FUND.OF GEN CHEM CHAP 1-13 W/ACCESS
16th Edition
ISBN: 9781323406038
Author: McMurry
Publisher: PEARSON C
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Chapter 3.10, Problem 3.26P
Interpretation Introduction
Interpretation: The relation between the size of ions and melting point to be predicted.
Concept Introduction:
Properties of ionic compound: Ionic compounds are usually crystalline solids. Ions are generally varies in size and charges, so ions are packed together in different ways in crystal. Ionic compounds dissolves in water if the attraction between the ion and the water molecule overcomes the attraction of the ions for one another.
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The beta-lactamase hydrolyzes the lactam-ring in penicillin. Describe the mechanism
of hydrolysis, insuring to include the involvement of S, D, & K in the reaction sequence. Please help
To map the active site of beta-lactamase, the enzyme was hydrolyzed with trypsin to yield a hexapeptide (P1) with the following amino acids. Glu, Lys, Leu, Phe, Met, and Ser. Treatment of P1 with phenyl isothiocyanate yielded a PTH derivative of phenylalanine and a peptide (P2). Treatment of P1 with cyanogenbromide gave an acidic tetrapeptide (P3) and a dipeptide (P4).Treatment of P2 with 1-fluoro-2,4-dinitrobenzene, followed by complete hydrolysis, yields N-2,4-dinitrophenyl-Glu. P1, P2, and P3 contain the active site serine.
Why doesn't D in this hexapeptide not participate in the hydrolysis of the beta-lactam ring even though S, K, and D are involved in the catalyst?
To map the active site of -lactamase, the enzyme was hydrolyzed with trypsin to yield a hexapeptide (P1) with the following amino acids. Glu, Lys, Leu, Phe, Met, and Ser. Treatment of P1 with phenyl isothiocyanate yielded a PTH derivative of phenylalanine and a peptide (P2). Treatment of P1 with cyanogenbromide gave an acidic tetrapeptide (P3) and a dipeptide (P4).Treatment of P2 with 1-fluoro-2,4-dinitrobenzene, followed by complete hydrolysis, yields N-2,4-dinitrophenyl-Glu. P1, P2, and P3 contain the active site serine.
Using the experimental results described above derive the primary sequence of the active site hexapeptide. Please help!
Chapter 3 Solutions
FUND.OF GEN CHEM CHAP 1-13 W/ACCESS
Ch. 3.1 - Magnesium atoms lose two electrons when they...Ch. 3.1 - Prob. 3.2PCh. 3.1 - Prob. 3.3KCPCh. 3.2 - Prob. 3.4PCh. 3.2 - Prob. 3.5PCh. 3.2 - Prob. 3.6KCPCh. 3.3 - Iron is an important component of hemoglobin, a...Ch. 3.3 - Prob. 3.8PCh. 3.3 - Blood serum in healthy adults normally contains...Ch. 3.4 - Prob. 3.10P
Ch. 3.4 - Which element in the following pairs is likely to...Ch. 3.4 - Prob. 3.12PCh. 3.5 - Prob. 3.1CIAPCh. 3.5 - Prob. 3.13PCh. 3.5 - Prob. 3.14PCh. 3.5 - Prob. 3.15PCh. 3.6 - Prob. 3.16PCh. 3.6 - Prob. 3.17PCh. 3.6 - Prob. 3.3CIAPCh. 3.6 - Prob. 3.4CIAPCh. 3.8 - Prob. 3.18PCh. 3.8 - Prob. 3.19PCh. 3.8 - Prob. 3.20PCh. 3.8 - Prob. 3.21KCPCh. 3.9 - Prob. 3.22PCh. 3.9 - Name the following compounds: (a)SnO2 (b)Ca(CN)2...Ch. 3.9 - Prob. 3.24PCh. 3.9 - Prob. 3.25KCPCh. 3.10 - Prob. 3.26PCh. 3.10 - Prob. 3.5CIAPCh. 3.11 - Prob. 3.27PCh. 3.11 - Prob. 3.28KCPCh. 3.11 - Prob. 3.7CIAPCh. 3 - Prob. 3.29UKCCh. 3 - Prob. 3.30UKCCh. 3 - Write the symbols for the ions represented in the...Ch. 3 - Prob. 3.32UKCCh. 3 - Prob. 3.33UKCCh. 3 - Prob. 3.34UKCCh. 3 - Prob. 3.35UKCCh. 3 - Prob. 3.36UKCCh. 3 - Prob. 3.37APCh. 3 - Prob. 3.38APCh. 3 - Prob. 3.39APCh. 3 - Prob. 3.40APCh. 3 - Prob. 3.41APCh. 3 - Identify the element X in the following ions and...Ch. 3 - Prob. 3.43APCh. 3 - Prob. 3.44APCh. 3 - Based on the following atomic numbers and...Ch. 3 - Prob. 3.46APCh. 3 - Prob. 3.47APCh. 3 - Prob. 3.48APCh. 3 - Prob. 3.49APCh. 3 - Prob. 3.50APCh. 3 - Prob. 3.51APCh. 3 - Prob. 3.52APCh. 3 - Prob. 3.53APCh. 3 - Prob. 3.54APCh. 3 - Prob. 3.55APCh. 3 - Prob. 3.56APCh. 3 - (a)Write equations for the loss of an electron by...Ch. 3 - Prob. 3.58APCh. 3 - Prob. 3.59APCh. 3 - Prob. 3.60APCh. 3 - Prob. 3.61APCh. 3 - Prob. 3.62APCh. 3 - Prob. 3.63APCh. 3 - Prob. 3.64APCh. 3 - Prob. 3.65APCh. 3 - Prob. 3.66APCh. 3 - Prob. 3.67APCh. 3 - Prob. 3.68APCh. 3 - Prob. 3.69APCh. 3 - Prob. 3.70APCh. 3 - Prob. 3.71APCh. 3 - Prob. 3.72APCh. 3 - Prob. 3.73APCh. 3 - Prob. 3.74APCh. 3 - Prob. 3.75APCh. 3 - Prob. 3.76APCh. 3 - Give the formula and the name of the anions for...Ch. 3 - Explain why the hydride ion, H, has a noble gas...Ch. 3 - The H ion (Problem 3.78) is stable but the Li ion...Ch. 3 - Prob. 3.80CPCh. 3 - Prob. 3.81CPCh. 3 - The names given for the following compounds are...Ch. 3 - The formulas given for the following compounds are...Ch. 3 - Prob. 3.84CPCh. 3 - Element X reacts with element Y to give a product...Ch. 3 - Prob. 3.86CPCh. 3 - The term alum" refers to a group of ionic...Ch. 3 - Prob. 3.88GPCh. 3 - Prob. 3.89GPCh. 3 - Prob. 3.90GP
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