7.5PAECh. 7 - Prob. 7.6PAECh. 7 - Why is the ion not found in nature?Ch. 7 - Why do nonmetals tend to form anions rather than...Ch. 7 - Prob. 7.9PAECh. 7 - 7.10 Arrange the members of each of the following...Ch. 7 - 7.11 Arrange the following sets of anions in order...Ch. 7 - 7.12 Which pair will form a compound with the...Ch. 7 - 7.13 Figure 7-2 depicts the interactions of an ion...Ch. 7 - 7.14 Describe the difference between a covalent...Ch. 7 - 7.15 Covalently bonded compounds tend to have much...Ch. 7 - Prob. 7.16PAECh. 7 - 7.17 Coulombic forces are often used to explain...Ch. 7 - 7.18 In terms of the strengths of the covalent...Ch. 7 - 7.19 If the formation of chemical bonds always...Ch. 7 - 7.20 Draw the Lewis dot symbol for each of the...Ch. 7 - 7.21 Theoretical models for the structure of...Ch. 7 - 7.22 Use Lewis dot symbols to explain why chlorine...Ch. 7 - 7.23 Define the term lone pair.Ch. 7 - 7.24 How many electrons are shared between two...Ch. 7 - 7.25 How does the bond energy of a double bond...Ch. 7 - 7.26 How is electronegativity defined?Ch. 7 - 7.27 Distinguish between electron affinity and...Ch. 7 - 7.28 Certain elements in the periodic table shown...Ch. 7 - 7.29 When two atoms with different...Ch. 7 - 7.30 The bond in HF is said to be polar, with the...Ch. 7 - 7.31 Why is a bond between two atoms with...Ch. 7 - Prob. 7.32PAECh. 7 - 7.33 In each group of three bonds, which bond is...Ch. 7 - Prob. 7.34PAECh. 7 - 7.35 Which one of the following contains botb...Ch. 7 - Prob. 7.36PAECh. 7 - 7.37 Draw the Lewis structure for each of the...Ch. 7 - 7.38 Draw a Lewis structure for each of the...Ch. 7 - Prob. 7.39PAECh. 7 - 7.40 Why is it impossible for hydrogen to be the...Ch. 7 - Prob. 7.41PAECh. 7 - 7.42 Draw resonance structure for (a) (b) and (c)Ch. 7 - Prob. 7.43PAECh. 7 - Prob. 7.44PAECh. 7 - Prob. 7.45PAECh. 7 - 7.46 Consider the nitrogen-oxygen bond lengths in...Ch. 7 - 7.47 Which of the species listed has a Lewis...Ch. 7 - 7.48 Identify what is incorrect in the Lewis...Ch. 7 - 7.49 Identify what is incorrect in the Lewis...Ch. 7 - 7.50 Chemical species are said to be isoelectronic...Ch. 7 - 7.51 Explain the concept of wave interference in...Ch. 7 - 7.52 How does orbital overlap explain the buildup...Ch. 7 - 7.53 How do sigma and pi bonds differ? How are...Ch. 7 - 7.54 CO , CO2 , CH3OH , and CO32 , all contain...Ch. 7 - 7.55 Draw the Lewis dot structure of the following...Ch. 7 - 7.56 Draw the Lewis dot structures of the...Ch. 7 - 7.57 What observation about molecules compels us...Ch. 7 - Prob. 7.58PAECh. 7 - 7.59 What type of hybrid orbital is generated by...Ch. 7 - 7.60 What type of hybridization would be expected...Ch. 7 - 7.61 What hybrid orbitals would be expected for...Ch. 7 - 7.62 What type of hybridization would you expect...Ch. 7 - 7.63 What physical concept forms the premise of...Ch. 7 - 7.64 Predict the geometry of the following...Ch. 7 - Prob. 7.65PAECh. 7 - Prob. 7.66PAECh. 7 - Prob. 7.67PAECh. 7 - 7.68 Give approximate values for the indicated...Ch. 7 - 7.69 Propene has the chemical formula Describe the...Ch. 7 - Prob. 7.70PAECh. 7 - Prob. 7.71PAECh. 7 - 7.72 How does an MSN differ from amorphous silica...Ch. 7 - Prob. 7.73PAECh. 