General, Organic, & Biological Chemistry
General, Organic, & Biological Chemistry
3rd Edition
ISBN: 9780073511245
Author: Janice Gorzynski Smith Dr.
Publisher: McGraw-Hill Education
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Chapter 6, Problem 6.89P

Consider the gas-phase reaction of ethylene ( CH 2 |  |CH 2 ) with hydrogen to form ethane ( C 2 H 6 ) , which occurs in the presence of a palladium catalyst ( Section-6 .4B ) .

  1. Write the expression for the equilibrium constant for this reaction.
  2. If Δ H = 28 kcal, are the products or reactants higher in energy?
  3. Which is likely to be true about the equilibrium constant for the reaction: K > 1 or K < 1.
  4. How much energy is released when 20.0 g of ethylene reacts?
  5. What happens to the rate of the reaction if the concentration of ethylene isincreased?
  6. What happens to the equilibrium when each of the following changes occurs: [ 1 ] an increase in [H 2 ]; [2] a decrease in [C 2 H 6 ]; [3] an increase in temperature; [ 4 ] an increase inpressure; [ 5 ] removal of the palladium catalyst?

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Consider the gas-phase reaction of ethylene (CH 2 CH 2) with hydrogen to form ethane (C 2H 6), which occurs in the presence of a palladium catalyst (Section 6.4B). a. Write the expression for the equilibrium constant for this reaction. b. If ΔH = −28 kcal/mol, are the products or reactants higher in energy? c. Which is likely to be true about the equilibrium constant for the reaction: K > 1 or K < 1? d. How much energy is released when 20.0 g of ethylene reacts? e. What happens to the rate of the reaction if the concentration of ethylene is increased? f. What happens to the equilibrium when each of the following changes occurs: [1] an increase in [H 2]; [2] a decrease in [C 2H 6]; [3] an increase in temperature; [4] an increase in pressure; [5] removal of the palladium catalyst?
For the equilibrium reaction 2SO 2(g) + O 2(g)   <->  2SO 3(g), ΔHº rxn = –198 kJ/mol. Which one of these factors would cause the equilibrium constant to  increase?     Add SO2 gas.     Add a catalyst.     None of these.     Decrease the temperature.     Remove O2 gas.
Consider the reaction: CH₂COOH(aq) + SO4 (aq) =HSO4(aq) + CH₂COO (aq) The K for CH₂COOH is 1.75 x 105 and the K, for HSO is 1.2 × 102. Is this reaction reactant favored or product favored? Select the single best answer. Reactant favored Product favored X 5 olo 2

Chapter 6 Solutions

General, Organic, & Biological Chemistry

Ch. 6.4 - Consider the reaction of ozone (O3) with nitrogen...Ch. 6.4 - Draw an energy diagram for an uncatalyzed...Ch. 6.5 - Identify the forward and reverse reactions in each...Ch. 6.5 - Write the expression for the equilibrium constant...Ch. 6.5 - Consider the reversible reaction AB, with K=1....Ch. 6.5 - Given each equilibrium constant, state whether the...Ch. 6.5 - Consider the following reaction:...Ch. 6.5 - Calculate the equilibrium constant for each...Ch. 6.5 - Prob. 6.19PCh. 6.6 - Prob. 6.20PCh. 6.6 - Prob. 6.21PCh. 6.6 - Prob. 6.22PCh. 6.6 - Prob. 6.23PCh. 6.6 - Prob. 6.24PCh. 6 - Prob. 6.25PCh. 6 - Prob. 6.26PCh. 6 - Prob. 6.27PCh. 6 - Prob. 6.28PCh. 6 - Prob. 6.29PCh. 6 - Prob. 6.30PCh. 6 - Prob. 6.31PCh. 6 - Prob. 6.32PCh. 6 - Prob. 6.33PCh. 6 - Prob. 6.34PCh. 6 - Prob. 6.35PCh. 6 - Prob. 6.36PCh. 6 - Prob. 6.37PCh. 6 - Prob. 6.38PCh. 6 - Prob. 6.39PCh. 6 - Prob. 6.40PCh. 6 - Prob. 6.41PCh. 6 - Ammonia ( NH3 ) decomposes to hydrogen and...Ch. 6 - Prob. 6.43PCh. 6 - Ethanol ( C2H6O ), a gasoline additive, is formed...Ch. 6 - Prob. 6.45PCh. 6 - Prob. 6.46PCh. 6 - Prob. 6.47PCh. 6 - Prob. 6.48PCh. 6 - Draw an energy diagram for the following reaction...Ch. 6 - Prob. 6.50PCh. 6 - Prob. 6.51PCh. 6 - Explain why a high energy of activation causes a...Ch. 6 - State two reasons why increasing temperature...Ch. 6 - Why does decreasing concentration decrease the...Ch. 6 - Prob. 6.55PCh. 6 - Prob. 6.56PCh. 6 - Which of the following affect the rate of a...Ch. 6 - Prob. 6.58PCh. 6 - How does a catalyst affect each of the following:...Ch. 6 - What is the difference between a catalyst and an...Ch. 6 - Prob. 6.61PCh. 6 - Consider the representation depicted in the...Ch. 6 - For each value, are the reactants or products...Ch. 6 - Prob. 6.64PCh. 6 - Prob. 6.65PCh. 6 - Prob. 6.66PCh. 6 - Prob. 6.67PCh. 6 - Prob. 6.68PCh. 6 - Prob. 6.69PCh. 6 - Consider three different equilibrium mixtures...Ch. 6 - Write an expression for the equilibrium constant...Ch. 6 - Write an expression for the equilibrium constant...Ch. 6 - Prob. 6.73PCh. 6 - Use each expression for the equilibrium constant...Ch. 6 - Prob. 6.75PCh. 6 - Consider the following reaction:...Ch. 6 - Prob. 6.77PCh. 6 - Consider the following reaction. H2(g)+I2(g)2HI(g)...Ch. 6 - Prob. 6.79PCh. 6 - Prob. 6.80PCh. 6 - Consider the reaction of N2(g)+O2(g)2NO(g). What...Ch. 6 - Consider the reaction of H2(g)+F2(g)2HF(g). What...Ch. 6 - Prob. 6.83PCh. 6 - Consider the reversible reaction ABA+B, shown at...Ch. 6 - Consider the endothermic conversion of oxygen to...Ch. 6 - Consider the exothermic reaction:...Ch. 6 - Consider the exothermic reaction:...Ch. 6 - Consider the endothermic reaction:...Ch. 6 - Consider the gas-phase reaction of ethylene...Ch. 6 - Methanol (CHO), which is used as a fuel in race...Ch. 6 - Prob. 6.91PCh. 6 - How does a catalytic converter clean up automobile...Ch. 6 - Prob. 6.93PCh. 6 - The reaction of salicylic acid with acetic acid...Ch. 6 - Prob. 6.95PCh. 6 - Prob. 6.96PCh. 6 - Prob. 6.97PCh. 6 - Prob. 6.98PCh. 6 - Prob. 6.99CPCh. 6 - Prob. 6.100CP
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