It is to be determined if all the atoms in buta-1, 3-diene have to reside in the same plane or not. Concept introduction: Groups which are connected by a single bond have the ability to rotate freely relative to each other. But the groups which are connected by a double bond do not rotate freely. In case of a double bond, the pi bond would be broken because during rotation, the overlap between p orbitals would be destroyed. When two atoms are connected by a double bond, those two atoms and all the atoms directly attached to them, prefer to lie in the same plane.

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Answer 1

Question

Chapter 3, Problem 3.49P

Interpretation Introduction

Interpretation:

It is to be determined if all the atoms in buta-1, 3-diene have to reside in the same plane or not.

Concept introduction:

Groups which are connected by a single bond have the ability to rotate freely relative to each other. But the groups which are connected by a double bond do not rotate freely. In case of a double bond, the pi bond would be broken because during rotation, the overlap between p orbitals would be destroyed. When two atoms are connected by a double bond, those two atoms and all the atoms directly attached to them, prefer to lie in the same plane.

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• Q: Calculate the wavelength of the radiation that will be absorbed in promoting an electron from the HOMO to the LUMO in butadiene.

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Answer 2

Question

Chapter 3, Problem 3.49P

Interpretation Introduction

Interpretation:

It is to be determined if all the atoms in buta-1, 3-diene have to reside in the same plane or not.

Concept introduction:

Groups which are connected by a single bond have the ability to rotate freely relative to each other. But the groups which are connected by a double bond do not rotate freely. In case of a double bond, the pi bond would be broken because during rotation, the overlap between p orbitals would be destroyed. When two atoms are connected by a double bond, those two atoms and all the atoms directly attached to them, prefer to lie in the same plane.

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Answer 3

Question

Chapter 3, Problem 3.49P

Interpretation Introduction

Interpretation:

It is to be determined if all the atoms in buta-1, 3-diene have to reside in the same plane or not.

Concept introduction:

Groups which are connected by a single bond have the ability to rotate freely relative to each other. But the groups which are connected by a double bond do not rotate freely. In case of a double bond, the pi bond would be broken because during rotation, the overlap between p orbitals would be destroyed. When two atoms are connected by a double bond, those two atoms and all the atoms directly attached to them, prefer to lie in the same plane.

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Answer 4

Question

Chapter 3, Problem 3.49P

Interpretation Introduction

Interpretation:

It is to be determined if all the atoms in buta-1, 3-diene have to reside in the same plane or not.

Concept introduction:

Groups which are connected by a single bond have the ability to rotate freely relative to each other. But the groups which are connected by a double bond do not rotate freely. In case of a double bond, the pi bond would be broken because during rotation, the overlap between p orbitals would be destroyed. When two atoms are connected by a double bond, those two atoms and all the atoms directly attached to them, prefer to lie in the same plane.

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Answer 5

Chapter 3, Problem 3.49P

Interpretation Introduction

Interpretation:

It is to be determined if all the atoms in buta-1, 3-diene have to reside in the same plane or not.

Concept introduction:

Groups which are connected by a single bond have the ability to rotate freely relative to each other. But the groups which are connected by a double bond do not rotate freely. In case of a double bond, the pi bond would be broken because during rotation, the overlap between p orbitals would be destroyed. When two atoms are connected by a double bond, those two atoms and all the atoms directly attached to them, prefer to lie in the same plane.

Answer 6

Chapter 3, Problem 3.49P

Interpretation Introduction

Interpretation:

It is to be determined if all the atoms in buta-1, 3-diene have to reside in the same plane or not.

Concept introduction:

Groups which are connected by a single bond have the ability to rotate freely relative to each other. But the groups which are connected by a double bond do not rotate freely. In case of a double bond, the pi bond would be broken because during rotation, the overlap between p orbitals would be destroyed. When two atoms are connected by a double bond, those two atoms and all the atoms directly attached to them, prefer to lie in the same plane.

Answer 7

Chapter 3, Problem 3.49P

Interpretation Introduction

Interpretation:

It is to be determined if all the atoms in buta-1, 3-diene have to reside in the same plane or not.

Concept introduction:

Groups which are connected by a single bond have the ability to rotate freely relative to each other. But the groups which are connected by a double bond do not rotate freely. In case of a double bond, the pi bond would be broken because during rotation, the overlap between p orbitals would be destroyed. When two atoms are connected by a double bond, those two atoms and all the atoms directly attached to them, prefer to lie in the same plane.

Answer 8

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Answer 10

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Answer 11

Ch. 3 - Prob. 3.1P Ch. 3 - Prob. 3.2P Ch. 3 - Prob. 3.3P Ch. 3 - Prob. 3.4P Ch. 3 - Prob. 3.5P Ch. 3 - Prob. 3.6P Ch. 3 - Prob. 3.7P Ch. 3 - Prob. 3.8P Ch. 3 - Prob. 3.9P Ch. 3 - Prob. 3.10P

Solution Summary: The author explains that all atoms in buta-1, 3-diene have to reside in the same plane.

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Chapter 3 Solutions