7 - 7.74 In a lattice, a positive ion is often...Ch. 7 - 7.75 Use the concept of lattice energy to...Ch. 7 - Prob. 7.76PAECh. 7 - Prob. 7.77PAECh. 7 - Prob. 7.78PAECh. 7 - Prob. 7.79PAECh. 7 - Prob. 7.80PAECh. 7 - Prob. 7.81PAECh. 7 - Prob. 7.82PAECh. 7 - Prob. 7.83PAECh. 7 - 7.84 Which of the following molecules is least...Ch. 7 - 7.85 Consider the molecule whose structure is...Ch. 7 - 7.86 Nitrogen triiodide, NI3(s) , is unstable and...Ch. 7 - 7.87 Nitrogen is capable of forming single,...Ch. 7 - 7.88 The N5+ cation has been synthesized and...Ch. 7 - Prob. 7.89PAECh. 7 - Prob. 7.90PAECh. 7 - 7.91 A Lewis structure for the oxalate ion is...Ch. 7 - Prob. 7.92PAECh. 7 - 7.93 An unknown metal M forms a chloride with the...Ch. 7 - Prob. 7.94PAECh. 7 - Prob. 7.95PAECh. 7 - 7.96 Consider the hydrocarbons whose structures...Ch. 7 - 7.97 Consider the structure shown below for as...Ch. 7 - Prob. 7.98PAECh. 7 - Prob. 7.99PAECh. 7 - Prob. 7.100PAECh. 7 - 7.101 Lead selenide nanocrystals may provide a...Ch. 7 - Prob. 7.102PAECh. 7 - Prob. 7.103PAECh. 7 - 7.104 Hydrogen azide, HN3 , is a liquid that...Ch. 7 - Prob. 7.105PAECh. 7 - Prob. 7.106PAECh. 7 - 7.107 How do the Lewis symbols for C, Si, and Ge...Ch. 7 - Prob. 7.108PAECh. 7 - Prob. 7.109PAE
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- Nonearrow_forward3. A molecular form of "dicarbon", C2, can be generated in gas phase. Its bond dissociation energy has been determined at 599 kJ/mol. Use molecular orbital theory to explain why energy of dissociation for C₂+ is 513 kJ/mol, and that for C2² is 818 kJ/mol. (10 points)arrow_forward9.73 g of lead(IV) chloride contains enough Cl- ions to make ____ g of magnesium chloride.arrow_forward
- 6. a) C2's. Phosphorus pentafluoride PF5 belongs to D3h symmetry group. Draw the structure of the molecule, identify principal axis of rotation and perpendicular (4 points) b) assume that the principal axis of rotation is aligned with z axis, assign symmetry labels (such as a1, b2, etc.) to the following atomic orbitals of the P atom. (character table for this group is included in the Supplemental material). 3s 3pz (6 points) 3dz²arrow_forward2. Construct Lewis-dot structures, and draw VESPR models for the ions listed below. a) SiF5 (4 points) b) IOF4 (4 points)arrow_forward5. Complex anion [AuCl2]¯ belongs to Doh symmetry point group. What is the shape of this ion? (4 points)arrow_forward
- 4. Assign the following molecules to proper point groups: Pyridine N 1,3,5-triazine N Narrow_forward7. a) Under normal conditions (room temperature & atmospheric pressure) potassium assumes bcc lattice. Atomic radius for 12-coordinate K atom is listed as 235 pm. What is the radius of potassium atom under normal conditions? (3 points) b) Titanium metal crystallyzes in hcp lattice. Under proper conditions nitrogen can be absorbed into the lattice of titanium resulting in an alloy of stoichiometry TiNo.2. Is this compound likely to be a substitutional or an interstitial alloy? (Radius of Ti (12-coordinate) is 147 pm; radius of N atom is 75 pm. (3 points)arrow_forwardcan someone answer the questions and draw out the complete mechanismarrow_forward
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