Chemistry: Atoms First
2nd Edition
ISBN: 9780073511184
Author: Julia Burdge, Jason Overby Professor
Publisher: McGraw-Hill Education
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Chapter 5, Problem 5.72QP
Interpretation Introduction
Interpretation: By using dinitrogen monoxide
Concept introduction: Percent composition by mass of each element present in a compound is known as the compound’s percent composition by mass.
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Identifying electron-donating and electron-withdrawing effects on benzene
For each of the substituted benzene molecules below, determine the inductive and resonance effects the substituent will have on the
benzene ring, as well as the overall electron-density of the ring compared to unsubstituted benzene.
Inductive Effects
Resonance Effects
Overall Electron-Density
Molecule
CF3
O donating
O donating
O withdrawing
O withdrawing
O no inductive effects
O no resonance effects
electron-rich
electron-deficient
O similar to benzene
CH3
O donating
O withdrawing
O no inductive effects
O donating
O withdrawing
Ono resonance effects
O electron-rich
O electron-deficient
O similar to benzene
Explanation
Check
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* Hint: Think back to Chem 1 solubility rules.
Follow Up Questions for Part B
12. What impact do the following disturbances to a system at equilibrium have on k, the rate constant
for the forward reaction? Explain. (4 pts)
a) Changing the concentration of a reactant or product. (2 pts)
b) Changing the temperature of an exothermic reaction. (2 pts)
of
Draw TWO general chemical equation to prepare Symmetrical and non-Symmetrical ethers
Draw 1 chemical reaction of an ether
Chapter 5 Solutions
Chemistry: Atoms First
Ch. 5.2 - Write Lewis dot symbols for (a) fluoride ion (F),...Ch. 5.2 - Write Lewis dot symbols for (a) Ca2+, (b) N3 and...Ch. 5.2 - Indicate the charge on each of the ions...Ch. 5.2 - Prob. 1PPCCh. 5.2 - Prob. 5.2.1SRCh. 5.2 - Prob. 5.2.2SRCh. 5.2 - Prob. 5.2.3SRCh. 5.2 - Prob. 5.2.4SRCh. 5.3 - Arrange MgO, CaO, and SrO in order of increasing...Ch. 5.3 - Prob. 2PPA
Ch. 5.3 - Arrange the compounds NaF, MgO, and AlN in order...Ch. 5.3 - Prob. 2PPCCh. 5.3 - Prob. 5.3.1SRCh. 5.3 - Prob. 5.3.2SRCh. 5.4 - Prob. 5.3WECh. 5.4 - Prob. 3PPACh. 5.4 - Prob. 3PPBCh. 5.4 - Prob. 3PPCCh. 5.4 - Prob. 5.4WECh. 5.4 - Prob. 4PPACh. 5.4 - Prob. 4PPBCh. 5.4 - Prob. 4PPCCh. 5.4 - Prob. 5.4.1SRCh. 5.4 - Prob. 5.4.2SRCh. 5.4 - Prob. 5.4.3SRCh. 5.4 - Prob. 5.4.4SRCh. 5.5 - Prob. 5.5WECh. 5.5 - Prob. 5PPACh. 5.5 - Draw (a) a space-filling molecular model of carbon...Ch. 5.5 - Prob. 5PPCCh. 5.5 - Prob. 5.6WECh. 5.5 - Prob. 6PPACh. 5.5 - Prob. 6PPBCh. 5.5 - Prob. 6PPCCh. 5.5 - Prob. 5.5.1SRCh. 5.5 - Prob. 5.5.2SRCh. 5.6 - Name the following binary molecular compounds: (a)...Ch. 5.6 - Prob. 7PPACh. 5.6 - Prob. 7PPBCh. 5.6 - Prob. 7PPCCh. 5.6 - Prob. 5.8WECh. 5.6 - Give the molecular formula for each of the...Ch. 5.6 - Prob. 8PPBCh. 5.6 - Draw a molecular model of sulfur trioxide.Ch. 5.6 - Prob. 5.6.1SRCh. 5.6 - Prob. 5.6.2SRCh. 5.6 - Prob. 5.6.3SRCh. 5.6 - Prob. 5.6.4SRCh. 5.7 - Prob. 5.9WECh. 5.7 - Name the following ionic compounds: (a) Na2SO4,...Ch. 5.7 - Prob. 9PPBCh. 5.7 - Prob. 9PPCCh. 5.7 - Name the following species: (a) BrO4, (b) HCO3,...Ch. 5.7 - Prob. 10PPACh. 5.7 - Prob. 10PPBCh. 5.7 - Prob. 10PPCCh. 5.7 - Prob. 5.11WECh. 5.7 - Prob. 11PPACh. 5.7 - Prob. 11PPBCh. 5.7 - Prob. 11PPCCh. 