Concept explainers
(a)
Interpretation:
Types of attractive intermolecular interactions that arise between molecules of
Concept Introduction:
Intermolecular forces are forces that are responsible for interaction between molecules. Such forces include both attractive as well as repulsive forces.
Types of intermolecular forces:
1. Ion-dipole forces: These forces come into play when ions interact with polar molecules. Ion gets attracted to oppositely charged end of polar molecule.
2. Dipole-dipole forces: These forces arise when there is interaction between oppositely charged ends of different dipoles.
3. London forces: These forces exist when there is interaction between nonpolar molecules. There occurs distortion in symmetry of electron clouds when two nonpolar molecules come closer to each other. Such forces exist in all molecules and therefore London forces are called universal.
4. Hydrogen bonding: This intermolecular force exists when hydrogen atoms are connected to highly electronegative elements like
(b)
Interpretation:
Types of attractive intermolecular interactions that arise between molecules of
Concept Introduction:
Refer to part (a).
(c)
Interpretation:
Types of attractive intermolecular interactions that arise between molecules of
Concept Introduction:
Refer to part (a).
(d)
Interpretation:
Types of attractive intermolecular interactions that arise between molecules of
Concept Introduction:
Refer to part (a).
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ACHIEVE/CHEMICAL PRINCIPLES ACCESS 1TERM
- (a) How do the structures of these molecules account for these differences in boiling point? Provide a full account of the structures and their influence on the differences in this physical property. Name Boiling Point methane -161.6 °C methanol 64.7 °C propane -42 °C propan-1-ol 97 °Carrow_forwardName the type(s) of intermolecular forces that exists between molecules (or basic units) in each of the following species and identify the following species that are capable of hydrogen-bonding among themselves. (a) BeH2, (b) CH3COOHarrow_forward3arrow_forward
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- Name the type(s) of intermolecular forces that exists between molecules (or basic units) in each of the following species: (a) NaCL (b) CS2arrow_forwardHydrazine 1H2NNH22, hydrogen peroxide (HOOH), andwater 1H2O2 all have exceptionally high surface tensionscompared with other substances of comparable molecularweights. (a) Draw the Lewis structures for these three compounds.(b) What structural property do these substanceshave in common, and how might that account for the highsurface tensions?arrow_forwardNatural gas consists primarily of methane, CH4(g).(a) Write a balanced chemical equation for the completecombustion of methane to produce CO2(g) as the onlycarbon-containing product. (b) Write a balanced chemicalequation for the incomplete combustion of methaneto produce CO(g) as the only carbon-containing product.(c) At 25 °C and 1.0 atm pressure, what is the minimumquantity of dry air needed to combust 1.0 L of CH4(g) completelyto CO2(g)?arrow_forward
- A lecture hall contains 12 rows of seats. If the professor releases laughing gas (N2O) from the front of the room and tear gas (C6H11OBr) simultaneously from the back of the room, in which row are the students apt to start and to cry simultaneously?arrow_forwardBased on the type or types of intermolecular forces, predictthe substance in each pair that has the higher boiling point:(a) propane (C3H8) or n-butane (C4H10), (b) diethyl ether(CH3CH2OCH2CH3) or 1-butanol (CH3CH2CH2CH2OH),(c) sulfur dioxide (SO2) or sulfur trioxide (SO3), (d) phosgene(Cl2CO) or formaldehyde (H2CO).arrow_forwardName the type(s) of intermolecular forces that exists between molecules (or basic units) in each of the following species: (a) LiF, (b) CH4, (c) SO2 (a) benzene (C6H6), (b) CH3Cl, (c) PF3, (d) NaCl, (e) CS2arrow_forward
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