Physical Chemistry
Physical Chemistry
2nd Edition
ISBN: 9781133958437
Author: Ball, David W. (david Warren), BAER, Tomas
Publisher: Wadsworth Cengage Learning,
bartleby

Concept explainers

bartleby

Videos

Textbook Question
Book Icon
Chapter 4, Problem 4.40E

Equation 4.19 says that

( U V ) S = p

If we are considering the variation of Δ U , the change in the change of the internal energy, we can write that as (see the previous problem for an analogous argument)

( ( Δ U ) V ) S = Δ p

Show that this is entirely consistent with the first law of thermodynamics.

Blurred answer
Students have asked these similar questions
A typical candy bar weighs about 2 oz (1.00 oz= 28.4 g).(a) Assuming that a candy bar is 100% sugar and that 1.0 g of sugar is equivalent to about 4.0 Calories of energy, calculate the energy (in kJ) contained in a typical candy bar.(b) Assuming that your mass is 58 kg and you convert chemicalpotential energy to work with 100% efficiency, how high wouldyou have to climb to work off the energy in a candy bar? (Poten-tial energy =mass XgXheight, where g=9.8 m/s².)(c) Why is your actual conversion of potential energy to workless than 100% efficient?
The French chemists, Pierre L. Dulong and Alexis T. Petit, noted in 1819 that the molar heat capacity of many solids at ordinary temperatures is proportional to the number of atoms per formula unit of the solid. They quantified their observations in what is known as Dulong and Petit's rule, which says that the molar heat capacity, ??CP , of a solid can be expressed as   ??=?⋅3?CP=N⋅3⁢R   where ?N is the number of atoms per formula unit and ?R is the universal gas constant. The observed heat capacity per gram of a compound containing thallium and chlorine is 0.21 J·K−1·g−10.21 J·K−1·g−1 . Use Dulong and Petit's rule to determine the empirical formula of the compound.
The net change in the multistep biochemical process of photosynthesis is that CO₂ and H₂O form glucose (C₆H₁₂O₆)and O₂. Chlorophyll absorbs light in the 600 to 700 nm region.(a) Write a balanced thermochemical equation for formation of1.00 mol of glucose. (b) What is the minimum number of pho-tons with λ=680. nm needed to prepare 1.00 mol of glucose?

Chapter 4 Solutions

Physical Chemistry

Ch. 4 - Consider a piston whose compression ratio is 10:1;...Ch. 4 - When one dives, water pressure increases by 1atm...Ch. 4 - Calculate G(25C) for this chemical reaction, which...Ch. 4 - Thermodynamic properties can also be determined...Ch. 4 - Calculate G in two different ways for the...Ch. 4 - Calculate G in two different ways for the...Ch. 4 - For the reaction C(graphite)C(diamond) at 25C,...Ch. 4 - Determine G for the following reaction at 0C and...Ch. 4 - What is the maximum amount of electrical that is,...Ch. 4 - When a person performs work, it is non-pV work....Ch. 4 - Can non-pV work be obtained from a process for...Ch. 4 - Can pV work be obtained from a process for which...Ch. 4 - Batteries are chemical systems that can be used to...Ch. 4 - The value of G for any phase change at constant p...Ch. 4 - The value of G for any phase change at constant p...Ch. 4 - Under what conditions is A=0 for a phase change?...Ch. 4 - Example 4.2 calculated A for one step of a Carnot...Ch. 4 - Can CV and Cp be easily defined using the natural...Ch. 4 - Analogous to equation 4.26, what is the expression...Ch. 4 - Prob. 4.30ECh. 4 - Prob. 4.31ECh. 4 - Prob. 4.32ECh. 4 - Although ideally, U=H=0 for a gas-phase process at...Ch. 4 - Use equations 4.21 and 4.25 to explain why H and G...Ch. 4 - Prob. 4.35ECh. 4 - Which of the following functions are exact...Ch. 4 - Prob. 4.37ECh. 4 - Prob. 4.38ECh. 4 - Prob. 4.39ECh. 4 - Equation 4.19 says that (UV)S=p If we are...Ch. 4 - For an isentropic process, what is the approximate...Ch. 4 - Use the ideal gas law to demonstrate the cyclic...Ch. 4 - Prob. 4.43ECh. 4 - Prob. 4.44ECh. 4 - Evaluate (U/V)T for an ideal gas. Use the...Ch. 4 - Evaluate (U/V)T for a van der Waals gas. Use the...Ch. 4 - Repeat the previous exercise for a gas that...Ch. 4 - Determine an expression for (p/S)T for an ideal...Ch. 4 - Determine the value of the derivative {[(G)]/T}p...Ch. 4 - Prob. 4.50ECh. 4 - Prob. 4.51ECh. 4 - A 0.988-mole sample of argon expands from 25.0L to...Ch. 4 - A 3.66-mol sample of He contracts from 15.5L to...Ch. 4 - Prob. 4.54ECh. 4 - Prob. 4.55ECh. 4 - Use the Gibbs-Helmholtz equation to demonstrate...Ch. 4 - For the equation 2H2(g)+O2(g)2H2O(g)...Ch. 4 - Use equation 4.46 as an example and find an...Ch. 4 - What is the value of G when 1.00mol of water at...Ch. 4 - Prob. 4.60ECh. 4 - Prob. 4.61ECh. 4 - Prob. 4.62ECh. 4 - Prob. 4.63ECh. 4 - Prob. 4.64ECh. 4 - What is the change in the chemical potential of a...Ch. 4 - Prob. 4.66ECh. 4 - Prob. 4.67ECh. 4 - Prob. 4.68ECh. 4 - Prob. 4.69ECh. 4 - Can equation 4.62 be used to calculate for an...Ch. 4 - Prob. 4.71ECh. 4 - Of helium and oxygen gases, which one do you...Ch. 4 - Prob. 4.73ECh. 4 - Use equation 4.39 to determine a numerical value...Ch. 4 - Prob. 4.75ECh. 4 - Prob. 4.76E
Knowledge Booster
Background pattern image
Chemistry
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Similar questions
SEE MORE QUESTIONS
Recommended textbooks for you
Text book image
Chemistry for Engineering Students
Chemistry
ISBN:9781337398909
Author:Lawrence S. Brown, Tom Holme
Publisher:Cengage Learning
Text book image
Chemistry by OpenStax (2015-05-04)
Chemistry
ISBN:9781938168390
Author:Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark Blaser
Publisher:OpenStax
Text book image
Chemistry: The Molecular Science
Chemistry
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:Cengage Learning
Text book image
General Chemistry - Standalone book (MindTap Cour...
Chemistry
ISBN:9781305580343
Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell
Publisher:Cengage Learning
Text book image
Chemistry
Chemistry
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Cengage Learning
Text book image
Chemistry: An Atoms First Approach
Chemistry
ISBN:9781305079243
Author:Steven S. Zumdahl, Susan A. Zumdahl
Publisher:Cengage Learning
Calorimetry Concept, Examples and Thermochemistry | How to Pass Chemistry; Author: Melissa Maribel;https://www.youtube.com/watch?v=nSh29lUGj00;License: Standard YouTube License, CC-BY