
ORGANIC CHEMISTRY (LL)-PACKAGE
8th Edition
ISBN: 9781319316389
Author: VOLLHARDT
Publisher: MAC HIGHER
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Question
Chapter 6.6, Problem 6.16TIY
(a)
Interpretation Introduction
Interpretation:The chemical structure of (S)-alanine & the relevant enantiomer of 2-bromopropanoic acid should be drawn.
Concept introduction:Stereoisomers have two configurations called as R&S. The R configuration corresponds to the clockwise arrangement of the priority groups and S represents the anticlockwise arrangement of the priority groups.
(b)
Interpretation Introduction
Interpretation: The product of the given SN2 reaction should be stated.
Concept introduction:
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Identifying electron-donating and
For each of the substituted benzene molecules below, determine the inductive and resonance effects the substituent will have on the
benzene ring, as well as the overall electron-density of the ring compared to unsubstituted benzene.
Molecule
Inductive Effects
NH2
○ donating
NO2
Explanation
Check
withdrawing
no inductive effects
Resonance Effects
Overall Electron-Density
○ donating
O withdrawing
O no resonance effects
O donating
O withdrawing
O donating
withdrawing
O no inductive effects
Ono resonance effects
O electron-rich
electron-deficient
O similar to benzene
O electron-rich
O electron-deficient
O similar to benzene
olo
18
Ar
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Rank each of the following substituted benzene molecules in order of which will react fastest (1) to slowest (4) by electrophilic
aromatic substitution.
Explanation
Check
Х
(Choose one)
OH
(Choose one)
OCH3
(Choose one)
OH
(Choose one)
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Assign R or S to all the chiral centers in each compound drawn below
porat
bg
9
Br
Br
Chapter 6 Solutions
ORGANIC CHEMISTRY (LL)-PACKAGE
Ch. 6.2 - Prob. 6.1ECh. 6.2 - Prob. 6.3TIYCh. 6.3 - Prob. 6.4ECh. 6.3 - Prob. 6.5ECh. 6.3 - Prob. 6.6ECh. 6.3 - Prob. 6.7ECh. 6.3 - Prob. 6.8ECh. 6.4 - Prob. 6.10TIYCh. 6.4 - Prob. 6.11ECh. 6.5 - Prob. 6.12E
Ch. 6.5 - Prob. 6.13ECh. 6.6 - Prob. 6.14ECh. 6.6 - Prob. 6.16TIYCh. 6.6 - Prob. 6.17ECh. 6.7 - Prob. 6.18ECh. 6.7 - Prob. 6.19ECh. 6.7 - Prob. 6.20ECh. 6.8 - Prob. 6.21ECh. 6.8 - Prob. 6.22ECh. 6.8 - Prob. 6.23ECh. 6.8 - Prob. 6.24ECh. 6.9 - Prob. 6.26TIYCh. 6.10 - Prob. 6.27ECh. 6.10 - Prob. 6.28ECh. 6 - Prob. 31PCh. 6 - Prob. 32PCh. 6 - Prob. 33PCh. 6 - Prob. 34PCh. 6 - Prob. 35PCh. 6 - Prob. 36PCh. 6 - Prob. 37PCh. 6 - Prob. 38PCh. 6 - Prob. 39PCh. 6 - Prob. 40PCh. 6 - Prob. 41PCh. 6 - Prob. 42PCh. 6 - Prob. 43PCh. 6 - Prob. 44PCh. 6 - Prob. 45PCh. 6 - Prob. 46PCh. 6 - Prob. 47PCh. 6 - Prob. 48PCh. 6 - Prob. 49PCh. 6 - Prob. 50PCh. 6 - Prob. 51PCh. 6 - Prob. 52PCh. 6 - Prob. 53PCh. 6 - Prob. 54PCh. 6 - Prob. 55PCh. 6 - Prob. 56PCh. 6 - Prob. 57PCh. 6 - Prob. 58PCh. 6 - Prob. 59PCh. 6 - Prob. 60PCh. 6 - Prob. 61PCh. 6 - Prob. 62PCh. 6 - Prob. 63PCh. 6 - Prob. 64PCh. 6 - Prob. 65PCh. 6 - Prob. 66PCh. 6 - Prob. 67PCh. 6 - Prob. 68P
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