Concept explainers
Interpretation:
The two resonance structures of Sulphite ion (
Concept Introduction:
Octet Rule:
The octet rule states that the noble gas electron configuration is attained by the element, when the element either loses or gains or shares its atoms. The formulas for the compounds that contain specific elements can be predicted with the help of Octet rule. The octet rule holds good for those compounds that are made of elements present in second period and hence the important study on organic compounds that mainly consists of Carbon, Nitrogen and Oxygen atoms can be done with the help of Octet rule. The loss gain or sharing electrons of particular atom is dependent on properties of atoms that are determined by the number of subatomic particles inside in the atom.
Resonance:
Resonance is a method to relating to describe about delocalized electrons inside certain molecules or polyatomic ions where the Lewis structure can’t be expressed. A molecule or ion containing delocalized electrons can be represented by using several similar structures such structures are called as resonance structures or canonical structures.
The delocalization of electron lowers the potential energy of the substance and making it more stable than any of the contributing structures. The variation in the potential energy of the actual structure and that of resemblance structure with lowest potential energy is known as resonance energy or delocalization energy.
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Chemistry: Atoms First
- Consider the pyrosulfate ion, S2O72-. It has no sulfur–sulfur nor oxygen–oxygen bonds. (a) Write a Lewis structure for the pyrosulfate ion using only single bonds. (b) What is the formal charge on the sulfur atoms for the Lewis structure you drew in part (a)? (c) Write another Lewis structure using six bonds and two O—S bonds. (d) What is the formal charge on each atom for the structure you drew in part (c)?arrow_forwardBond Enthalpy When atoms of the hypothetical element X are placed together, they rapidly undergo reaction to form the X2 molecule: X(g)+X(g)X2(g) a Would you predict that this reaction is exothermic or endothermic? Explain. b Is the bond enthalpy of X2 a positive or a negative quantity? Why? c Suppose H for the reaction is 500 kJ/mol. Estimate the bond enthalpy of the X2 molecule. d Another hypothetical molecular compound, Y2(g), has a bond enthalpy of 750 kJ/mol, and the molecular compound XY(g) has a bond enthalpy of 1500 kJ/mol. Using bond enthalpy information, calculate H for the following reaction. X2(g)+Y2(g)2XY(g) e Given the following information, as well as the information previously presented, predict whether or not the hypothetical ionic compound AX is likely to form. In this compound, A forms the A+ cation, and X forms the X anion. Be sure to justify your answer. Reaction: A(g)+12X2(g)AX(s)The first ionization energy of A(g) is 400 kJ/mol. The electron affinity of X(g) is 525 kJ/mol. The lattice energy of AX(s) is 100 kJ/mol. f If you predicted that no ionic compound would form from the reaction in Part e, what minimum amount of AX(s) lattice energy might lead to compound formation?arrow_forwardWrite the Lewis structure for nitrosyl fluoride, FNO. Using only a periodic table, identify (a) which is the longer bond. (b) which is the stronger bond. (c) which is the more polar bond.arrow_forward
- For each of the following, use formal charges to choose the Lewis formula that gives the best description of the electron distribution: a ClO2F b SO2 c ClO3arrow_forwardDraw resonance structures for each of these ions: NSO− and SNO−. (The atoms are bonded in the order given in each case, that is, S is the central atom in NSO−.) Use formal charges to determine which ion is likely to be more stable. Explain why the two ions cannot be considered resonance structures of each other.arrow_forwardDraw resonance formulas of the phosphoric acid molecule, (HO)3PO. Obtain formal charges for the atoms in these resonance formulas. From this result, which resonance formula would you expect to most closely approximate the actual electron distribution?arrow_forward
- Write reasonable Lewis structures for the following species, none of which follow the octet rule. (a) BF3 (b) NO (c) CO+ (d) ClO3arrow_forwardWrite reasonable Lewis structures for the following species, none of which follow the octet rule. (a) BeCl2 (b) SeO2- (c) ClO3 (d) CH3arrow_forwardTwo Lewis structures can be written for nitrosyl fluoride, which contains one nitrogen, one oxygen, and one fluorine atom per molecule. Write the two Lewis structures land assign a formal charge to each atom.arrow_forward
- Draw a Lewis structure for SO2Cl2 in which the octet rule is satisfied on all atoms and show all NONZERO formal charges on all atoms.arrow_forwardThe azide ion, N, is a symmetrical ion, in which all of the possible Lewis structures have formal charge on one or more atoms. Draw three possible Lewis structures for this ion. Draw the molecule by placing atoms on the grid and connecting them with bonds. Include all nonbonding electrons. Show the formal charges of all atoms. Q NNNITY ¤•• Q Submit Q NENN N=N-N² N²NN с H O N S P F Br CI X Type the new charge. Press ENTER to finish editing. Press TAB to go through atoms in the structure. Previous Answers Request Answer X Incorrect; Try Again; One attempt remaining Morearrow_forwardA student proposes the following Lewis structure for the isocyanate NCO− ion. Assign a formal charge to each atom in the student's Lewis structure.arrow_forward
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