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Concept explainers
Interpretation:
The greatest resonance contributor from the given resonance structures is to be identified.
Concept introduction:
The lowest energy (more stable) resonance structure is the greatest resonance contributor to the hybrid. The stability of a resonance structure is governed by the following factors: greater number of atoms with octets, greater number of covalent bonds, and least number of formal charges. Further, the negative charge on the more electronegative atom and the positive charge on the least electronegative atom increase the stability of the resonance structure. The electron donating groups stabilize the positively charged atom, and the electron withdrawing groups stabilize the negatively charged atoms.
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Chapter 6 Solutions
Organic Chemistry: Principles And Mechanisms: Study Guide/solutions Manual (second)
- Write the equilibrium constant expression for the following reaction: HNO2(aq) + H2O(l) ⇌ H3O+(aq) + NO2-(aq)arrow_forwardWrite the reaction quotient for: Pb2+(aq) + 2 Cl- (aq) ⇌ PbCl2(s)arrow_forwardWrite the equilibrium constant expression for the following system at equilibrium: I2 (g) ⇌ 2 I (g)arrow_forward
- Don't used hand raiting and don't used Ai solutionarrow_forwardWe learned four factors (ARIO) for comparing the relative acidity of compounds. When two of these factors are in competition, the order of priority is the order in which these factors were covered ("atom" being the most important factor and "orbital" being the least important). However, we also mentioned that there are exceptions to this order of priority. Compare the two compounds and identify the exception. OH PK-4.75 SH PK-10.6 5. "Resonance" is more important than "atom" because the conjugate base of first compound is more stable than the second. "Atom" is more important than "resonance" because the conjugate base of first compound is more stable than the second. "Resonance" is more important than "atom" because the conjugate base of second compound is more stable than the first. "Atom" is more important than "resonance" because the conjugate base of second compound is more stable than the first.arrow_forwardThe relative fitnesses of three genotypes are WA/A= 1.0, WA/a = 0.7, and Wa/a = 0.3. If the population starts at the allele frequency p = 0.5, what is the value of p in the next generation? (3 pts) 12pt v Paragraph V BIU ALarrow_forward
- Identify the most acidic proton in the compound: a d b Оа Ob Ос ○ darrow_forwardA Standard Reference Material is certified to contain 94.6 ppm of an organic contaminant in soil. Your analysis gives values of 98.6, 98.4, 97.2, 94.6, and 96.2. Do your results differ from the expected results at the 95% confidence interval?arrow_forwardThe percentage of an additive in gasoline was measured six times with the following results: 0.13, 0.12, 0.16, 0.17, 0.20, and 0.11%. Find the 95% confidence interval for the percentage of additive.arrow_forward
- Explain why this data led Rayleigh to look for and to discover Ar.arrow_forward5) Confidence interval. Berglund and Wichardt investigated the quantitative determination of Cr in high-alloy steels using a potentiometric titration of Cr(VI). Before the titration, samples of the steel were dissolved in acid and the chromium oxidized to Cr(VI) using peroxydisulfate. Shown here are the results (as %w/w Cr) for the analysis of a reference steel. 16.968, 16.922, 16.840, 16.883, 16.887, 16.977, 16.857, 16.728 Calculate the mean, the standard deviation, and the 95% confidence interval about the mean. What does this confidence interval mean?arrow_forwardIn the Nitrous Acid Test for Amines, what is the observable result for primary amines? Group of answer choices nitrogen gas bubbles form a soluble nitrite salt yellow oily layer of nitrosoaminearrow_forward
- Organic Chemistry: A Guided InquiryChemistryISBN:9780618974122Author:Andrei StraumanisPublisher:Cengage Learning
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