Concept explainers
Interpretation:
The resonance structures have to be drawn for the molecule in which the octet rule is satisfied for both
Concept Introduction:
Octet Rule:
The octet rule states that the noble gas electron configuration is attained by the element, when the element either loses or gains or shares its atoms. The formulas for the compounds that contain specific elements can be predicted with the help of Octet rule. The octet rule holds good for those compounds that are made of elements present in second period and hence the important study on organic compounds that mainly consists of Carbon, Nitrogen and Oxygen atoms can be done with the help of Octet rule. The loss gain or sharing electrons of particular atom is dependent on properties of atoms that are determined by the number of subatomic particles inside in the atom.
Resonance:
Resonance is a method to relating to describe about delocalized electrons inside certain molecules or polyatomic ions where the Lewis structure can’t be expressed. A molecule or ion containing delocalized electrons can be represented by using several similar structures such structures are called as resonance structures or canonical structures.
The delocalization of electron lowers the potential energy of the substance and making it more stable than any of the contributing structures. The variation in the potential energy of the actual structure and that of resemblance structure with lowest potential energy is known as resonance energy or delocalization energy.
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Chemistry: Atoms First
- Draw resonance structures for each of these ions: NSO− and SNO−. (The atoms are bonded in the order given in each case, that is, S is the central atom in NSO−.) Use formal charges to determine which ion is likely to be more stable. Explain why the two ions cannot be considered resonance structures of each other.arrow_forwardTwo Lewis structures can be written for nitrosyl fluoride, which contains one nitrogen, one oxygen, and one fluorine atom per molecule. Write the two Lewis structures land assign a formal charge to each atom.arrow_forwardA complete Lewis structure must show all nonzero formal charges. Complete each of thefollowing Lewis structures by adding any missing formal charges.arrow_forward
- Write all resonance structures of chlorobenzene, C6H5Cl, a molecule with the same cyclic structure as benzene. In all structures, keep the CCl bond as a single bond. Which resonance structures are the most important?arrow_forwardChloromethane has the Lewis structure _______________________________ The carbon atom is sharing 4 electron pairs. In each shared pair the carbon atom “owns” 1 electron. The number of electrons that “belong” to carbon is ___. Carbon, being a Group ___ element would have 4 , outer shell electrons in the unbonded, neutral state. Therefore, the carbon atom in chloromethane has a formal charge of zero.arrow_forwardWrite the Lewis structure and chemical formula of the compound with a molar mass of about 70 g/mol that contains 19.7% nitrogen and 80.3% fluorine by mass, and determine the formal charge of the atoms in this compound.arrow_forward
- 3. The skeleton of chloromethane is __________________ The central carbon atom is bonded to each of the other atoms by a shared electron pair (represented by a straight line, ___) giving Now, each hydrogen has two electrons and the carbon atom has eight. However, chlorine must be provided with unshared electrons (represented by pairs of dots, ) to complete its octet, thusarrow_forwardAspirin is made from salicylic acid, which has this Lewis structure: (a) Which is the longest carbon-carbon bond? (b) Which is the strongest carbon-oxygen bond? (c) Draw resonance structures for this molecule.arrow_forwardA polyatomic ion is composed of C, N, and an unknown element X. The skeletal Lewis structure of this polyatomic ion is [XCN]. The ion X2 has an electron configuration of [Ar]4s23d104p6. What is element X? Knowing the identity of X, complete the Lewis structure of the polyatomic ion, including all important resonance structures.arrow_forward
- Methylcyanoacrylate is the active ingredient in super glues. Its Lewis structure is In this molecule, which is the (a) weakest carbon-containing bond? (b) strongest carbon-containing bond? (c) most polar bond?arrow_forwardA common trait of simple organic compounds is to have Lewis structures where all atoms have a formal charge of zero. Consider the following incomplete Lewis structure for an organic compound called methyl cyanoacrylate, the main ingredient in Super Glue. Draw a complete Lewis structure for methyl cyanoacrylate in which all atoms have a formal charge of zero.arrow_forwardWrite reasonable Lewis structures for the following species, none of which follow the octet rule. (a) BF3 (b) NO (c) CO+ (d) ClO3arrow_forward
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