Principles of Physics: A Calculus-Based Text
5th Edition
ISBN: 9781133104261
Author: Raymond A. Serway, John W. Jewett
Publisher: Cengage Learning
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Chapter 29, Problem 8OQ
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Two electrons in the same atom have n = 3 and l = 1. (a) List
the quantum numbers for the possible states of the atom.
(b) How many states would be possible if the exclusion prin-
ciple did not apply to the atom?
(a) If one subshell of an atom has 9 electrons in it, what is the minimum value of l ? (b) What is the spectroscopic notation for this atom, if this subshell is part of the n = 3shell?
(a) Using Bohr’s second postulate of quantization of orbital angular momentum show that the circumference of the electron in the n,h orbital state in hydrogen atom is n times the de-Broglie wavelength associated with it.
(b) The electron in hydrogen atom is initially in the third excited state. What is the maximum number of spectral lines which can be emitted when it finally moves to the ground state?
Chapter 29 Solutions
Principles of Physics: A Calculus-Based Text
Ch. 29.2 - Prob. 29.1QQCh. 29.2 - Prob. 29.2QQCh. 29.4 - Prob. 29.3QQCh. 29.5 - Prob. 29.4QQCh. 29.6 - Prob. 29.5QQCh. 29.6 - Prob. 29.6QQCh. 29 - Prob. 1OQCh. 29 - Prob. 2OQCh. 29 - Prob. 3OQCh. 29 - Prob. 4OQ
Ch. 29 - Prob. 5OQCh. 29 - Prob. 6OQCh. 29 - Prob. 7OQCh. 29 - Prob. 8OQCh. 29 - Prob. 9OQCh. 29 - Prob. 10OQCh. 29 - Prob. 1CQCh. 29 - Prob. 2CQCh. 29 - Prob. 3CQCh. 29 - Prob. 4CQCh. 29 - Prob. 5CQCh. 29 - Prob. 6CQCh. 29 - Prob. 7CQCh. 29 - Prob. 8CQCh. 29 - Prob. 9CQCh. 29 - Prob. 10CQCh. 29 - Prob. 1PCh. 29 - Prob. 2PCh. 29 - Prob. 3PCh. 29 - Prob. 4PCh. 29 - Prob. 5PCh. 29 - Prob. 6PCh. 29 - Prob. 7PCh. 29 - Prob. 8PCh. 29 - Prob. 10PCh. 29 - Prob. 11PCh. 29 - Prob. 12PCh. 29 - Prob. 13PCh. 29 - Prob. 14PCh. 29 - Prob. 15PCh. 29 - Prob. 16PCh. 29 - Prob. 17PCh. 29 - Prob. 18PCh. 29 - Prob. 19PCh. 29 - Prob. 20PCh. 29 - Prob. 21PCh. 29 - Prob. 22PCh. 29 - Prob. 23PCh. 29 - Prob. 24PCh. 29 - Prob. 25PCh. 29 - Prob. 26PCh. 29 - Prob. 27PCh. 29 - Prob. 28PCh. 29 - Prob. 29PCh. 29 - Prob. 30PCh. 29 - Prob. 31PCh. 29 - Prob. 32PCh. 29 - Prob. 33PCh. 29 - Prob. 34PCh. 29 - Prob. 35PCh. 29 - Prob. 36PCh. 29 - Prob. 37PCh. 29 - Prob. 38PCh. 29 - Prob. 39PCh. 29 - Prob. 40PCh. 29 - Prob. 41PCh. 29 - Prob. 42PCh. 29 - Prob. 43PCh. 29 - Prob. 44PCh. 29 - Prob. 45PCh. 29 - Prob. 46PCh. 29 - Prob. 47PCh. 29 - Prob. 48PCh. 29 - Prob. 49PCh. 29 - Prob. 50PCh. 29 - Prob. 51PCh. 29 - Prob. 52PCh. 29 - Prob. 53PCh. 29 - Prob. 54PCh. 29 - Prob. 55PCh. 29 - Prob. 57PCh. 29 - Prob. 58PCh. 29 - Prob. 59PCh. 29 - Prob. 60PCh. 29 - Prob. 61PCh. 29 - Prob. 63PCh. 29 - Prob. 64PCh. 29 - Prob. 65PCh. 29 - Prob. 66P
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- An electron in the hydrogen atom makes a transition from an energy state of principal quantum number ni to the n = 2 state. If the photon emitted has a wavelength of 434 nm, what is the value of ni? Enter just the value of ni, and not the whole expression (e.g., do not enter n = 2).arrow_forwardA free electron with kinetic energy 12eV collides with a Hydrogen atom and causes the atom to be raised to the first excited state. Given that the ground state energy is -13.6 eV and the first excited state energy is -3.4 eV, calculate: a) The kinetic energy of the free electron after the collision. b) The wavelength of the photon emitted when the atom returns to the ground state. [Assume speed of light c = 3x108 m/s, Planck constant h = 4.14 x 10-¹5 ev s]arrow_forward(a) The Lyman series in hydrogen is the transition from energy levels n = 2, 3, 4, ... to the ground state n = 1. The energy levels are given by 13.60 eV En n- (i) What is the second longest wavelength in nm of the Lyman series? (ii) What is the series limit of the Lyman series? [1 eV = 1.602 x 1019 J, h = 6.626 × 10-34 J.s, c = 3 × 10° m.s] %3D Two emission lines have wavelengts A and + A2, respectively, where AA <<2. Show that the angular separation A0 in a grating spectrometer is given aproximately by (b) A0 = V(d/m)-2 where d is the grating constant and m is the order at which the lines are observed.arrow_forward
