Introductory Chemistry: A Foundation
9th Edition
ISBN: 9781337399425
Author: Steven S. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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Chapter 5, Problem 11CR
What are bus? How are ions formed from atoms? Do isolated atoms form ions spontaneously? To what do the termscationandanionrefer? In terms of subatomic particles, how is an ion related to the atom from which it is formed? Does the nucleus of an atom change when the atom is converted into an ion? How can the periodic table be used to predict what ion an element’s atoms will form?
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Part I.
Draw reaction mechanism for the transformations of benzophenone to benzopinacol to benzopinaco lone and answer the ff:
Pinacol (2,3-dimethyl, 1-3-butanediol) on treatment w/ acid gives a mixture of pina colone
and
(3,3-dimethyl-2-butanone) 2,3-dimethyl-1,3-butadiene. Give reasonable mechanism
the formation of the products
For
Show the mechanism for these reactions
Draw the stepwise mechanism
Chapter 5 Solutions
Introductory Chemistry: A Foundation
Ch. 5.2 - Exercise 5.1 Name the following compounds....Ch. 5.2 - Prob. 1CTCh. 5.2 - Exercise 5.2 Give the names of the following...Ch. 5.3 - Exercise 5.3 Name the following compounds....Ch. 5.3 - Exercise 5.4 Name the following compounds....Ch. 5.4 - Exercise 5.5 Name the following binary compounds....Ch. 5.5 - Exercise 5.6 Name each of the following compounds....Ch. 5.5 - Exercise 5.7 Name the following compounds....Ch. 5.7 - Prob. 1CTCh. 5.7 - Prob. 5.8SC
Ch. 5 - In some cases the Roman numeral in a name is the...Ch. 5 - Prob. 2ALQCh. 5 - The formulas MgO and CO look very similar. What is...Ch. 5 - Explain how to use the periodic table to determine...Ch. 5 - Prob. 5ALQCh. 5 - Prob. 6ALQCh. 5 - Name each of the following compounds. SO5 P2S5Ch. 5 - Why do we callBa(NO3)2 barium nitrate hut...Ch. 5 - What is the difference between sulfuric acid and...Ch. 5 - The “Chemistry in Focus” segment Sugar of Lead...Ch. 5 - Prob. 2QAPCh. 5 - Prob. 3QAPCh. 5 - Prob. 4QAPCh. 5 - Prob. 5QAPCh. 5 - Prob. 6QAPCh. 5 - Prob. 7QAPCh. 5 - We indicate the charge of a metallic element that...Ch. 5 - Prob. 9QAPCh. 5 - Prob. 10QAPCh. 5 - Prob. 11QAPCh. 5 - Prob. 12QAPCh. 5 - Prob. 13QAPCh. 5 - Prob. 14QAPCh. 5 - Prob. 15QAPCh. 5 - Prob. 16QAPCh. 5 - Write the name of each of the following binary...Ch. 5 - Write the name for each of the following binary...Ch. 5 - Name each of the following binary compounds, using...Ch. 5 - The formulasNa2O andN2O look very similar. What is...Ch. 5 - Name each of the following binary compounds, using...Ch. 5 - Name each of the following binary compounds, using...Ch. 5 - What is apolyatomicion? Give examples of five...Ch. 5 - Prob. 24QAPCh. 5 - Prob. 25QAPCh. 5 - Prob. 26QAPCh. 5 - Prob. 27QAPCh. 5 - Prob. 28QAPCh. 5 - Prob. 29QAPCh. 5 - Prob. 30QAPCh. 5 - Prob. 31QAPCh. 