Chemistry: Atoms First
Chemistry: Atoms First
2nd Edition
ISBN: 9780073511184
Author: Julia Burdge, Jason Overby Professor
Publisher: McGraw-Hill Education
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Chapter 6, Problem 6.44QP
Interpretation Introduction

Interpretation:

The explanation why compounds containing elements in the third period of the periodic table and beyond doesn’t obey the octet rule has to be given.

Concept Introduction:

Octet Rule:

The octet rule states that the noble gas electron configuration is attained by the element, when the element either loses or gains or shares its atoms.  The formulas for the compounds that contain specific elements can be predicted with the help of Octet rule.  The octet rule holds good for those compounds that are made of elements present in second period and hence the important study on organic compounds that mainly consists of Carbon, Nitrogen and Oxygen atoms can be done with the help of Octet rule.  The loss gain or sharing electrons of particular atom is dependent on properties of atoms that are determined by the number of subatomic particles inside in the atom.

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In nitryl chloride (NO2Cl), the chlorine atom and the twooxygen atoms are bonded to a central nitrogen atom, andall the atoms lie in a plane. Draw the two electron dot resonance forms that satisfy the octet rule and that together areconsistent with the fact that the two nitrogen–oxygenbonds are equivalent.
In nitryl chloride (NO2Cl), the chlorine atom and the two oxygen atoms are bonded to a central nitrogen atom, and all the atoms lie in a plane. Draw the two electron dot resonance forms that satisfy the octet rule and that together are consistent with the fact that the two nitrogen–oxygen bonds are equivalent.
Some chemists believe that satisfaction of the octet rule should be the top criterion for choosing the dominant Lewis structure of a molecule or ion. Other chemists believe that achieving the best formal charges should be the top criterion. Consider the dihydrogen phosphate ion, HaPO, , in which the H atoms are bonded to O atoms. (a) What is the predicted dominant Lewis structure if satisfying the octet rule is the top eriterion? (b) What is the predicted dominant Lewis structure if achieving the best formal charges is the top criterion?

