Physical Chemistry
Physical Chemistry
2nd Edition
ISBN: 9781133958437
Author: Ball, David W. (david Warren), BAER, Tomas
Publisher: Wadsworth Cengage Learning,
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Chapter 4, Problem 4.74E

Use equation 4.39 to determine a numerical value for the Joule-Thomson coefficient, μ JT , for sulfur dioxide, SO 2 , at 25 ° C , assuming that it acts as a van der Waals gas. Van der Waals constants can be found in Table 1.6 .

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JON Determine the bund energy for UCI (in kJ/mol Hcl) using me balanced chemical equation and bund energies listed? का (My (9) +36/2(g)-(((3(g) + 3(g) A Hryn = -330. KJ bond energy и-н 432 bond bond C-1413 C=C 839 N-H 391 C=O 1010 S-H 363 б-н 467 02 498 N-N 160 N=N 243 418 C-C 341 C-0 358 C=C C-C 339 N-Br 243 Br-Br C-Br 274 193 614 (-1 214||(=olin (02) 799 C=N 615 AAL
Determine the bond energy for HCI ( in kJ/mol HCI) using he balanced cremiculequecticnand bund energles listed? also c double bond to N is 615, read numbets carefully please!!!! Determine the bund energy for UCI (in kJ/mol cl) using me balanced chemical equation and bund energies listed? 51 (My (9) +312(g)-73(g) + 3(g) =-330. KJ спод bond energy Hryn H-H bond band 432 C-1 413 C=C 839 NH 391 C=O 1010 S-1 343 6-H 02 498 N-N 160 467 N=N C-C 341 CL- 243 418 339 N-Br 243 C-O 358 Br-Br C=C C-Br 274 193 614 (-1 216 (=olin (02) 799 C=N 618

Chapter 4 Solutions

Physical Chemistry

Ch. 4 - Consider a piston whose compression ratio is 10:1;...Ch. 4 - When one dives, water pressure increases by 1atm...Ch. 4 - Calculate G(25C) for this chemical reaction, which...Ch. 4 - Thermodynamic properties can also be determined...Ch. 4 - Calculate G in two different ways for the...Ch. 4 - Calculate G in two different ways for the...Ch. 4 - For the reaction C(graphite)C(diamond) at 25C,...Ch. 4 - Determine G for the following reaction at 0C and...Ch. 4 - What is the maximum amount of electrical that is,...Ch. 4 - When a person performs work, it is non-pV work....Ch. 4 - Can non-pV work be obtained from a process for...Ch. 4 - Can pV work be obtained from a process for which...Ch. 4 - Batteries are chemical systems that can be used to...Ch. 4 - The value of G for any phase change at constant p...Ch. 4 - The value of G for any phase change at constant p...Ch. 4 - Under what conditions is A=0 for a phase change?...Ch. 4 - Example 4.2 calculated A for one step of a Carnot...Ch. 4 - Can CV and Cp be easily defined using the natural...Ch. 4 - Analogous to equation 4.26, what is the expression...Ch. 4 - Prob. 4.30ECh. 4 - Prob. 4.31ECh. 4 - Prob. 4.32ECh. 4 - Although ideally, U=H=0 for a gas-phase process at...Ch. 4 - Use equations 4.21 and 4.25 to explain why H and G...Ch. 4 - Prob. 4.35ECh. 4 - Which of the following functions are exact...Ch. 4 - Prob. 4.37ECh. 4 - Prob. 4.38ECh. 4 - Prob. 4.39ECh. 4 - Equation 4.19 says that (UV)S=p If we are...Ch. 4 - For an isentropic process, what is the approximate...Ch. 4 - Use the ideal gas law to demonstrate the cyclic...Ch. 4 - Prob. 4.43ECh. 4 - Prob. 4.44ECh. 4 - Evaluate (U/V)T for an ideal gas. Use the...Ch. 4 - Evaluate (U/V)T for a van der Waals gas. Use the...Ch. 4 - Repeat the previous exercise for a gas that...Ch. 4 - Determine an expression for (p/S)T for an ideal...Ch. 4 - Determine the value of the derivative {[(G)]/T}p...Ch. 4 - Prob. 4.50ECh. 4 - Prob. 4.51ECh. 4 - A 0.988-mole sample of argon expands from 25.0L to...Ch. 4 - A 3.66-mol sample of He contracts from 15.5L to...Ch. 4 - Prob. 4.54ECh. 4 - Prob. 4.55ECh. 4 - Use the Gibbs-Helmholtz equation to demonstrate...Ch. 4 - For the equation 2H2(g)+O2(g)2H2O(g)...Ch. 4 - Use equation 4.46 as an example and find an...Ch. 4 - What is the value of G when 1.00mol of water at...Ch. 4 - Prob. 4.60ECh. 4 - Prob. 4.61ECh. 4 - Prob. 4.62ECh. 4 - Prob. 4.63ECh. 4 - Prob. 4.64ECh. 4 - What is the change in the chemical potential of a...Ch. 4 - Prob. 4.66ECh. 4 - Prob. 4.67ECh. 4 - Prob. 4.68ECh. 4 - Prob. 4.69ECh. 4 - Can equation 4.62 be used to calculate for an...Ch. 4 - Prob. 4.71ECh. 4 - Of helium and oxygen gases, which one do you...Ch. 4 - Prob. 4.73ECh. 4 - Use equation 4.39 to determine a numerical value...Ch. 4 - Prob. 4.75ECh. 4 - Prob. 4.76E
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