(a) Interpretation: Why the greater contribution, from the second of the two resonance structures shown, is counterintuitive based on charge stability is to be explained. Concept introduction: The relative stabilities of resonance structures can be determined on the basis of charge stability. The structure with positive charge on less electronegative atom and negative charge on more electronegative atom is more stable. The most stable resonance structure contributes more to the resonance hybrid.

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Answer 1

Question

Chapter 6, Problem 6.29P

Interpretation Introduction

(a)

Interpretation:

Why the greater contribution, from the second of the two resonance structures shown, is counterintuitive based on charge stability is to be explained.

Concept introduction:

The relative stabilities of resonance structures can be determined on the basis of charge stability. The structure with positive charge on less electronegative atom and negative charge on more electronegative atom is more stable. The most stable resonance structure contributes more to the resonance hybrid.

Interpretation Introduction

(b)

Interpretation:

The greater contribution from the second resonance structure is to be explained.

Concept introduction:

The most stable resonance structure contributes most to the hybrid.

Stability of a resonance structure depends on a number of factors. More the number of bonds, more the number of atoms that follow the octet or the duet rule and less the number of formal charge, the more stable the structure.

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Commercial bleach contains either chlorine or oxygen as an active ingredient. A commercial oxygenated bleach is much safer to handle and less likely to ruin your clothes. It is possible to determine the amount of active ingredient in an oxygenated bleach product by performing a redox titration. The balance reaction for such a titration is: 6H+ +5H2O2 +2MnO4- à 5O2 + 2Mn2+ + 8H2O If you performed the following procedure: “First, dilute the Seventh Generation Non-Chlorine Bleach by pipetting 10 mL of bleach in a 100 mL volumetric flask and filling the flask to the mark with distilled water. Next, pipet 10 mL of the diluted bleach solution into a 250 mL Erlenmeyer flask and add 20 mL of 1.0 M H2SO4 to the flask. This solution should be titrated with 0.0100 M KMnO4 solution.” It took 18.47mL of the KMnO4 to reach the endpoint on average. What was the concentration of H2O2 in the original bleach solution in weight % assuming the density of bleach is 1g/mL?

10.

Proper care of pH electrodes: Why can you not store a pH electrode in distilled water? What must you instead store it in? Why?

Answer 2

Question

Chapter 6, Problem 6.29P

Interpretation Introduction

(a)

Interpretation:

Why the greater contribution, from the second of the two resonance structures shown, is counterintuitive based on charge stability is to be explained.

Concept introduction:

The relative stabilities of resonance structures can be determined on the basis of charge stability. The structure with positive charge on less electronegative atom and negative charge on more electronegative atom is more stable. The most stable resonance structure contributes more to the resonance hybrid.

Interpretation Introduction

(b)

Interpretation:

The greater contribution from the second resonance structure is to be explained.

Concept introduction:

The most stable resonance structure contributes most to the hybrid.

Stability of a resonance structure depends on a number of factors. More the number of bonds, more the number of atoms that follow the octet or the duet rule and less the number of formal charge, the more stable the structure.

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Answer 3

Question

Chapter 6, Problem 6.29P

Interpretation Introduction

(a)

Interpretation:

Why the greater contribution, from the second of the two resonance structures shown, is counterintuitive based on charge stability is to be explained.

Concept introduction:

The relative stabilities of resonance structures can be determined on the basis of charge stability. The structure with positive charge on less electronegative atom and negative charge on more electronegative atom is more stable. The most stable resonance structure contributes more to the resonance hybrid.

Interpretation Introduction

(b)

Interpretation:

The greater contribution from the second resonance structure is to be explained.

Concept introduction:

The most stable resonance structure contributes most to the hybrid.

Stability of a resonance structure depends on a number of factors. More the number of bonds, more the number of atoms that follow the octet or the duet rule and less the number of formal charge, the more stable the structure.

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Answer 4

Question

Chapter 6, Problem 6.29P

Interpretation Introduction

(a)

Interpretation:

Why the greater contribution, from the second of the two resonance structures shown, is counterintuitive based on charge stability is to be explained.

Concept introduction:

The relative stabilities of resonance structures can be determined on the basis of charge stability. The structure with positive charge on less electronegative atom and negative charge on more electronegative atom is more stable. The most stable resonance structure contributes more to the resonance hybrid.

Interpretation Introduction

(b)

Interpretation:

The greater contribution from the second resonance structure is to be explained.

Concept introduction:

The most stable resonance structure contributes most to the hybrid.

Stability of a resonance structure depends on a number of factors. More the number of bonds, more the number of atoms that follow the octet or the duet rule and less the number of formal charge, the more stable the structure.

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Answer 5

Chapter 6, Problem 6.29P

Interpretation Introduction

(a)

Interpretation:

Why the greater contribution, from the second of the two resonance structures shown, is counterintuitive based on charge stability is to be explained.

Concept introduction:

The relative stabilities of resonance structures can be determined on the basis of charge stability. The structure with positive charge on less electronegative atom and negative charge on more electronegative atom is more stable. The most stable resonance structure contributes more to the resonance hybrid.

Interpretation Introduction

(b)

Interpretation:

The greater contribution from the second resonance structure is to be explained.

Concept introduction:

The most stable resonance structure contributes most to the hybrid.

Stability of a resonance structure depends on a number of factors. More the number of bonds, more the number of atoms that follow the octet or the duet rule and less the number of formal charge, the more stable the structure.

Answer 6

Chapter 6, Problem 6.29P

Interpretation Introduction

(a)

Interpretation:

Why the greater contribution, from the second of the two resonance structures shown, is counterintuitive based on charge stability is to be explained.

Concept introduction:

The relative stabilities of resonance structures can be determined on the basis of charge stability. The structure with positive charge on less electronegative atom and negative charge on more electronegative atom is more stable. The most stable resonance structure contributes more to the resonance hybrid.

Answer 7

Chapter 6, Problem 6.29P

Interpretation Introduction

(a)

Interpretation:

Why the greater contribution, from the second of the two resonance structures shown, is counterintuitive based on charge stability is to be explained.

Concept introduction:

The relative stabilities of resonance structures can be determined on the basis of charge stability. The structure with positive charge on less electronegative atom and negative charge on more electronegative atom is more stable. The most stable resonance structure contributes more to the resonance hybrid.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The greater contribution from the second resonance structure is to be explained.

Concept introduction:

The most stable resonance structure contributes most to the hybrid.

Stability of a resonance structure depends on a number of factors. More the number of bonds, more the number of atoms that follow the octet or the duet rule and less the number of formal charge, the more stable the structure.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The greater contribution from the second resonance structure is to be explained.

Concept introduction:

The most stable resonance structure contributes most to the hybrid.

Stability of a resonance structure depends on a number of factors. More the number of bonds, more the number of atoms that follow the octet or the duet rule and less the number of formal charge, the more stable the structure.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 6 - Prob. 6.1P Ch. 6 - Prob. 6.2P Ch. 6 - Prob. 6.3P Ch. 6 - Prob. 6.4P Ch. 6 - Prob. 6.5P Ch. 6 - Prob. 6.6P Ch. 6 - Prob. 6.7P Ch. 6 - Prob. 6.8P Ch. 6 - Prob. 6.9P Ch. 6 - Prob. 6.10P

Solution Summary: The author explains why the greater contribution from the second resonance structure is counterintuitive based on charge stability.

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