5 - Prob. 32QAPCh. 5 - Give the name of each of the following polyatomic...Ch. 5 - Prob. 34QAPCh. 5 - Prob. 35QAPCh. 5 - Prob. 36QAPCh. 5 - Give a simple definition of anacid.Ch. 5 - Prob. 38QAPCh. 5 - Prob. 39QAPCh. 5 - Prob. 40QAPCh. 5 - Prob. 41QAPCh. 5 - Prob. 42QAPCh. 5 - Prob. 43QAPCh. 5 - Prob. 44QAPCh. 5 - Prob. 45QAPCh. 5 - Prob. 46QAPCh. 5 - Prob. 47QAPCh. 5 - Prob. 48QAPCh. 5 - Prob. 49QAPCh. 5 - Prob. 50QAPCh. 5 - Prob. 51APCh. 5 - Prob. 52APCh. 5 - Prob. 53APCh. 5 - Prob. 54APCh. 5 - Prob. 55APCh. 5 - Prob. 56APCh. 5 - Name the following compounds. Ca(C2H3O2)2 PCl3...Ch. 5 - Prob. 58APCh. 5 - Prob. 59APCh. 5 - Prob. 60APCh. 5 - Most metallic elements formoxides, and often the...Ch. 5 - Consider a hypothetical simple ionDetermine the...Ch. 5 - Prob. 63APCh. 5 - A metal ion with a 2+ charge has 23 electrons and...Ch. 5 - Prob. 65APCh. 5 - Prob. 66APCh. 5 - The noble metals gold, silver, and platinum are...Ch. 5 - Prob. 68APCh. 5 - The elements of Group 7 (fluorine, chlorine,...Ch. 5 - Prob. 70APCh. 5 - Prob. 71APCh. 5 - An ion with one less electron than it has protons...Ch. 5 - An atom that has lost three electrons will have a...Ch. 5 - An ion with two more electrons than it has protons...Ch. 5 - For each of the negative ions listed in column 1,...Ch. 5 - For each of the following processes that show the...Ch. 5 - For each of the following atomic numbers, use the...Ch. 5 - For the following pairs of ions, use the principle...Ch. 5 - Prob. 79APCh. 5 - Prob. 80APCh. 5 - Prob. 81APCh. 5 - Prob. 82APCh. 5 - Prob. 83APCh. 5 - Name each of the following compounds....Ch. 5 - Prob. 85APCh. 5 - Prob. 86APCh. 5 - Write the foḿu1a for each of the following...Ch. 5 - Give the name of each of the following polyatomic...Ch. 5 - Prob. 89APCh. 5 - Prob. 90APCh. 5 - Prob. 91APCh. 5 - Prob. 92APCh. 5 - Prob. 93APCh. 5 - Complete the following table to predict whether...Ch. 5 - Prob. 95CPCh. 5 - Prob. 96CPCh. 5 - Prob. 97CPCh. 5 - Prob. 98CPCh. 5 - Prob. 1CRCh. 5 - Prob. 2CRCh. 5 - Prob. 3CRCh. 5 - Without consulting your textbook or notes, state...Ch. 5 - Prob. 5CRCh. 5 - What is meant by anuclear atom? Describe the...Ch. 5 - Prob. 7CRCh. 5 - Prob. 8CRCh. 5 - Prob. 9CRCh. 5 - Are most elements found in nature in the elemental...Ch. 5 - What are bus? How are ions formed from atoms? Do...Ch. 5 - Prob. 12CRCh. 5 - Prob. 13CRCh. 5 - Prob. 14CRCh. 5 - Prob. 15CRCh. 5 - Prob. 16CRCh. 5 - Prob. 17CRCh. 5 - Prob. 18CRCh. 5 - Prob. 19CRCh. 5 - Prob. 20CRCh. 5 - Prob. 21CRCh. 5 - How many electrons, protons, and neutrons are...Ch. 5 - What simple ion does each of the following...Ch. 5 - Prob. 24CRCh. 5 - Prob. 25CRCh. 5 - Prob. 26CRCh. 5 - Prob. 27CRCh. 5 - Prob. 28CRCh. 5 - Prob. 29CRCh. 5 - Prob. 30CRCh. 5 - Prob. 31CR
