Introductory Chemistry: Concepts and Critical Thinking (8th Edition)
8th Edition
ISBN: 9780134421377
Author: Charles H Corwin
Publisher: PEARSON
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Chapter 3, Problem 10E
Interpretation Introduction
(a)
Interpretation:
Whether the conversion of solid to liquid requires heating or cooling is to be stated.
Concept introduction:
Any substance in the universe which occupies volume and possesses mass is known as matter. It can be classified physically as well as chemically.
The physical classification of the matter is as follows:
• Solids
• Liquids
• Gases
The solid
Interpretation Introduction
(b)
Interpretation:
Whether the conversion of liquid to gas requires heating or cooling is to be stated.
Concept introduction:
Any substance in the universe which occupies volume and possesses mass is known as matter. It can be classified physically as well as chemically.
The physical classification of the matter is as follows:
• Solids
• Liquids
• Gases
The solid state of matter consists of a fixed shape and fixed volume. The liquid state of matter consists of a fixed volume but does not possess a fixed shape. This state of matter takes the shape of the vessel in which it is stored. The gaseous state of matter possesses neither a fixed volume nor a fixed shape.
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From the following potentials, calculate the activity of Cl- in saturated KCl.
E0 (calomel electrode)= 0.268 V
E (calomel electrode, saturated KCl)= 0.241 V
Calculate the voltage of each of the following cells.
a) Fe(s)/Fe2+ (1.55 x 10-2 M)//Cu2+ (6.55 x 10-3 M)/Cu(s)
b) Pt, H2 (0.255 bar)/HCl (4.55 x 10-4 M), AgCl (sat'd)/Ag
Fe2+ +2e- = Fe E0= -0.44 V
Cu2+ + 2e- = Cu E0= 0.337 V
Ag+ + e- = Ag E0= 0.799 V
AgCl(s) + e- = Ag(s) + Cl- E0= 0.222 V
2H+ + 2e- = H2 E0= 0.000 V
A solution contains 0.097 M Ce3+, 1.55x10-3 M Ce4+, 1.55x10-3 M Mn2+, 0.097 M MnO4-, and 1.00 M HClO4 (F= 9.649 x 104 C/mol).
a) Write a balanced net reaction that can occur between species in this solution.
b) Calculate deltaG0 and K for the reaction.
c) Calculate E and deltaG for the conditions given.
Ce4+ + e- = Ce3+ E0= 1.70 V
MnO4- + 8H+ + 5e- = Mn2+ + 4H2O E0= 1.507 V
Chapter 3 Solutions
Introductory Chemistry: Concepts and Critical Thinking (8th Edition)
Ch. 3 - Prob. 1CECh. 3 - Prob. 2CECh. 3 - Prob. 3CECh. 3 - Prob. 4CECh. 3 - Prob. 5CECh. 3 - Prob. 6CECh. 3 - Prob. 7CECh. 3 - Prob. 8CECh. 3 - Prob. 9CECh. 3 - Prob. 10CE
