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(a)
Interpretation:
The bond angles in tert-butyl cation has to be predicted.
(b)
Interpretation:
The hybridization of carbon bearing the positive charge has to be given.
Concept Introduction:
Hybridization:
Hybridization is defined as intermixing of atomic or molecular orbital. The valance orbitals of an atom is allowed to combine with valence orbital of another orbital. The resulting orbitals forms a bond and these orbitals are known as hybridized orbital.
(c)
Interpretation:
A balanced chemical equation between tert-butyl cation and water as Lewis acid with water has to be given.
Concept Introduction:
Balanced Chemical equation:
A balanced chemical equation is an equation which contains same elements in same number on both the sides (reactant and product side) of the chemical equation thereby obeying the law of conservation of mass.
(d)
Interpretation:
A balanced chemical equation between tert-butyl cation and water as Bronsted-Lowary acid with water has to be given.
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Chapter 4 Solutions
Organic Chemistry
- A chemistry graduate student is studying the rate of this reaction: 2 HI (g) →H2(g) +12(g) She fills a reaction vessel with HI and measures its concentration as the reaction proceeds: time (minutes) [IH] 0 0.800M 1.0 0.301 M 2.0 0.185 M 3.0 0.134M 4.0 0.105 M Use this data to answer the following questions. Write the rate law for this reaction. rate = 0 Calculate the value of the rate constant k. k = Round your answer to 2 significant digits. Also be sure your answer has the correct unit symbol.arrow_forwardNonearrow_forwardNonearrow_forward
- Q2: Label the following molecules as chiral or achiral, and label each stereocenter as R or S. CI CH3 CH3 NH2 C CH3 CH3 Br CH3 X &p Bra 'CH 3 "CH3 X Br CH3 Me - N OMe O DuckDuckarrow_forward1. For the four structures provided, Please answer the following questions in the table below. a. Please draw π molecular orbital diagram (use the polygon-and-circle method if appropriate) and fill electrons in each molecular orbital b. Please indicate the number of π electrons c. Please indicate if each molecule provided is anti-aromatic, aromatic, or non- aromatic TT MO diagram Number of π e- Aromaticity Evaluation (X choose one) Non-aromatic Aromatic Anti-aromatic || ||| + IVarrow_forward1.3 grams of pottasium iodide is placed in 100 mL of o.11 mol/L lead nitrate solution. At room temperature, lead iodide has a Ksp of 4.4x10^-9. How many moles of precipitate will form?arrow_forward
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