- Consider a 1s electron in a hydrogen atom where the wave function is given by 1 -#()*** e Y15 = (a) Calculate the most probable value, 'mp, of finding the electron. (b) Calculate the average value, (r), of finding the electron. (c) Plot both the probability density and the total radial probability density vs. distance in units of Bohr radii for the 1s orbital.arrow_forwardSuppose two electrons in an atom have quantum numbers n= 2 and L=1 . (a) How many states are possible for those two electrons? (Keep in mind that the electrons are indistinguishable.) (b) If the Pauli exclusion principle did not apply to the electrons, how many states would be possible?arrow_forwardTwo electrons in the same atom have n = 3 and ℓ = 1. (a) List the quantum numbers for the possible states of the atom. (b) How many states would be possible if the exclusion principle did not apply to the atom?arrow_forward
- The average value (or expected value) of r^k, where r is the distance of an electron in the state with principal quantum number n and orbital quantum number leo proton in the hydrogen atom is given by the integral below, where Pnl(r) is a radial probability density of the state with quantum number n, lek is an arbitrary power. For an electron in the ground state of the hydrogen atom. a) calculate <r>nl in terms of the Bohr radius aB b) calculate <l/r>nl in terms of aB c) calculate <U(r)>nl, where U(r) = -e^2/(4piE0r). Respond in eV units. d) Considering also that the electron is in the ground state, estimate the expected value for two kinetic energy <K> and its mean quadratic velocity v. e) Is it justifiable to disregard relativistic corrections for this system? Justify.arrow_forwardAn electron is in the nth Bohr orbit of the hydrogen atom. (a) Show that the period of the electron is T = n3t0 and determine the numerical value of t0. (b) On average, an electron remains in the n = 2 orbit for approximately 10 ms before it jumps down to the n = 1 (ground-state) orbit. How many revolutions does the electron make in the excited state? (c) Define the period of one revolution as an electron year, analogous to an Earth year being the period of the Earth’s motion around the Sun. Explain whether we should think of the electron in the n = 2 orbit as “living for a long time.”arrow_forwardH-atom. The wave function of one of the electrons in the 2p orbital is given by (ignoring spin) r 2,1,0 (1,0,0)= - 7 exp(-270) c ao 1 |32πα cose Where do is the Bohr radius. In the Bohr model, the radius of the electron orbit is given by m=2 = n²ao = 4ao. The probability that the electron can be found at some radius between r and r + dr is given by 2π P(r) dr = √2 = √ ₁²ª d$ S ² What is the expectation value of the distance of the electron from the nucleus (r)? Clue: expected value is computed by (r) = forP(r) dr then do integration by parts do sin 0 de | Yn.l.m² (r, $,0)|²r² drarrow_forward
- Two electrons in the same atom both have n = 6 and l = 1. Assume the electrons are distinguishable, so that interchanging them defines a new state. (a) How many states of the atom are possible considering the quantum numbers these two electrons can have? (b) How many states would be possible if the exclusion principle were inoperative?arrow_forwardConsider a large number of hydrogen atoms, with electrons all initially in the n = 4 state. (a) How many different wavelengths would be observed in the emission spectrum of these atoms? (b) What is the longest wavelength that could be observed? (c) To which series does the wavelength found in (b) belong?arrow_forwardThe wave function for the Is state of an electron in the hydrogen atom is VIs(P) = e-p/ao where ao is the Bohr radius. The probability of finding the electron in a region W of R³ is equal to J, P(x, y, 2) dV where, in spherical coordinates, p(p) = |V1s(P)² Use integration in spherical coordinates to show that the probability of finding the electron at a distance greater than the Bohr radius is equal to 5/e = 0.677. (The Bohr radius is ao =5.3 x 10-1" m, but this value is not needed.)arrow_forward
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