5.7 - Prob. 5.7.1SRCh. 5.7 - Prob. 5.7.2SRCh. 5.7 - Prob. 5.7.3SRCh. 5.7 - Prob. 5.7.4SRCh. 5.8 - Calculate the molecular mass or the formula mass,...Ch. 5.8 - Calculate the molecular or formula mass of each of...Ch. 5.8 - Prob. 12PPBCh. 5.8 - Prob. 12PPCCh. 5.8 - Prob. 5.8.1SRCh. 5.8 - Prob. 5.8.2SRCh. 5.8 - Prob. 5.8.3SRCh. 5.8 - Prob. 5.8.4SRCh. 5.8 - Prob. 5.8.5SRCh. 5.8 - Prob. 5.8.6SRCh. 5.9 - Prob. 5.13WECh. 5.9 - Prob. 13PPACh. 5.9 - Prob. 13PPBCh. 5.9 - Prob. 13PPCCh. 5.9 - Prob. 5.9.1SRCh. 5.9 - Prob. 5.9.2SRCh. 5.10 - Prob. 5.14WECh. 5.10 - Prob. 14PPACh. 5.10 - Prob. 14PPBCh. 5.10 - Prob. 5.15WECh. 5.10 - Prob. 15PPACh. 5.10 - Prob. 15PPBCh. 5.10 - Prob. 15PPCCh. 5.10 - Prob. 5.16WECh. 5.10 - Prob. 16PPACh. 5.10 - Prob. 16PPBCh. 5.10 - Prob. 16PPCCh. 5.10 - Prob. 5.10.1SRCh. 5.10 - Prob. 5.10.2SRCh. 5.10 - Prob. 5.10.3SRCh. 5.10 - Prob. 5.10.4SRCh. 5 - Define the term compound and explain how a...Ch. 5 - Prob. 5.2QPCh. 5 - Prob. 5.3QPCh. 5 - Prob. 5.4QPCh. 5 - Use the second member of each group from Group 1A...Ch. 5 - Without referring to Figure 5.1, write Lewis dot...Ch. 5 - Prob. 5.7QPCh. 5 - Indicate the charge on each of the ions...Ch. 5 - To what group of the periodic table does element X...Ch. 5 - Explain what ionic bonding is.Ch. 5 - Prob. 5.11QPCh. 5 - Prob. 5.12QPCh. 5 - Prob. 5.13QPCh. 5 - Prob. 5.14QPCh. 5 - Prob. 5.15QPCh. 5 - Prob. 5.16QPCh. 5 - Prob. 5.17QPCh. 5 - Prob. 5.18QPCh. 5 - Prob. 5.19QPCh. 5 - Explain why the chemical formulas of ionic...Ch. 5 - Prob. 5.21QPCh. 5 - Give the formulas and names of the compounds...Ch. 5 - Prob. 5.23QPCh. 5 - Prob. 5.24QPCh. 5 - Prob. 5.25QPCh. 5 - Prob. 5.26QPCh. 5 - Prob. 5.27QPCh. 5 - Prob. 5.28QPCh. 5 - Prob. 5.29QPCh. 5 - Prob. 5.30QPCh. 5 - Prob. 5.31QPCh. 5 - Prob. 5.32QPCh. 5 - Prob. 5.33QPCh. 5 - Sulfur reacts with fluorine to produce three...Ch. 5 - Prob. 5.35QPCh. 5 - Prob. 5.36QPCh. 5 - Prob. 5.37QPCh. 5 - Prob. 5.38QPCh. 5 - Give an example of a case in which two molecules...Ch. 5 - Prob. 5.40QPCh. 5 - Prob. 5.41QPCh. 5 - Prob. 5.42QPCh. 5 - Identify the following as elements or compounds:...Ch. 5 - Prob. 5.44QPCh. 5 - Prob. 5.45QPCh. 5 - Prob. 5.46QPCh. 5 - Prob. 5.47QPCh. 5 - Prob. 5.48QPCh. 5 - Prob. 5.49QPCh. 5 - Describe how the naming of molecular binary...Ch. 5 - Define the term acid.Ch. 5 - Prob. 5.52QPCh. 5 - Prob. 5.53QPCh. 5 - Prob. 5.54QPCh. 5 - Prob. 5.55QPCh. 5 - Prob. 5.56QPCh. 5 - Prob. 5.57QPCh. 5 - Prob. 5.58QPCh. 5 - Prob. 5.59QPCh. 5 - Prob. 5.60QPCh. 5 - Prob. 5.61QPCh. 5 - Prob. 5.62QPCh. 5 - Prob. 5.63QPCh. 5 - Prob. 5.64QPCh. 5 - Prob. 5.65QPCh. 5 - Prob. 5.66QPCh. 5 - Prob. 5.67QPCh. 5 - Prob. 5.68QPCh. 5 - Prob. 5.69QPCh. 5 - Prob. 5.70QPCh. 5 - Prob. 5.71QPCh. 5 - Prob. 5.72QPCh. 5 - Prob. 5.73QPCh. 5 - Prob. 5.74QPCh. 5 - Prob. 5.75QPCh. 5 - Prob. 5.76QPCh. 5 - Prob. 5.77QPCh. 5 - Prob. 5.78QPCh. 5 - All the substances listed here are fertilizers...Ch. 5 - Prob. 5.80QPCh. 5 - Molar mass is numerically equivalent to molecular...Ch. 5 - Prob. 5.82QPCh. 5 - Prob. 5.83QPCh. 5 - Prob. 5.84QPCh. 5 - Prob. 5.85QPCh. 5 - Prob. 5.86QPCh. 5 - Prob. 5.87QPCh. 5 - The density of water is 1.00 g/mL at 4C. How many...Ch. 5 - Cinnamic alcohol is used to add a pleasant scent...Ch. 5 - The chemical formula for rust can be represented...Ch. 5 - Prob. 5.91QPCh. 5 - Prob. 5.92QPCh. 5 - Prob. 5.93QPCh. 5 - Prob. 5.94QPCh. 5 - Equilin is an estrogen isolated from the urine of...Ch. 5 - Prob. 5.96QPCh. 5 - Prob. 5.97QPCh. 5 - Prob. 5.98QPCh. 5 - Prob. 5.99QPCh. 5 - Prob. 5.100QPCh. 5 - What is wrong with or ambiguous