Physical Chemistry
Physical Chemistry
2nd Edition
ISBN: 9781133958437
Author: Ball, David W. (david Warren), BAER, Tomas
Publisher: Wadsworth Cengage Learning,
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Chapter 4, Problem 4.40E

Equation 4.19 says that

( U V ) S = p

If we are considering the variation of Δ U , the change in the change of the internal energy, we can write that as (see the previous problem for an analogous argument)

( ( Δ U ) V ) S = Δ p

Show that this is entirely consistent with the first law of thermodynamics.

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Chapter 4 Solutions

Physical Chemistry

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