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Concept explainers
(a)
Interpretation:
The Lewis structure of hydride ion and sodium hydride has to be drawn. Also, the consistency of high melting point with Lewis structure has to be explained.
Concept Introduction:
Lewis structure: This is the only way to show the sharing of electrons between atom in polar covalent bonds or covalent bond. This is often called Lewis structure. This structure denotes valence electrons of an atom by dots and also it shows the way of valence electron distributed within a molecule.
(b)
Interpretation:
The gas evolved when sodium hydride is added slowly to water has to be identified. Also, the reason for basic nature of the resulting solution has to be given.
Concept Introduction:
Position of equilibrium in acid-base reaction:
In an acid-base reaction, the position of equilibrium always favors reaction of the stronger acid and stronger base to form the weaker acid and weaker base. Therefore, the major species present at equilibrium in an acid-base reaction are weaker acid and weaker base. The reaction equilibrium shifts to a direction where weaker acid and weaker base is formed. Acids with greater
(c)
Interpretation:
Using curved arrows to indicate flow of electrons, a reaction equation between hydride ion and 1-butylene has to be given.
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Chapter 4 Solutions
Organic Chemistry
- (a) Which poisonous gas is evolved when white phosphorus is heated with Cone. NaOH solution? Write the chemical equation. (b) Write the formula of first noble gas compound prepared by N. Bartlett. What inspired N. Bartlett to prepare this compound? (c) Fluorine is a stronger oxidising agent than chlorine. Why? (d)Write one use of chlorine gas.arrow_forwardEach of the chemically active Period 2 elements forms stable compounds in which it has bonds to fluorine. (a) What are the names and formulas of these compounds? (b) Does ∆EN increase or decrease left to right across the period? (c) Does percent ionic character increase or decrease left to right? (d) Draw Lewis structures for these compoundsarrow_forwardCompounds such as NaBH4, Al(BH4)3, and LiAlH4 are complex hydrides used as reducing agents in many syntheses. (a) Give the oxidation state of each element in these compounds. (b) Write a Lewis structure for the polyatomic anion in NaBH4, and predict its shape.arrow_forward
- Chlorine dioxide gas (ClO2) is used as a commercial bleachingagent. It bleaches materials by oxidizing them. In thecourse of these reactions, the ClO2 is itself reduced. (a)What is the Lewis structure for ClO2? (b) Why do you thinkthat ClO2 is reduced so readily? (c) When a ClO2 moleculegains an electron, the chlorite ion, ClO2-, forms. Draw theLewis structure for ClO2-. (d) Predict the O—Cl—O bondangle in the ClO2- ion. (e) One method of preparing ClO2is by the reaction of chlorine and sodium chlorite:Cl2(g) + 2 NaClO2(s)------>2 ClO2(g) + 2 NaCl(s)If you allow 15.0 g of NaClO2 to react with 2.00 L of chlorinegas at a pressure of 1.50 atm at 21 °C, how many gramsof ClO2 can be prepared?arrow_forwardCompounds such as NaBH4, Al(BH4)3, and LiAlH4 are complexhydrides used as reducing agents in many syntheses.(a) Give the oxidation state of each element in these compounds.(b) Write a Lewis structure for the polyatomic anion in NaBH4, and predict its shape.arrow_forwardWrite an equation to show that nitrous acid , HNO2 , behaves as an acid in water.arrow_forward
- Compounds such as NaBH₄, Al(BH₄)₃, and LiAlH₄ arecomplex hydrides used as reducing agents in many syntheses.(a) Give the oxidation state of each element in these compounds.(b) Write a Lewis structure for the polyatomic anion in NaBH₄,and predict its shape.arrow_forwardThe first four ionization energies of an element X are 578, 1817, 2745, and 11,577 kJ·mol–1. What is the most likely formula for the most stable ion of Xarrow_forward(a) What are the common oxidation states of the halogens?(b) Give an explanation based on electron configuration for the range and values of the oxidation states of chlorine.(c) Why is fluorine an exception to the pattern of oxidation states found for the other group members?arrow_forward
- (i) Write the electro-dot structures for sodium, oxygen, and magnesium(ii) Show the formation of Na2O and MgO by the transfer of electrons(iii) What are the ions present in these compounds?arrow_forward(A) if both sentences are true, (B) if both sentences are false, (C) if the first sentence is true but the second is false, and (D) if the first sentence is false but the second is true. 1. When a non-metallic oxide reacts with water, a base will be formed as the product of the reaction. When a metallic oxide like phosphorous pentoxide reacts with water, a base will be formed as the product of the reaction. 2. When water is mixed with oxides, hydrogen gas is evolved. A red to blue color change in the litmus paper indicates that the solution tested is an acid. 3. The filtrate in any filtration process is left on the surface of the filter paper, while the residue is collected at the bottom of the flask/container after passing through the filter paper. In the distillation process, the methyl violet served as a compound to acidify the water. 4. In the Winkler Titration Method, the starch solution turns colorless in the presence of free iodine in the solution to be titrated. In the Winkler…arrow_forwardComplete and balance the following equations. Write the entire equation, including the reactants and products, and include the physical state of each species. (a) K(s) + H2O(l)→ (b) NaH(s) + H2O(l)→arrow_forward
- Chemistry: The Molecular ScienceChemistryISBN:9781285199047Author:John W. Moore, Conrad L. StanitskiPublisher:Cengage LearningChemistry: Principles and PracticeChemistryISBN:9780534420123Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward MercerPublisher:Cengage LearningChemistry by OpenStax (2015-05-04)ChemistryISBN:9781938168390Author:Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark BlaserPublisher:OpenStax
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