Organic Chemistry-Package(Custom)
4th Edition
ISBN: 9781259141089
Author: SMITH
Publisher: MCG
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Chapter 31, Problem 31.11P
Interpretation Introduction
Interpretation: The possible structure of ABS, a
Concept introduction: The copolymer is composed of two or more different monomers. The simpler units which combine to form
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ABS, a widely produced copolymer used in crash helmets, small appliances, and toys, is formed from three monomers–acrylonitrile (CH2 = CHCN), buta-1,3-diene (CH2 = CH–CH = CH2), and styrene (CH2 = CHPh). Draw a possible structure for ABS.
ABS, a widely produced copolymer used for high-impact applications like car bumpers and crash helmets, is formed from three
monomers-acrylonitrile (CH2 = CHCN), 1,3-butadiene (CH2= CH-CH=CH2), and styrene (CH2= CHPH). Draw a possible
structure for ABS.
(a) Draw the structure of polystyrene, which is formed by polymerizing the monomer styrene, C6H5CH=CH2.
Chapter 31 Solutions
Organic Chemistry-Package(Custom)
Ch. 31 - Prob. 31.1PCh. 31 - Prob. 31.2PCh. 31 - Prob. 31.3PCh. 31 - Draw the mechanism for the radical polymerization...Ch. 31 - Prob. 31.5PCh. 31 - Prob. 31.6PCh. 31 - Prob. 31.7PCh. 31 - Prob. 31.8PCh. 31 - Prob. 31.9PCh. 31 - Prob. 31.10P
Ch. 31 - Prob. 31.11PCh. 31 - Problem 30.12
What polymer is formed by anionic...Ch. 31 - Prob. 31.13PCh. 31 - Prob. 31.14PCh. 31 - Problem 30.15
What polyamide is formed from each...Ch. 31 - Prob. 31.16PCh. 31 - Prob. 31.17PCh. 31 - Prob. 31.18PCh. 31 - Prob. 31.19PCh. 31 - Prob. 31.20PCh. 31 - Prob. 31.21PCh. 31 - Prob. 31.22PCh. 31 - Prob. 31.23PCh. 31 - Prob. 31.24PCh. 31 - Prob. 31.25PCh. 31 - Prob. 31.26PCh. 31 - 30.26 Draw the structure of the polymer formed by...Ch. 31 - Prob. 31.28PCh. 31 - Prob. 31.29PCh. 31 - Prob. 31.30PCh. 31 - Prob. 31.31PCh. 31 - Prob. 31.32PCh. 31 - Prob. 31.33PCh. 31 - Prob. 31.34PCh. 31 - Prob. 31.35PCh. 31 - Prob. 31.36PCh. 31 - Prob. 31.37PCh. 31 - Prob. 31.38PCh. 31 - Prob. 31.39PCh. 31 - 30.39 Draw a stepwise mechanism for the...Ch. 31 - 30.40 Cationic polymerization of 3-phenylpropene ...Ch. 31 - Prob. 31.42PCh. 31 - Prob. 31.43PCh. 31 - 30.43 Although styrene undergoes both cationic and...Ch. 31 - 30.44 Rank the following compounds in order of...Ch. 31 - Prob. 31.46PCh. 31 - Prob. 31.47PCh. 31 - 30.47 Draw a stepwise mechanism for the following...Ch. 31 - 30.48 Draw a stepwise mechanism for the reaction...Ch. 31 - Prob. 31.50PCh. 31 - Prob. 31.51PCh. 31 - Prob. 31.52PCh. 31 - 30.52 (a) Explain why poly (vinyl alcohol) cannot...Ch. 31 - Prob. 31.54PCh. 31 - 30.53 Devise a synthesis of terephthalic acid and...Ch. 31 - Prob. 31.56PCh. 31 - Prob. 31.57PCh. 31 - 30.56 Compound A is a novel poly (ester amide)...Ch. 31 - Researchers at Rutgers University have developed...Ch. 31 - 30.58 Melmac, a thermosetting polymer formed from...Ch. 31 - 30.59 Although chain branching in radical...Ch. 31 - Prob. 31.62P
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- (a) Draw the structure of polystyrene, which is formed by polymerizing the monomer styrene, C6H5CH=CH2. (b) What monomer is used to form poly(vinyl acetate), a polymer used in paints and adhesives?arrow_forwardPoly(lactic acid) (PLA) has received much recent attention because the lactic acid monomer [CH3CH(OH)COOH] from which it is made can be obtained from carbohydrates rather than petroleum. This makes PLA a more “environmentally friendly” polyester. (A more in-depth discussion of green polymer synthesis is presented in Chapter 30.) Draw the structure of PLA.arrow_forwardLow-density polyethylene (LDPE) has a higher degree of chain branching than highdensity polyethylene (HDPE). Explain the relationship between chain branching and density.arrow_forward
- Poly(lactic acid) (PLA) has received much recent attention because the lactic acid monomer [CH3CH(OH)COOH] from which it is made can be obtained from carbohydrates rather than petroleum. This makes PLA a more “environmentally friendly” polyester. (A further discussion of green polymer synthesis is presented in Chapter 28.) Draw the structure of PLA.arrow_forwardHow many monomers are there in a molecule of PVC if the average molecular weight is 1,000,000 g/mol?arrow_forward1. Formaldehyde (methanal: H2C=0) can be polymerized to produce Delrin (polyoxymethylene), a strong and easily molded plastic. Write a chemical reaction that shows the formation of this polymer.arrow_forward
- Draw the constitutional (structural) isomers of C5H12 and then draw the structure of trans-2-butene, and then sketch the product that would result if this compound reacted with bromine, Br2.arrow_forwardDraw the structure of polystyrene, which is formed by polymerizing the monomer styrene, C6H5CH=CH2. What monomer is used to form poly(vinyl acetate), a polymer used in paints and adhesives?arrow_forwardA polymer closely related to PET is PBT, which is made from terephthalic acid and butane-1,4-diol.(a) Propose a structure for PBT and write the condensed formula for the structure.(b) What does PBT stand for? That is, what do you expect the trivial name of PBT to be?(c) Would you expect PBT to have a higher or lower melting point than PET? Justify your answer.(d) PBT, rather than PET, is used in molding because it crystallizes faster. Explain why PBT crystallizes more quickly than PET.arrow_forward
- Define Polyethylene ?arrow_forwardPolychloroprene, commonly known as neoprene, is widely used in wetsuits and in rubber parts that must withstand exposure to gasoline or other solvents. What monomer is used to make this synthetic rubber?arrow_forwardDetermine the number of H,C=CH, monomeric units in one molecule of polyethylene with a molar mass of 13,500 g. unitsarrow_forward
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