Introductory Chemistry: Concepts and Critical Thinking (8th Edition)
8th Edition
ISBN: 9780134421377
Author: Charles H Corwin
Publisher: PEARSON
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Chapter 3, Problem 26KT
Interpretation Introduction
Interpretation:
The key term that corresponds to the definitions “the stored energy that matter possesses owing to its position or composition” is to be stated.
Concept introduction:
The potential energy of a particle or a system is the energy due to its state. The potential energy of a moving object is zero. When two particles attract each other, then the potential energy of the system is negative. When two particles repel each other, then the potential energy of the system is positive.
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From the following potentials, calculate the activity of Cl- in saturated KCl.
E0 (calomel electrode)= 0.268 V
E (calomel electrode, saturated KCl)= 0.241 V
Calculate the voltage of each of the following cells.
a) Fe(s)/Fe2+ (1.55 x 10-2 M)//Cu2+ (6.55 x 10-3 M)/Cu(s)
b) Pt, H2 (0.255 bar)/HCl (4.55 x 10-4 M), AgCl (sat'd)/Ag
Fe2+ +2e- = Fe E0= -0.44 V
Cu2+ + 2e- = Cu E0= 0.337 V
Ag+ + e- = Ag E0= 0.799 V
AgCl(s) + e- = Ag(s) + Cl- E0= 0.222 V
2H+ + 2e- = H2 E0= 0.000 V
A solution contains 0.097 M Ce3+, 1.55x10-3 M Ce4+, 1.55x10-3 M Mn2+, 0.097 M MnO4-, and 1.00 M HClO4 (F= 9.649 x 104 C/mol).
a) Write a balanced net reaction that can occur between species in this solution.
b) Calculate deltaG0 and K for the reaction.
c) Calculate E and deltaG for the conditions given.
Ce4+ + e- = Ce3+ E0= 1.70 V
MnO4- + 8H+ + 5e- = Mn2+ + 4H2O E0= 1.507 V
Chapter 3 Solutions
Introductory Chemistry: Concepts and Critical Thinking (8th Edition)
Ch. 3 - Prob. 1CECh. 3 - Prob. 2CECh. 3 - Prob. 3CECh. 3 - Prob. 4CECh. 3 - Prob. 5CECh. 3 - Prob. 6CECh. 3 - Prob. 7CECh. 3 - Prob. 8CECh. 3 - Prob. 9CECh. 3 - Prob. 10CE
Ch. 3 - Prob. 11CECh. 3 - Prob. 12CECh. 3 - Prob. 1KTCh. 3 - Prob. 2KTCh. 3 - Prob. 3KTCh. 3 - Prob. 4KTCh. 3 - Prob. 5KTCh. 3 - Prob. 6KTCh. 3 - Prob. 7KTCh. 3 - Prob. 8KTCh. 3 - Prob. 9KTCh. 3 - Prob. 10KTCh. 3 - Prob. 11KTCh. 3 - Prob. 12KTCh. 3 - Prob. 13KTCh. 3 - Prob. 14KTCh. 3 - Prob. 15KTCh. 3 - Prob. 16KTCh. 3 - Prob. 17KTCh. 3 - Prob. 18KTCh. 3 - Prob. 19KTCh. 3 - Prob. 20KTCh. 3 - Prob. 21KTCh. 3 - Prob. 22KTCh. 3 - Prob. 23KTCh. 3 - Prob. 24KTCh. 3 - Prob. 25KTCh. 3 - Prob. 26KTCh. 3 - Prob. 27KTCh. 3 - Prob. 28KTCh. 3 - Prob. 29KTCh. 3 - Prob. 30KTCh. 3 - Prob. 1ECh. 3 - Prob. 2ECh. 3 - Prob. 3ECh. 3 - Prob. 4ECh. 3 - Prob. 5ECh. 3 - Prob. 6ECh. 3 - Prob. 7ECh. 3 - Prob. 8ECh. 3 - Prob. 9ECh. 3 - Prob. 10ECh. 3 - Prob. 11ECh. 3 - Prob. 12ECh. 3 - Prob. 13ECh. 3 - Prob. 14ECh. 3 - Prob. 15ECh. 3 - Prob. 16ECh. 3 - Prob. 17ECh. 3 - Prob. 18ECh. 3 - Prob. 19ECh. 3 - Prob. 20ECh. 3 - Prob. 21ECh. 3 - Prob. 22ECh. 3 - Prob. 23ECh. 3 - Prob. 24ECh. 3 - Prob. 25ECh. 3 - Prob. 26ECh. 3 - Prob. 27ECh. 3 - Prob. 28ECh. 3 - Prob. 29ECh. 3 - Prob. 30ECh. 3 - Prob. 31ECh. 3 - Prob. 32ECh. 3 - Prob. 33ECh. 3 - Prob. 34ECh. 3 - Prob. 35ECh. 3 - Prob. 36ECh. 3 - Prob. 37ECh. 3 - Prob. 38ECh. 3 - Prob. 39ECh. 3 - Prob. 40ECh. 3 - Prob. 41ECh. 3 - Prob. 42ECh. 3 - Prob. 43ECh. 3 - Prob. 44ECh. 3 - Prob. 45ECh. 3 - Prob. 46ECh. 3 - Prob. 47ECh. 3 - Prob. 48ECh. 3 - Prob. 49ECh. 3 - Prob. 50ECh. 3 - Prob. 51ECh. 3 - Prob. 52ECh. 3 - Prob. 53ECh. 3 - Prob. 54ECh. 3 - Prob. 55ECh. 3 - Prob. 56ECh. 3 - Prob. 57ECh. 3 - Prob. 58ECh. 3 - Prob. 59ECh. 3 - Prob. 60ECh. 3 - Prob. 61ECh. 3 - Prob. 62ECh. 3 - Prob. 63ECh. 3 - Prob. 64ECh. 3 - Prob. 65ECh. 3 - Prob. 66ECh. 3 - Prob. 67ECh. 3 - Prob. 68ECh. 3 - Prob. 69ECh. 3 - Prob. 70ECh. 3 - Prob. 71ECh. 3 - Prob. 72ECh. 3 - Prob. 73ECh. 3 - Prob. 74ECh. 3 - Prob. 75ECh. 3 - Prob. 76ECh. 3 - Prob. 77ECh. 3 - Prob. 78ECh. 3 - Prob. 79ECh. 3 - Prob. 80ECh. 3 - Prob. 81ECh. 3 - Prob. 82ECh. 3 - Prob. 83ECh. 3 - Prob. 84ECh. 3 - Prob. 85ECh. 3 - Prob. 86ECh. 3 - Prob. 87ECh. 3 - Prob. 88ECh. 3 - Prob. 89ECh. 3 - Prob. 90ECh. 3 - Prob. 91ECh. 3 - Prob. 92ECh. 3 - Prob. 93ECh. 3 - Prob. 94ECh. 3 - Prob. 95ECh. 3 - Prob. 96ECh. 3 - Prob. 1STCh. 3 - Prob. 2STCh. 3 - Prob. 3STCh. 3 - Prob. 4STCh. 3 - Prob. 5STCh. 3 - Prob. 6STCh. 3 - Prob. 7STCh. 3 - Prob. 8STCh. 3 - Prob. 9STCh. 3 - Prob. 10STCh. 3 - Prob. 11STCh. 3 - Prob. 12STCh. 3 - Prob. 13STCh. 3 - Prob. 14STCh. 3 - Prob. 15STCh. 3 - Prob. 16STCh. 3 - Prob. 17STCh. 3 - Prob. 18STCh. 3 - Prob. 19STCh. 3 - Prob. 20ST
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Solutions: Crash Course Chemistry #27; Author: Crash Course;https://www.youtube.com/watch?v=9h2f1Bjr0p4;License: Standard YouTube License, CC-BY