Ch. 3 - Prob. 11CECh. 3 - Prob. 12CECh. 3 - Prob. 1KTCh. 3 - Prob. 2KTCh. 3 - Prob. 3KTCh. 3 - Prob. 4KTCh. 3 - Prob. 5KTCh. 3 - Prob. 6KTCh. 3 - Prob. 7KTCh. 3 - Prob. 8KTCh. 3 - Prob. 9KTCh. 3 - Prob. 10KTCh. 3 - Prob. 11KTCh. 3 - Prob. 12KTCh. 3 - Prob. 13KTCh. 3 - Prob. 14KTCh. 3 - Prob. 15KTCh. 3 - Prob. 16KTCh. 3 - Prob. 17KTCh. 3 - Prob. 18KTCh. 3 - Prob. 19KTCh. 3 - Prob. 20KTCh. 3 - Prob. 21KTCh. 3 - Prob. 22KTCh. 3 - Prob. 23KTCh. 3 - Prob. 24KTCh. 3 - Prob. 25KTCh. 3 - Prob. 26KTCh. 3 - Prob. 27KTCh. 3 - Prob. 28KTCh. 3 - Prob. 29KTCh. 3 - Prob. 30KTCh. 3 - Prob. 1ECh. 3 - Prob. 2ECh. 3 - Prob. 3ECh. 3 - Prob. 4ECh. 3 - Prob. 5ECh. 3 - Prob. 6ECh. 3 - Prob. 7ECh. 3 - Prob. 8ECh. 3 - Prob. 9ECh. 3 - Prob. 10ECh. 3 - Prob. 11ECh. 3 - Prob. 12ECh. 3 - Prob. 13ECh. 3 - Prob. 14ECh. 3 - Prob. 15ECh. 3 - Prob. 16ECh. 3 - Prob. 17ECh. 3 - Prob. 18ECh. 3 - Prob. 19ECh. 3 - Prob. 20ECh. 3 - Prob. 21ECh. 3 - Prob. 22ECh. 3 - Prob. 23ECh. 3 - Prob. 24ECh. 3 - Prob. 25ECh. 3 - Prob. 26ECh. 3 - Prob. 27ECh. 3 - Prob. 28ECh. 3 - Prob. 29ECh. 3 - Prob. 30ECh. 3 - Prob. 31ECh. 3 - Prob. 32ECh. 3 - Prob. 33ECh. 3 - Prob. 34ECh. 3 - Prob. 35ECh. 3 - Prob. 36ECh. 3 - Prob. 37ECh. 3 - Prob. 38ECh. 3 - Prob. 39ECh. 3 - Prob. 40ECh. 3 - Prob. 41ECh. 3 - Prob. 42ECh. 3 - Prob. 43ECh. 3 - Prob. 44ECh. 3 - Prob. 45ECh. 3 - Prob. 46ECh. 3 - Prob. 47ECh. 3 - Prob. 48ECh. 3 - Prob. 49ECh. 3 - Prob. 50ECh. 3 - Prob. 51ECh. 3 - Prob. 52ECh. 3 - Prob. 53ECh. 3 - Prob. 54ECh. 3 - Prob. 55ECh. 3 - Prob. 56ECh. 3 - Prob. 57ECh. 3 - Prob. 58ECh. 3 - Prob. 59ECh. 3 - Prob. 60ECh. 3 - Prob. 61ECh. 3 - Prob. 62ECh. 3 - Prob. 63ECh. 3 - Prob. 64ECh. 3 - Prob. 65ECh. 3 - Prob. 66ECh. 3 - Prob. 67ECh. 3 - Prob. 68ECh. 3 - Prob. 69ECh. 3 - Prob. 70ECh. 3 - Prob. 71ECh. 3 - Prob. 72ECh. 3 - Prob. 73ECh. 3 - Prob. 74ECh. 3 - Prob. 75ECh. 3 - Prob. 76ECh. 3 - Prob. 77ECh. 3 - Prob. 78ECh. 3 - Prob. 79ECh. 3 - Prob. 80ECh. 3 - Prob. 81ECh. 3 - Prob. 82ECh. 3 - Prob. 83ECh. 3 - Prob. 84ECh. 3 - Prob. 85ECh. 3 - Prob. 86ECh. 3 - Prob. 87ECh. 3 - Prob. 88ECh. 3 - Prob. 89ECh. 3 - Prob. 90ECh. 3 - Prob. 91ECh. 3 - Prob. 92ECh. 3 - Prob. 93ECh. 3 - Prob. 94ECh. 3 - Prob. 95ECh. 3 - Prob. 96ECh. 3 - Prob. 1STCh. 3 - Prob. 2STCh. 3 - Prob. 3STCh. 3 - Prob. 4STCh. 3 - Prob. 5STCh. 3 - Prob. 6STCh. 3 - Prob. 7STCh. 3 - Prob. 8STCh. 3 - Prob. 9STCh. 3 - Prob. 10STCh. 3 - Prob. 11STCh. 3 - Prob. 12STCh. 3 - Prob. 13STCh. 3 - Prob. 14STCh. 3 - Prob. 15STCh. 3 - Prob. 16STCh. 3 - Prob. 17STCh. 3 - Prob. 18STCh. 3 - Prob. 19STCh. 3 - Prob. 20ST
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