ORGANIC CHEMISTRY-PACKAGE >CUSTOM<
10th Edition
ISBN: 9781260028355
Author: Carey
Publisher: MCG CUSTOM
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Question
Chapter 5, Problem 33P
Interpretation Introduction
Interpretation:
The chemical equation of primary alcoholwith each of the given reagents is to be written.
Concept Introduction:
When alcohol treated with hydrogen halide typically undergoes nucleophilic substitution reaction to yield
Primary alcohol proceeds via
Alcohol reacts with sodium azide to yield sodium alkonate.
Alcohol reacts with sodium bromide in the presence of sulfuric acid and heat to yield alkyl halide.
When three moles of alcohol reacts with phosphorus tribromide to yield alkyl halide with phosphorous acid and hydrogen bromide.
When alcohols treated with thionyl chlorides react to yield alkyl chloride with sulfur dioxide and hydrogen chloride.
When alcohols treated with methyl sulfonyl chloride in the presence of pyridine react to yield butyl methanesulfonate.
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Terpineol has 5 isomers. Write their structures and describe why chemically (optically) they receive those names. Number the carbons for a better description.
A student is given a mixture of benzoic acid, 3-nitroaniline and naphthalene to separate. The student dissolves the mixture in an organic solvent and adds NaOH to the solution. Two layers form. Which component(s) of the mixture remain in the organic solvent?
Group of answer choices
Benzoic acid and Naphthalene
3-Nitroaniline and naphthalene
3-Nitroaniline
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Hydration of aldehydes and ketones can be catalyzed by acid
or base. Bases catalyze hydration by:
protonating the carbonyl oxygen
making the carbonyl group more electrophilic
employing hydroxide ion, which is a better nucleophile than water
making the carbonyl group less electrophilic
shifting the equilibrium position of the reaction to favor products
Chapter 5 Solutions
ORGANIC CHEMISTRY-PACKAGE >CUSTOM<
Ch. 5.1 - Prob. 1PCh. 5.1 - Prob. 2PCh. 5.1 - Many compounds contain more than one functional...Ch. 5.2 - Prob. 4PCh. 5.3 - Prob. 5PCh. 5.4 - Classify the isomeric C4H10O alcohols as being...Ch. 5.5 - Bromine is less electronegative than chlorine, yet...Ch. 5.6 - Prob. 8PCh. 5.7 - Prob. 9PCh. 5.8 - Prob. 10P
Ch. 5.8 - Prob. 11PCh. 5.9 - Carbocations are key intermediates in petroleum...Ch. 5.9 - Prob. 13PCh. 5.9 - Prob. 14PCh. 5.11 - Prob. 15PCh. 5.13 - Prob. 16PCh. 5.14 - For the reaction of a primary alcohol RCH2OH with...Ch. 5.15 - Prob. 18PCh. 5 - Write structural formulas for each of the...Ch. 5 - Prob. 20PCh. 5 - Prob. 21PCh. 5 - Write structural formulas for all the...Ch. 5 - Prob. 23PCh. 5 - Prob. 24PCh. 5 - Epichlorohydrin is the common name of an...Ch. 5 - Prob. 26PCh. 5 - Prob. 27PCh. 5 - Prob. 28PCh. 5 - Some of the most important organic compounds in...Ch. 5 - Prob. 30PCh. 5 - Prob. 31PCh. 5 - Prob. 32PCh. 5 - Prob. 33PCh. 5 - Prob. 34PCh. 5 - Prob. 35PCh. 5 - Prob. 36PCh. 5 - Prob. 37PCh. 5 - Prob. 38PCh. 5 - Prob. 39PCh. 5 - Prob. 40PCh. 5 - The reaction of 2,2-dimethyl-1-propanol...Ch. 5 - (a) Assuming that the rate-determining elementary...Ch. 5 - The reaction of 3-tert-butyl-3-pentanol with...Ch. 5 - Prob. 44PCh. 5 - Prob. 45PCh. 5 - Prob. 46DSPCh. 5 - Prob. 47DSPCh. 5 - Prob. 48DSPCh. 5 - Prob. 49DSPCh. 5 - Prob. 50DSPCh. 5 - Prob. 51DSPCh. 5 - Prob. 52DSP
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- 14-31 Compare the acidity of alcohols and phenols, which are both classes of organic compounds that contain an —OH group.arrow_forward17-60 1-Propanol can be prepared by the reduction of an aldehyde, but it cannot be prepared by the acid catalyzed hydration of an alkene. Explain why it cannot be prepared from an alkene.arrow_forwardDraw structural formulas for the following entities. a. Propanoate ion b. Sodium propanoate c. Acetate ion d. Sodium acetatearrow_forward
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