about the phrase...Ch. 5 - Prob. 5.102QPCh. 5 - Prob. 5.103QPCh. 5 - Prob. 5.104QPCh. 5 - Ethane and acetylene are two gaseous hydrocarbons....Ch. 5 - Prob. 5.106QPCh. 5 - Prob. 5.107QPCh. 5 - Prob. 5.108QPCh. 5 - Prob. 5.109QPCh. 5 - Prob. 5.110QPCh. 5 - Prob. 5.111QPCh. 5 - Determine the molecular and empirical formulas of...Ch. 5 - Prob. 5.113QPCh. 5 - Prob. 5.114QPCh. 5 - Prob. 5.115QPCh. 5 - Prob. 5.116QPCh. 5 - Prob. 5.117QPCh. 5 - Prob. 5.118QPCh. 5 - Prob. 5.119QPCh. 5 - Prob. 5.120QPCh. 5 - Prob. 5.121QPCh. 5 - Prob. 5.122QPCh. 5 - Prob. 5.123QPCh. 5 - Prob. 5.124QPCh. 5 - Prob. 5.125QPCh. 5 - Prob. 5.126QPCh. 5 - Prob. 5.127QPCh. 5 - The compound 2,3-dimercaptopropanol...Ch. 5 - Prob. 5.129QPCh. 5 - Prob. 5.130QPCh. 5 - Prob. 5.131QPCh. 5 - Prob. 5.132QPCh. 5 - Calculate the number of cations and anions in each...Ch. 5 - Calculate the percent composition by mass of all...Ch. 5 - Prob. 5.135QPCh. 5 - Prob. 5.136QPCh. 5 - Prob. 5.137QPCh. 5 - Prob. 5.138QPCh. 5 - Prob. 5.1KSPCh. 5 - Prob. 5.2KSPCh. 5 - Prob. 5.3KSPCh. 5 - Prob. 5.4KSP
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- Rank each of the following substituted benzene molecules in order of which will react fastest (1) to slowest (4) by electrophilic aromatic substitution. OCH 3 (Choose one) OH (Choose one) Br (Choose one) Explanation Check NO2 (Choose one) © 2025 McGraw Hill LLC. All Rights Reserved. Terms of Use | Privacy Center | Aarrow_forwardFor each of the substituted benzene molecules below, determine the inductive and resonance effects the substituent will have on the benzene ring, as well as the overall electron-density of the ring compared to unsubstituted benzene. Molecule Inductive Effects O donating O withdrawing O no inductive effects Resonance Effects Overall Electron-Density ○ donating ○ withdrawing O no resonance effects O electron-rich O electron-deficient O similar to benzene Cl O donating O withdrawing ○ donating ○ withdrawing O no inductive effects O no resonance effects O Explanation Check O electron-rich O electron-deficient similar to benzene X © 2025 McGraw Hill LLC. All Rights Reserved. Terms of Use | Privacy Center | Accessarrow_forwardIdentifying electron-donating and For each of the substituted benzene molecules below, determine the inductive and resonance effects the substituent will have on the benzene ring, as well as the overall electron-density of the ring compared to unsubstituted benzene. Molecule Inductive Effects NH2 ○ donating NO2 Explanation Check withdrawing no inductive effects Resonance Effects Overall Electron-Density ○ donating O withdrawing O no resonance effects O donating O withdrawing O donating withdrawing O no inductive effects Ono resonance effects O electron-rich electron-deficient O similar to benzene O electron-rich O electron-deficient O similar to benzene olo 18 Ar 2025 McGraw Hill LLC. All Rights Reserved. Terms of Use | Privacy Center | Accessibilityarrow_forward
- Rank each of the following substituted benzene molecules in order of which will react fastest (1) to slowest (4) by electrophilic aromatic substitution. Explanation Check Х (Choose one) OH (Choose one) OCH3 (Choose one) OH (Choose one) © 2025 McGraw Hill LLC. All Rights Reserved. Terms of Use | Privacy Centerarrow_forwardAssign R or S to all the chiral centers in each compound drawn below porat bg 9 Br Brarrow_forwarddescrive the energy levels of an atom and howan electron moces between themarrow_forward
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