General, Organic, & Biological Chemistry
General, Organic, & Biological Chemistry
3rd Edition
ISBN: 9780073511245
Author: Janice Gorzynski Smith Dr.
Publisher: McGraw-Hill Education
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Chapter 6.5, Problem 6.17P

Consider the following reaction: 2H 2 ( g ) + S 2 ( g ) 2H 2 S ( g ) with K = 1 .1 × 10 7 . (a) Write the expression for the equilibrium constant for this reaction. (b) Are the reactants or products favored at equilibrium? (c) Would you predict Δ H to be positive or negative? (d) Are the reactants or products lower in energy? (e) Would you predict this reaction to be fast or slow? Explain your choice.

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Be sure to answer all parts. Consider the following reaction: 2 H2(g) + S2(g) 2 H,S(g) with K = 1.1 x× 10'. (a) Write the expression for the equilibrium constant for this reaction. (b) Are the reactants or products favo at equilibrium? (c) Would you predict AH to be positive or negative? (d) Are the reactants or products lower in energy? (e) Would you predict this reaction to be fast or slow? (a) K = (b) (select) (c) AH would be (select) (d) The (select) are lower in energy. (e) (select)
2. Consider the following equilibrium: C (s) + H,O (g) = CÓ (g) + H, (g), AH® = +131.3 kJ-mol·' (1) Please write the expression of reaction quotient K. (2) Use Le Chatelier's Principle to state and explain the effect on the equilibrium when: (a) the pressure of H2O is increased; (b) the temperature is increased; (c) the concentration of the H, is increased; (d) The total pressure is increased by decreasing the volume. 作答
7.B Consider the chemical equation C(s) + 2A(g) 5 2B(I) + heat. Be sure to briefly JUSTIFY each answer below. (a) Will SQUEEZING the container cause a disturbance to equilibrium? If so, then in what direction will the reaction occur? (b) Will RAISING THE TEMPERATURE of the system cause a disturbance to equilibrium? If so, then in what direction will the reaction occur? (c) What is the sign of the standard reaction ENTHALPY? Does the enthalpy change provide a favorable or unfavorable contribution to the spontaneity of the forward reaction at standard state conditions? (d) What is the sign of the standard reaction ENTROPY? Does the entropy change provide a favorable or unfavorable contribution to the spontaneity of the forward reaction at standard state conditions? (e) Based on (c,d) describe the preference for products or reactants at equilibrium at very LOW temperatures. (f) Based on (c,d) describe the preference for products or reactants at equilibrium at very HIGH temperatures.

Chapter 6 Solutions

General, Organic, & Biological Chemistry

Ch. 6.4 - Consider the reaction of ozone (O3) with nitrogen...Ch. 6.4 - Draw an energy diagram for an uncatalyzed...Ch. 6.5 - Identify the forward and reverse reactions in each...Ch. 6.5 - Write the expression for the equilibrium constant...Ch. 6.5 - Consider the reversible reaction AB, with K=1....Ch. 6.5 - Given each equilibrium constant, state whether the...Ch. 6.5 - Consider the following reaction:...Ch. 6.5 - Calculate the equilibrium constant for each...Ch. 6.5 - Prob. 6.19PCh. 6.6 - Prob. 6.20PCh. 6.6 - Prob. 6.21PCh. 6.6 - Prob. 6.22PCh. 6.6 - Prob. 6.23PCh. 6.6 - Prob. 6.24PCh. 6 - Prob. 6.25PCh. 6 - Prob. 6.26PCh. 6 - Prob. 6.27PCh. 6 - Prob. 6.28PCh. 6 - Prob. 6.29PCh. 6 - Prob. 6.30PCh. 6 - Prob. 6.31PCh. 6 - Prob. 6.32PCh. 6 - Prob. 6.33PCh. 6 - Prob. 6.34PCh. 6 - Prob. 6.35PCh. 6 - Prob. 6.36PCh. 6 - Prob. 6.37PCh. 6 - Prob. 6.38PCh. 6 - Prob. 6.39PCh. 6 - Prob. 6.40PCh. 6 - Prob. 6.41PCh. 6 - Ammonia ( NH3 ) decomposes to hydrogen and...Ch. 6 - Prob. 6.43PCh. 6 - Ethanol ( C2H6O ), a gasoline additive, is formed...Ch. 6 - Prob. 6.45PCh. 6 - Prob. 6.46PCh. 6 - Prob. 6.47PCh. 6 - Prob. 6.48PCh. 6 - Draw an energy diagram for the following reaction...Ch. 6 - Prob. 6.50PCh. 6 - Prob. 6.51PCh. 6 - Explain why a high energy of activation causes a...Ch. 6 - State two reasons why increasing temperature...Ch. 6 - Why does decreasing concentration decrease the...Ch. 6 - Prob. 6.55PCh. 6 - Prob. 6.56PCh. 6 - Which of the following affect the rate of a...Ch. 6 - Prob. 6.58PCh. 6 - How does a catalyst affect each of the following:...Ch. 6 - What is the difference between a catalyst and an...Ch. 6 - Prob. 6.61PCh. 6 - Consider the representation depicted in the...Ch. 6 - For each value, are the reactants or products...Ch. 6 - Prob. 6.64PCh. 6 - Prob. 6.65PCh. 6 - Prob. 6.66PCh. 6 - Prob. 6.67PCh. 6 - Prob. 6.68PCh. 6 - Prob. 6.69PCh. 6 - Consider three different equilibrium mixtures...Ch. 6 - Write an expression for the equilibrium constant...Ch. 6 - Write an expression for the equilibrium constant...Ch. 6 - Prob. 6.73PCh. 6 - Use each expression for the equilibrium constant...Ch. 6 - Prob. 6.75PCh. 6 - Consider the following reaction:...Ch. 6 - Prob. 6.77PCh. 6 - Consider the following reaction. H2(g)+I2(g)2HI(g)...Ch. 6 - Prob. 6.79PCh. 6 - Prob. 6.80PCh. 6 - Consider the reaction of N2(g)+O2(g)2NO(g). What...Ch. 6 - Consider the reaction of H2(g)+F2(g)2HF(g). What...Ch. 6 - Prob. 6.83PCh. 6 - Consider the reversible reaction ABA+B, shown at...Ch. 6 - Consider the endothermic conversion of oxygen to...Ch. 6 - Consider the exothermic reaction:...Ch. 6 - Consider the exothermic reaction:...Ch. 6 - Consider the endothermic reaction:...Ch. 6 - Consider the gas-phase reaction of ethylene...Ch. 6 - Methanol (CHO), which is used as a fuel in race...Ch. 6 - Prob. 6.91PCh. 6 - How does a catalytic converter clean up automobile...Ch. 6 - Prob. 6.93PCh. 6 - The reaction of salicylic acid with acetic acid...Ch. 6 - Prob. 6.95PCh. 6 - Prob. 6.96PCh. 6 - Prob. 6.97PCh. 6 - Prob. 6.98PCh. 6 - Prob. 6.99CPCh. 6 - Prob. 6.100CP
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