ORGANIC CHEMISTRY (LL)-PACKAGE
ORGANIC CHEMISTRY (LL)-PACKAGE
8th Edition
ISBN: 9781319316389
Author: VOLLHARDT
Publisher: MAC HIGHER
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Chapter 6.8, Problem 6.21E

(a)

Interpretation Introduction

Interpretation:The better nucleophile out of HS & H2S should be selected.

Concept introduction:Nucleophile is an electron rich, negative ion or a molecule with an electronegative atom & lone pairs of electrons.

(b)

Interpretation Introduction

Interpretation: The better nucleophile out of CH3S & CH3SH should be selected.

Concept introduction: Nucleophile is an electron rich, negative ion or a molecule with an electronegative atom & lone pairs of electrons.

(c)

Interpretation Introduction

Interpretation: The better nucleophile out of CH3NH & CH3NH2 should be selected.

Concept introduction: Nucleophile is an electron rich, negative ion or a molecule with an electronegative atom & lone pairs of electrons.

(d)

Interpretation Introduction

Interpretation: The better nucleophile out of HSe & H2Se should be selected.

Concept introduction: Nucleophile is an electron rich, negative ion or a molecule with an electronegative atom & lone pairs of electrons.

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Transmitance 3. Which one of the following compounds corresponds to this IR spectrum? Point out the absorption band(s) that helped you decide. OH H3C OH H₂C CH3 H3C CH3 H3C INFRARED SPECTRUM 0.8- 0.6 0.4- 0.2 3000 2000 1000 Wavenumber (cm-1) 4. Consider this compound: H3C On the structure above, label the different types of H's as A, B, C, etc. In table form, list the labeled signals, and for each one state the number of hydrogens, their shifts, and the splitting you would observe for these hydrogens in the ¹H NMR spectrum. Label # of hydrogens splitting Shift (2)
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