EBK ORGANIC CHEMISTRY: PRINCIPLES AND M
2nd Edition
ISBN: 9780393630817
Author: KARTY
Publisher: W.W.NORTON+CO. (CC)
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Chapter 3, Problem 3.19P
Interpretation Introduction
Interpretation:
An orbital picture of
Concept introduction:
The orbitals that overlap to form the bonds in a molecule depend on the hybridization of the central atoms. End-on overlap of hybrid orbitals leads to formation of
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Students have asked these similar questions
H
genistein
HO,
H
H
: ОН
HO,
H
(a) Is the hybridization of each C in the right-most ring the same? Explain.
(b) Is the hybridization of the O atoms in/on the center ring the same as that of the O atoms in the OH
groups? Explain.
(c) How many carbon-oxygen o-bonds are there in genistein? How many carbon-oxygen n-bonds?
(d) Do all the lone pairs on the oxygens occupy the same type of hybrid orbital? Explain by labeling
the hybridization of each oxygen atom in genistein.
Please answer a and for me. Thanks
(b)
2.
(C) Assign the hybridization, number of p orbitals remaining following hybridization, and
Hybridization and MOS
formal charge for nitrogen and carbon 1 in the molecule below.
H₂-CH₂
N
HH
Atom
Hybridization
(sp, sp², or sp³)
Carbon 1
Nitrogen
# p orbitals
remaining
(0, 1, 2, or 3)
Formal charge
(0, -1, or +1)
σ
Circle all types of molecular orbitals that are present in this molecule
π
(c) (1) Circle the HOMO of the molecule in (a):
σ
π
(d) ) Circle the LUMO of the molecule in (a):
σ
π
σ'
πο
nonbonding
πο
nonbonding
π"
HO
Chapter 3 Solutions
EBK ORGANIC CHEMISTRY: PRINCIPLES AND M
Ch. 3 - Prob. 3.1PCh. 3 - Prob. 3.2PCh. 3 - Prob. 3.3PCh. 3 - Prob. 3.4PCh. 3 - Prob. 3.5PCh. 3 - Prob. 3.6PCh. 3 - Prob. 3.7PCh. 3 - Prob. 3.8PCh. 3 - Prob. 3.9PCh. 3 - Prob. 3.10P
Ch. 3 - Prob. 3.11PCh. 3 - Prob. 3.12PCh. 3 - Prob. 3.13PCh. 3 - Prob. 3.14PCh. 3 - Prob. 3.15PCh. 3 - Prob. 3.16PCh. 3 - Prob. 3.17PCh. 3 - Prob. 3.18PCh. 3 - Prob. 3.19PCh. 3 - Prob. 3.20PCh. 3 - Prob. 3.21PCh. 3 - Prob. 3.22PCh. 3 - Prob. 3.23PCh. 3 - Prob. 3.24PCh. 3 - Prob. 3.25PCh. 3 - Prob. 3.26PCh. 3 - Prob. 3.27PCh. 3 - Prob. 3.28PCh. 3 - Prob. 3.29PCh. 3 - Prob. 3.30PCh. 3 - Prob. 3.31PCh. 3 - Prob. 3.32PCh. 3 - Prob. 3.33PCh. 3 - Prob. 3.34PCh. 3 - Prob. 3.35PCh. 3 - Prob. 3.36PCh. 3 - Prob. 3.37PCh. 3 - Prob. 3.38PCh. 3 - Prob. 3.39PCh. 3 - Prob. 3.40PCh. 3 - Prob. 3.41PCh. 3 - Prob. 3.42PCh. 3 - Prob. 3.43PCh. 3 - Prob. 3.44PCh. 3 - Prob. 3.45PCh. 3 - Prob. 3.46PCh. 3 - Prob. 3.47PCh. 3 - Prob. 3.48PCh. 3 - Prob. 3.49PCh. 3 - Prob. 3.50PCh. 3 - Prob. 3.51PCh. 3 - Prob. 3.52PCh. 3 - Prob. 3.53PCh. 3 - Prob. 3.54PCh. 3 - Prob. 3.55PCh. 3 - Prob. 3.56PCh. 3 - Prob. 3.1YTCh. 3 - Prob. 3.2YTCh. 3 - Prob. 3.3YTCh. 3 - Prob. 3.4YTCh. 3 - Prob. 3.5YTCh. 3 - Prob. 3.6YTCh. 3 - Prob. 3.7YTCh. 3 - Prob. 3.8YTCh. 3 - Prob. 3.9YTCh. 3 - Prob. 3.10YTCh. 3 - Prob. 3.11YTCh. 3 - Prob. 3.12YTCh. 3 - Prob. 3.13YT
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