Chapter 6 Solutions

Chemistry: Atoms First

Ch. 6.2 - Prob. 3PPBCh. 6.2 - Prob. 3PPCCh. 6.2 - Prob. 6.2.1SRCh. 6.2 - Prob. 6.2.2SRCh. 6.2 - Prob. 6.2.3SRCh. 6.2 - Prob. 6.2.4SRCh. 6.3 - Draw the Lewis structure for carbon disulfide...Ch. 6.3 - Prob. 4PPACh. 6.3 - Prob. 4PPBCh. 6.3 - Prob. 4PPCCh. 6.3 - Prob. 6.3.1SRCh. 6.3 - Prob. 6.3.2SRCh. 6.4 - The widespread use of fertilizers has resulted in...Ch. 6.4 - Prob. 5PPACh. 6.4 - Prob. 5PPBCh. 6.4 - Prob. 5PPCCh. 6.4 - Formaldehyde (CH2O), which can be used 10 preserve...Ch. 6.4 - Prob. 6PPACh. 6.4 - Prob. 6PPBCh. 6.4 - Prob. 6PPCCh. 6.4 - Prob. 6.4.1SRCh. 6.4 - Prob. 6.4.2SRCh. 6.5 - Prob. 6.7WECh. 6.5 - Prob. 7PPACh. 6.5 - Prob. 7PPBCh. 6.5 - Prob. 7PPCCh. 6.5 - Prob. 6.5.1SRCh. 6.5 - Prob. 6.5.2SRCh. 6.6 - Prob. 6.8WECh. 6.6 - Prob. 8PPACh. 6.6 - Prob. 8PPBCh. 6.6 - Prob. 8PPCCh. 6.6 - Prob. 6.9WECh. 6.6 - Prob. 9PPACh. 6.6 - Prob. 9PPBCh. 6.6 - Elements in the same group exhibit similar...Ch. 6.6 - Prob. 6.10WECh. 6.6 - Draw three resonance structures for the hydrogen...Ch. 6.6 - Draw two resonance structures for each speciesone...Ch. 6.6 - Prob. 10PPCCh. 6.6 - Prob. 6.6.1SRCh. 6.6 - Prob. 6.6.2SRCh. 6.6 - Prob. 6.6.3SRCh. 6.6 - Prob. 6.6.4SRCh. 6 - Prob. 6.1QPCh. 6 - Prob. 6.2QPCh. 6 - Prob. 6.3QPCh. 6 - Prob. 6.4QPCh. 6 - Prob. 6.5QPCh. 6 - Prob. 6.6QPCh. 6 - Prob. 6.7QPCh. 6 - Prob. 6.8QPCh. 6 - Prob. 6.9QPCh. 6 - Define electronegativity and explain the...Ch. 6 - Prob. 6.11QPCh. 6 - Prob. 6.12QPCh. 6 - Prob. 6.13QPCh. 6 - Prob. 6.14QPCh. 6 - Prob. 6.15QPCh. 6 - Prob. 6.16QPCh. 6 - Arrange the following bonds in order of increasing...Ch. 6 - Prob. 6.18QPCh. 6 - Prob. 6.19QPCh. 6 - Prob. 6.20QPCh. 6 - Prob. 6.21QPCh. 6 - Prob. 6.22QPCh. 6 - Prob. 6.23QPCh. 6 - Prob. 6.24QPCh. 6 - Prob. 6.25QPCh. 6 - Prob. 6.26QPCh. 6 - Prob. 6.27QPCh. 6 - Prob. 6.28QPCh. 6 - Prob. 6.29QPCh. 6 - Prob. 6.30QPCh. 6 - Prob. 6.31QPCh. 6 - Prob. 6.32QPCh. 6 - Prob. 6.33QPCh. 6 - Prob. 6.34QPCh. 6 - Draw all of the resonance structures for the...Ch. 6 - Prob. 6.36QPCh. 6 - Prob. 6.37QPCh. 6 - Draw three resonance structures for the molecule...Ch. 6 - Draw three reasonable resonance structures for the...Ch. 6 - Indicate which of the following are resonance...Ch. 6 - Prob. 6.41QPCh. 6 - Prob. 6.42QPCh. 6 - Draw a resonance structure of the guanine molecule...Ch. 6 - Prob. 6.44QPCh. 6 - Give three examples of compounds that do not...Ch. 6 - Prob. 6.46QPCh. 6 - Prob. 6.47QPCh. 6 - Prob. 6.48QPCh. 6 - Prob. 6.49QPCh. 6 - Prob. 6.50QPCh. 6 - Prob. 6.51QPCh. 6 - Prob. 6.52QPCh. 6 - Prob. 6.53QPCh. 6 - Draw Lewis structures for the radical species ClF2...Ch. 6 - Prob. 6.55QPCh. 6 - Prob. 6.56QPCh. 6 - Prob. 6.57QPCh. 6 - Prob. 6.58QPCh. 6 - Prob. 6.59QPCh. 6 - Prob. 6.60QPCh. 6 - Give an example of an ion or molecule containing...Ch. 6 - Prob. 6.62QPCh. 6 - Prob. 6.63QPCh. 6 - Prob. 6.64QPCh. 6 - Are the following statements true or false? (a)...Ch. 6 - Prob. 6.66QPCh. 6 - Prob. 6.67QPCh. 6 - Most organic acids can be represented as RCOOH,...Ch. 6 - Prob. 6.69QPCh. 6 - Prob. 6.70QPCh. 6 - Prob. 6.71QPCh. 6 - The following species have been detected in...Ch. 6 - Prob. 6.73QPCh. 6 - Prob. 6.74QPCh. 6 - The triiodide ion (I3) in which the I atoms are...Ch. 6 - Prob. 6.76QPCh. 6 - Prob. 6.77QPCh. 6 - The chlorine nitrate (ClONO2) molecule is believed...Ch. 6 - Prob. 6.79QPCh. 6 - For each of the following organic molecules draw a...Ch. 6 - Prob. 6.81QPCh. 6 - Draw Lewis structures for the following organic...Ch. 6 - Draw Lewis structures for the following four...Ch. 6 - Prob. 6.84QPCh. 6 - Prob. 6.85QPCh. 6 - Draw three resonance structures for (a) the...Ch. 6 - Prob. 6.87QPCh. 6 - Prob. 6.88QPCh. 6 - Prob. 6.89QPCh. 6 - Draw a Lewis structure for nitrogen pentoxide...Ch. 6 - Prob. 6.91QPCh. 6 - Nitrogen dioxide (NO2) is a stable compound....Ch. 6 - Prob. 6.93QPCh. 6 - Vinyl chloride (C2H3Cl) differs from ethylene...Ch. 6 - Prob. 6.95QPCh. 6 - Prob. 6.96QPCh. 6 - In 1999 an unusual cation containing only nitrogen...Ch. 6 - Prob. 6.98QPCh. 6 - Prob. 6.99QPCh. 6 - Electrostatic potential maps for three compounds...Ch. 6 - Which of the following atoms must always obey the...Ch. 6 - Prob. 6.2KSPCh. 6 - Prob. 6.3KSPCh. 6 - How many lone pairs are on the central atom in the...
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