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- Draw a structural formula of the principal product formed when benzonitrile is treated with each reagent. (a) H₂O (one equivalent), H₂SO₄, heat (b) H₂O (excess), H₂SO₄, heat (c) NaOH, H₂O, heat (d) LiAlH4, then H₂Oarrow_forwardDraw the stepwise mechanism for the reactionsarrow_forwardDraw stepwise mechanismarrow_forward
- Part I. Draw reaction mechanism for the transformations of benzophenone to benzopinacol to benzopinaco lone and answer the ff: a) Give the major reason for the exposure of benzophenone al isopropyl alcohol (w/acid) to direct sunlight of pina colone Mechanism For b) Pinacol (2,3-dimethy 1, 1-3-butanediol) on treatment w/ acid gives a mixture (3,3-dimethyl-2-butanone) and 2, 3-dimethyl-1,3-butadiene. Give reasonable the formation of the productsarrow_forwardwhat are the Iupac names for each structurearrow_forwardWhat are the IUPAC Names of all the compounds in the picture?arrow_forward
- 1) a) Give the dominant Intermolecular Force (IMF) in a sample of each of the following compounds. Please show your work. (8) SF2, CH,OH, C₂H₂ b) Based on your answers given above, list the compounds in order of their Boiling Point from low to high. (8)arrow_forward19.78 Write the products of the following sequences of reactions. Refer to your reaction road- maps to see how the combined reactions allow you to "navigate" between the different functional groups. Note that you will need your old Chapters 6-11 and Chapters 15-18 roadmaps along with your new Chapter 19 roadmap for these. (a) 1. BHS 2. H₂O₂ 3. H₂CrO4 4. SOCI₂ (b) 1. Cl₂/hv 2. KOLBU 3. H₂O, catalytic H₂SO4 4. H₂CrO4 Reaction Roadmap An alkene 5. EtOH 6.0.5 Equiv. NaOEt/EtOH 7. Mild H₂O An alkane 1.0 2. (CH3)₂S 3. H₂CrO (d) (c) 4. Excess EtOH, catalytic H₂SO OH 4. Mild H₂O* 5.0.5 Equiv. NaOEt/EtOH An alkene 6. Mild H₂O* A carboxylic acid 7. Mild H₂O* 1. SOC₁₂ 2. EtOH 3.0.5 Equiv. NaOEt/E:OH 5.1.0 Equiv. NaOEt 6. NH₂ (e) 1. 0.5 Equiv. NaOEt/EtOH 2. Mild H₂O* Br (f) i H An aldehyde 1. Catalytic NaOE/EtOH 2. H₂O*, heat 3. (CH,CH₂)₂Culi 4. Mild H₂O* 5.1.0 Equiv. LDA Br An ester 4. NaOH, H₂O 5. Mild H₂O* 6. Heat 7. MgBr 8. Mild H₂O* 7. Mild H₂O+arrow_forwardLi+ is a hard acid. With this in mind, which if the following compounds should be most soluble in water? Group of answer choices LiBr LiI LiF LiClarrow_forward
- Q4: Write organic product(s) of the following reactions and show the curved-arrow mechanism of the reactions. Br MeOH OSO2CH3 MeOHarrow_forwardProvide the correct IUPAC name for the compound shown here. Reset cis- 5- trans- ☑ 4-6- 2- 1- 3- di iso tert- tri cyclo sec- oct but hept prop hex pent yl yne ene anearrow_forwardQ6: Predict the major product(s) for the following reactions. Note the mechanism (SN1, SN2, E1 or E2) the reaction proceeds through. If no reaction takes place, indicate why. Pay attention to stereochemistry. NaCN DMF Br σ Ilm... Br H Br H H NaCN CH3OH KOtBu tBuOH NaBr H₂O LDA Et2O (CH3)2CHOH KCN DMSO NaOH H₂O, A LDA LDA Systemarrow_forward
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