ORGANIC CHEMISTRY (LL)-PACKAGE
ORGANIC CHEMISTRY (LL)-PACKAGE
8th Edition
ISBN: 9781319316389
Author: VOLLHARDT
Publisher: MAC HIGHER
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Chapter 6.6, Problem 6.16TIY

(a)

Interpretation Introduction

Interpretation:The chemical structure of (S)-alanine & the relevant enantiomer of 2-bromopropanoic acid should be drawn.

Concept introduction:Stereoisomers have two configurations called as R&S. The R configuration corresponds to the clockwise arrangement of the priority groups and S represents the anticlockwise arrangement of the priority groups.

(b)

Interpretation Introduction

Interpretation: The product of the given SN2 reaction should be stated.

Concept introduction: Alkyl halides have the ability to perform nucleophilic substitution reactions.

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Transmitance 3. Which one of the following compounds corresponds to this IR spectrum? Point out the absorption band(s) that helped you decide. OH H3C OH H₂C CH3 H3C CH3 H3C INFRARED SPECTRUM 0.8- 0.6 0.4- 0.2 3000 2000 1000 Wavenumber (cm-1) 4. Consider this compound: H3C On the structure above, label the different types of H's as A, B, C, etc. In table form, list the labeled signals, and for each one state the number of hydrogens, their shifts, and the splitting you would observe for these hydrogens in the ¹H NMR spectrum. Label # of hydrogens splitting Shift (2)
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