ORGANIC CHEMISTRY
ORGANIC CHEMISTRY
5th Edition
ISBN: 9781259977596
Author: SMITH
Publisher: MCG
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Chapter 31, Problem 31.7P
Interpretation Introduction

Interpretation: The ways of similarities between phosphoacylglycerols with soaps are to be stated.

Concept introduction: Phosphoacylglycerols are also known as phosphoglycerides. Their structures differ to triacylglycerols with one important difference. The phosphoacylglycerols involves esterification of only two OH groups of glycerol with fatty acid. The third hydroxyl group is a component of phosphodiester that is also bonded to an alcohol possessing low molecular weight.

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How might you prepare each of the following using a nucleophilic substitution reaction at some step? (a) (b) (c) (d) CH3 CH3C CCHCH3 CH3 CH3 0 CCH3 ☐ CH3 CH3CH2CH2CH2CN CH3CH2CH2NH2
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Manganese(II) Arsenate is insoluble in water at room temperature. (Note: Arsenate = AsO4³-) In the presence of aqueous ammonia, solid Manganese(II) Arsenate becomes more soluble and aqueous tetraamminemanganese (II) ion forms. When solid Manganese(II) arsenate was placed in a 2.00 M solution of ammonia, at equilibrium, 0.308 M of ammonia remains. If the Kf of tetraamminemanganese (II) ion is 250.0, Determine the Ksp of Manganese(II) arsenate Hint: You will have to figure out the Kspf of the overall chemical equation first, then solve for Ksp by using Kf and Kspf

Chapter 31 Solutions

ORGANIC CHEMISTRY

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