Interpretation: The structure of the polymer formed on reaction of
Concept introduction: In Step-growth
The polymers which can be melted and moulded to different shapes on heating are thermoplastic polymers. The highly crossed linked polymers which cannot be melted and moulded to different shapes are thermosetting polymers.
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Chapter 31 Solutions
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- A thermosetting material called polyester is made when a carboxylic acid reacts with dialcohol. Write the condensation polymerization with byproduct. The monomers of carboxylic acid and dialcohol are respectively: HO-C -C-OH HO-CH,CH,-OHarrow_forwardKodel is a condensation polymer made from terphthalic acid and 1,4-cyclohexandethanol. Write the structure of the resulting polymer.arrow_forwardWhat monomer is needed to form each polymer? COOEt COOEt cOOEt Et = CH,CH3 polyisobutylene (used to make basketballs) poly(ethyl acrylate) (used in latex paints)arrow_forward
- What polymer is formed when methyl α-methylacrylate [CH 2 C(CH 3)CO2CH 3] is polymerized? This polymer is used in Lucite and Plexiglas, transparent materials that are lighter but more impact resistant than glass.arrow_forwardMaleic anhydride reacts with ethylene glycol to produce an alkyd resin. Draw the structure of the condensation polymer produced.arrow_forwarddacron is the brand name for the polymer that is made from ethane-1,2-diol and benzene-1,4-dicarboxylic acid. what is the name for the linkages that join the monomers togetherarrow_forward
- A particularly strong and rigid polyester used for electronic parts is marketed under the trade name Glyptal. It is a polymer of terephthalic acid and glycerol. Draw a segment of the polymer and explain why it is so strong.arrow_forwardDrawing the Structure of a Polymer Formed from a Monomer What polymer is formed when CH2=CHCO2H (acrylic acid) is polymerized to form poly(acrylic acid)?arrow_forwardPoly(vinyl alcohol), a hydrophilic polymer used in aqueous adhesives, is made by polymerizing vinyl acetate and then hydrolyzing the ester linkages. We have seen that basic hydrolysis destroys the Dacron polymer. Poly(vinyl acetate) is converted to poly(vinyl alcohol) by a basic hydrolysis of the ester groups. Why doesn’t the hydrolysis destroy the poly(vinyl alcohol)polymer?arrow_forward
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