2nd Edition

ISBN: 9781133958437

Author: Ball, David W. (david Warren), BAER, Tomas

Publisher: Wadsworth Cengage Learning,

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Textbook Question

Chapter 4, Problem 4.46E

Evaluate ( ∂ U / ∂ V ) T for a van der Waals gas. Use the third expression from Example 4.11 and compare your answer to the answer from the previous exercise.

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Chapter 4, Problem 4.45E

Chapter 4, Problem 4.47E

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Chapter 4 Solutions

Physical Chemistry

Ch. 4 - List the sets of conditions that allow dS, dU, and...Ch. 4 - Explain why conditions for using S>0 as a strict...Ch. 4 - Explain how the equation dU+pdVTdS0 is consistent...Ch. 4 - Explain why the spontaneity conditions given in...Ch. 4 - Prove that the adiabatic free expansion of an...Ch. 4 - Derive equation 4.6 from equation 4.5.Ch. 4 - Derive equation 4.8 from equation 4.7.Ch. 4 - The third part of equation 4.9 mentions a...Ch. 4 - Calculate A for a process in which 0.160mole of an...Ch. 4 - What is the maximum amount of non-pV work that can...

Ch. 4 - Consider a piston whose compression ratio is 10:1;...Ch. 4 - When one dives, water pressure increases by 1atm...Ch. 4 - Calculate G(25C) for this chemical reaction, which...Ch. 4 - Thermodynamic properties can also be determined...Ch. 4 - Calculate G in two different ways for the...Ch. 4 - Calculate G in two different ways for the...Ch. 4 - For the reaction C(graphite)C(diamond) at 25C,...Ch. 4 - Determine G for the following reaction at 0C and...Ch. 4 - What is the maximum amount of electrical that is,...Ch. 4 - When a person performs work, it is non-pV work....Ch. 4 - Can non-pV work be obtained from a process for...Ch. 4 - Can pV work be obtained from a process for which...Ch. 4 - Batteries are chemical systems that can be used to...Ch. 4 - The value of G for any phase change at constant p...Ch. 4 - The value of G for any phase change at constant p...Ch. 4 - Under what conditions is A=0 for a phase change?...Ch. 4 - Example 4.2 calculated A for one step of a Carnot...Ch. 4 - Can CV and Cp be easily defined using the natural...Ch. 4 - Analogous to equation 4.26, what is the expression...Ch. 4 - Prob. 4.30E Ch. 4 - Prob. 4.31E Ch. 4 - Prob. 4.32E Ch. 4 - Although ideally, U=H=0 for a gas-phase process at...Ch. 4 - Use equations 4.21 and 4.25 to explain why H and G...Ch. 4 - Prob. 4.35E Ch. 4 - Which of the following functions are exact...Ch. 4 - Prob. 4.37E Ch. 4 - Prob. 4.38E Ch. 4 - Prob. 4.39E Ch. 4 - Equation 4.19 says that (UV)S=p If we are...Ch. 4 - For an isentropic process, what is the approximate...Ch. 4 - Use the ideal gas law to demonstrate the cyclic...Ch. 4 - Prob. 4.43E Ch. 4 - Prob. 4.44E Ch. 4 - Evaluate (U/V)T for an ideal gas. Use the...Ch. 4 - Evaluate (U/V)T for a van der Waals gas. Use the...Ch. 4 - Repeat the previous exercise for a gas that...Ch. 4 - Determine an expression for (p/S)T for an ideal...Ch. 4 - Determine the value of the derivative {[(G)]/T}p...Ch. 4 - Prob. 4.50E Ch. 4 - Prob. 4.51E Ch. 4 - A 0.988-mole sample of argon expands from 25.0L to...Ch. 4 - A 3.66-mol sample of He contracts from 15.5L to...Ch. 4 - Prob. 4.54E Ch. 4 - Prob. 4.55E Ch. 4 - Use the Gibbs-Helmholtz equation to demonstrate...Ch. 4 - For the equation 2H2(g)+O2(g)2H2O(g)...Ch. 4 - Use equation 4.46 as an example and find an...Ch. 4 - What is the value of G when 1.00mol of water at...Ch. 4 - Prob. 4.60E Ch. 4 - Prob. 4.61E Ch. 4 - Prob. 4.62E Ch. 4 - Prob. 4.63E Ch. 4 - Prob. 4.64E Ch. 4 - What is the change in the chemical potential of a...Ch. 4 - Prob. 4.66E Ch. 4 - Prob. 4.67E Ch. 4 - Prob. 4.68E Ch. 4 - Prob. 4.69E Ch. 4 - Can equation 4.62 be used to calculate for an...Ch. 4 - Prob. 4.71E Ch. 4 - Of helium and oxygen gases, which one do you...Ch. 4 - Prob. 4.73E Ch. 4 - Use equation 4.39 to determine a numerical value...Ch. 4 - Prob. 4.75E Ch. 4 - Prob. 4.76E

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