ORGANIC CHEMISTRY (LL)-PACKAGE
ORGANIC CHEMISTRY (LL)-PACKAGE
8th Edition
ISBN: 9781319316389
Author: VOLLHARDT
Publisher: MAC HIGHER
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Chapter 6.2, Problem 6.3TIY

(a)

Interpretation Introduction

Interpretation:The starting materials to produce (CH3CH2)2O should be suggested.

Concept introduction: (CH3CH2)2O is an ether having two similar CH3CH2 alkyl groups.

(b)

Interpretation Introduction

Interpretation: The starting materials to produce (CH3)4N+I should be suggested.

Concept introduction: (CH3)4N+I is a derivative of NH4+ where the four Hydrogen atoms have been replaced with four CH3 alkyl groups.

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Review of this week's reaction:  H2NCN (cyanamide) + CH3NHCH2COOH (sarcosine) + NaCl, NH4OH, H2O ----> H2NC(=NH)N(CH3)CH2COOH (creatine) Q7. Draw by hand the reaction of creatine synthesis listed above using line structures without showing the Cs and some of the Hs, but include the lone pairs of electrons wherever they apply. (4 pts) Q8. Considering the Zwitterion form of an amino acid, draw the Zwitterion form of Creatine. (2 pts) Q9. Explain with drawing why the C—N bond shown in creatine structure below can or cannot rotate. (3 pts)
Would the following organic synthesis occur in one step? Add any missing products, required catalysts, inorganic reagents, and other important conditions. Please include a detailed explanation and drawings showing how the reaction may occur in one step.
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