Interpretation:
An orbital symmetry analysis that a [3.3] sigmatropic reaction that is antrafacial on both components is allowed is to be shown. Would you expect such a reaction to be very common- the statement is to be verified.
Concept introduction:
Sigmatropic reaction can be described as the migration of allylic sigma bond at one end of the π-electron system to the other end of the π-electron system as an uncatalyzed intramolecular reaction. In some cases, Lewis acid catalysts can also be applied. Though, the position of π-bond is changed in Sigmatropic reaction, the total number of π-bonds remain unchanged. The sigma bond can be cleaved at the middle or at the end of the π-system. The formation of sigma bond at 3, 3-position of a 1, 5-diene is called as cope rearrangement.

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Chapter 28 Solutions
ORGANIC CHEMISTRY SAPLING ACCESS + ETEX
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- Physical ChemistryChemistryISBN:9781133958437Author:Ball, David W. (david Warren), BAER, TomasPublisher:Wadsworth Cengage Learning,
