Concept explainers
(a)
Interpretation:
The group of element A if its formal charge is zero should be identified.
Concept Introduction:
- A formal charge (FC) is the charge assigned to an atom in a molecule, irrespective of relative electronegativity by thinking that electrons in all
chemical bonds are shared equally among atoms. - This method is used to identify the most probable Lewis structures if more than one possibility exists for a compound.
- The Lewis structure with formal charge on each of the atoms close to zero is taken as the most plausible structure.
- Formal charge of an atom can be determined by the given formula.
To find: The group of element A it its formal charge is zero.
(b)
Interpretation:
The group of element A if its formal charge is zero should be identified.
Concept Introduction:
- A formal charge (FC) is the charge assigned to an atom in a molecule, irrespective of relative electronegativity by thinking that electrons in all chemical bonds are shared equally among atoms.
- This method is used to identify the most probable Lewis structures if more than one possibility exists for a compound.
- The Lewis structure with formal charge on each of the atoms close to zero is taken as the most plausible structure.
- Formal charge of an atom can be determined by the given formula.
To find: The group of element A it its formal charge is zero.
(c)
Interpretation:
The group of element A if its formal charge is zero should be identified.
Concept Introduction:
- A formal charge (FC) is the charge assigned to an atom in a molecule, irrespective of relative electronegativity by thinking that electrons in all chemical bonds are shared equally among atoms.
- This method is used to identify the most probable Lewis structures if more than one possibility exists for a compound.
- The Lewis structure with formal charge on each of the atoms close to zero is taken as the most plausible structure.
- Formal charge of an atom can be determined by the given formula.
To find: The group of element A it its formal charge is zero.
(d)
Interpretation:
The group of element A if its formal charge is zero should be identified.
Concept Introduction:
- A formal charge (FC) is the charge assigned to an atom in a molecule, irrespective of relative electronegativity by thinking that electrons in all chemical bonds are shared equally among atoms.
- This method is used to identify the most probable Lewis structures if more than one possibility exists for a compound.
- The Lewis structure with formal charge on each of the atoms close to zero is taken as the most plausible structure.
- Formal charge of an atom can be determined by the given formula.
To find: The group of element A it its formal charge is zero.
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Check out a sample textbook solutionChapter 6 Solutions
Chemistry: Atoms First
- A complete Lewis structure must show all nonzero formal charges. Complete each of thefollowing Lewis structures by adding any missing formal charges.arrow_forwardThe Lewis structure of acetone is Circling the carbonyl carbon, i.e., the carbon atom attached to oxygen, and its octet gives Circling the oxygen atom and its octet gives Thus, atoms share electrons in making bonds, and a pair of electrons may be included in the octet of two different atoms. When computing the formal charge on an atom, the number of electrons that belong to that atom is compared with the number of electrons the atom would have in the unbonded and neutral state. If the two numbers are the same, the formal charge on the atom is zero. In a Lewis structure both electrons in an unshared pair belong to the atom, and one of every pair of shared (bonding) electrons belongs to the atom.arrow_forwardPlease don't provide hand written solution....arrow_forward
- Draw a Lewis structure of your choice that has at least three equally reasonable resonance structures. You must show your work as to how the structure was drawn including showing valence electrons, any structures you draw that don’t work and require you to show a multiple bond, and formal charges on each atom that has a formal charge. For example, Nitrate ion has three structures (but you can’t draw this one). All three structures have formal charges and no one structure is preferred based on formal charge. Carbon dioxide would not be a valid choice. While it does have three structures, the structure that has two double bonds is the preferred structure while the structures with triple bonds are not equivalent to the double bonded version as they have multiple formal charges present.arrow_forwardPart A The Lewis structure for the chlorate ion is Calculate the formal charge on the chlorine (CI) atom. Express your answer as an integer. • View Available Hint(s) formal charge on Cl = Submit Part B Calculate the formal charge on each of the oxygen (O) atoms labeled a, b, and e in the following Lewis structure. :O: Express your answers as integers separated by commas. View Available Hint(s) formal charge on 0,, O, O, = Submitarrow_forwardDraw a Lewis diagram for BrO4- in which the central Br atom has a formal charge of zero and show all NONZERO formal charges on all atoms. Note that the overall charge on this ion is -1.arrow_forward
- II. Please expand each of the following bond-line formulas to the corresponding standard Lewis structure, be sure to show all the bonds and unshared electron pairs as well as formal charges, if it applies. 0: (a) (c) O Br | Br-B-Br -N- (b) HO: NO₂ 0: blos ohsup?arrow_forwardHello, I want the answer in clear handwriting, please. In which of the following molecules is it necessary to invoke charge-separated resonance structures in order that the central atom obeys the octet rule: (a) H2S; (b) HCN; (c) SO2; (d) AsF5; (e) [BF4]¯; (f) CO2; (g) BRF3.arrow_forwardShown here is a Lewis structure for the chlorite ion, ClO2–, that obeys the octet rule, showing all non-zero formal charges. How many resonance structures for ClO2– that obey the octet are possible? Note: Options 2 and 3 are marked wrongarrow_forward
- The molecular ion S3N, has the cyclic structure 'N All S-N bonds are equivalent. (a) Give six equivalent resonance hybrid Lewis diagrams for this molecular ion. (b) Compute the formal charges on all atoms in the molecular ion in each of the six Lewis diagrams. (c) Determine the charge on each atom in the polyatomic ion, assuming that the true distribution of electrons is the average of the six Lewis diagrams arrived at in parts (a) and (b). (d) An advanced calculation suggests that the actual charge resident on each N atom is –0.375 and on each S atom is +0.041. Show that this result is consis- tent with the overall +1 charge on the molecular ion. Z-Sarrow_forwardSome chemists believe that satisfaction of the octet rule should be the top criterion for choosing the dominant Lewis structure of a molecule or ion. Other chemists believe that achieving the best formal charges should be the top criterion. Consider the dihydrogen phosphate ion, HaPO, , in which the H atoms are bonded to O atoms. (a) What is the predicted dominant Lewis structure if satisfying the octet rule is the top eriterion? (b) What is the predicted dominant Lewis structure if achieving the best formal charges is the top criterion?arrow_forwardAlthough I3- is a known ion, F3- is not. (a) Draw the Lewis structure for I3- (it is linear, not a triangle). (b) One of your classmates says that F3 - does not exist because F is too electronegative to make bonds with another atom. Give an example that proves your classmate is wrong. (c) Another classmate says F3- does not exist because it would violate the octet rule.Is this classmate possibly correct? (d) Yet another classmatesays F3- does not exist because F is too small to make bonds tomore than one atom. Is this classmate possibly correct?arrow_forward
- Organic Chemistry: A Guided InquiryChemistryISBN:9780618974122Author:Andrei StraumanisPublisher:Cengage Learning