(a) Interpretation: The reason as to why the unpaired electron in the allyl radical is delocalized over C1, C3 positions with the help of resonance structures is to be stated. Concept introduction: Most of the organic structures cannot be represented using a single Lewis structure. Therefore, there exists more than one Lewis structure for representing a molecule or ion. These structures are known as resonance structures. The delocalization of electrons results in the formation of resonance structure.

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Answer 1

Question

Chapter 28, Problem 28.5P

Interpretation Introduction

(a)

Interpretation:

The reason as to why the unpaired electron in the allyl radical is delocalized over C1, C3 positions with the help of resonance structures is to be stated.

Concept introduction:

Most of the organic structures cannot be represented using a single Lewis structure. Therefore, there exists more than one Lewis structure for representing a molecule or ion. These structures are known as resonance structures. The delocalization of electrons results in the formation of resonance structure.

Interpretation Introduction

(b)

Interpretation:

The reason as to why the unpaired electron in the allyl radical is delocalized over C1, C3 positions with the help of molecular orbital arguments is to be stated.

Concept introduction:

The molecular orbital is a combination of two atomic orbitals. It is used to represent the regions in a molecule where the electron is likely to be present in an orbital. It represents the wave-like nature of an electron in a molecule.

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MISSED THIS? Read Section 19.9 (Pages 878-881); Watch IWE 19.10 Consider the following reaction: CH3OH(g) CO(g) + 2H2(g) (Note that AG,CH3OH(g) = -162.3 kJ/mol and AG,co(g)=-137.2 kJ/mol.) Part A Calculate AG for this reaction at 25 °C under the following conditions: PCH₂OH Pco PH2 0.815 atm = 0.140 atm 0.170 atm Express your answer in kilojoules to three significant figures. Ο ΑΣΦ AG = -150 Submit Previous Answers Request Answer □? kJ × Incorrect; Try Again; 2 attempts remaining Calculate the free energy change under nonstandard conditions (AGrxn) by using the following relationship: AGrxn = AGrxn + RTInQ, AGxn+RTInQ, where AGxn is the standard free energy change, R is the ideal gas constant, T is the temperature in kelvins, a is the reaction quotient. Provide Feedback Next >

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Answer 2

Question

Chapter 28, Problem 28.5P

Interpretation Introduction

(a)

Interpretation:

The reason as to why the unpaired electron in the allyl radical is delocalized over C1, C3 positions with the help of resonance structures is to be stated.

Concept introduction:

Most of the organic structures cannot be represented using a single Lewis structure. Therefore, there exists more than one Lewis structure for representing a molecule or ion. These structures are known as resonance structures. The delocalization of electrons results in the formation of resonance structure.

Interpretation Introduction

(b)

Interpretation:

The reason as to why the unpaired electron in the allyl radical is delocalized over C1, C3 positions with the help of molecular orbital arguments is to be stated.

Concept introduction:

The molecular orbital is a combination of two atomic orbitals. It is used to represent the regions in a molecule where the electron is likely to be present in an orbital. It represents the wave-like nature of an electron in a molecule.

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Answer 3

Question

Chapter 28, Problem 28.5P

Interpretation Introduction

(a)

Interpretation:

The reason as to why the unpaired electron in the allyl radical is delocalized over C1, C3 positions with the help of resonance structures is to be stated.

Concept introduction:

Most of the organic structures cannot be represented using a single Lewis structure. Therefore, there exists more than one Lewis structure for representing a molecule or ion. These structures are known as resonance structures. The delocalization of electrons results in the formation of resonance structure.

Interpretation Introduction

(b)

Interpretation:

The reason as to why the unpaired electron in the allyl radical is delocalized over C1, C3 positions with the help of molecular orbital arguments is to be stated.

Concept introduction:

The molecular orbital is a combination of two atomic orbitals. It is used to represent the regions in a molecule where the electron is likely to be present in an orbital. It represents the wave-like nature of an electron in a molecule.

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Answer 4

Question

Chapter 28, Problem 28.5P

Interpretation Introduction

(a)

Interpretation:

The reason as to why the unpaired electron in the allyl radical is delocalized over C1, C3 positions with the help of resonance structures is to be stated.

Concept introduction:

Most of the organic structures cannot be represented using a single Lewis structure. Therefore, there exists more than one Lewis structure for representing a molecule or ion. These structures are known as resonance structures. The delocalization of electrons results in the formation of resonance structure.

Interpretation Introduction

(b)

Interpretation:

The reason as to why the unpaired electron in the allyl radical is delocalized over C1, C3 positions with the help of molecular orbital arguments is to be stated.

Concept introduction:

The molecular orbital is a combination of two atomic orbitals. It is used to represent the regions in a molecule where the electron is likely to be present in an orbital. It represents the wave-like nature of an electron in a molecule.

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Answer 5

Chapter 28, Problem 28.5P

Interpretation Introduction

(a)

Interpretation:

The reason as to why the unpaired electron in the allyl radical is delocalized over C1, C3 positions with the help of resonance structures is to be stated.

Concept introduction:

Most of the organic structures cannot be represented using a single Lewis structure. Therefore, there exists more than one Lewis structure for representing a molecule or ion. These structures are known as resonance structures. The delocalization of electrons results in the formation of resonance structure.

Interpretation Introduction

(b)

Interpretation:

The reason as to why the unpaired electron in the allyl radical is delocalized over C1, C3 positions with the help of molecular orbital arguments is to be stated.

Concept introduction:

The molecular orbital is a combination of two atomic orbitals. It is used to represent the regions in a molecule where the electron is likely to be present in an orbital. It represents the wave-like nature of an electron in a molecule.

Answer 6

Chapter 28, Problem 28.5P

Interpretation Introduction

(a)

Interpretation:

The reason as to why the unpaired electron in the allyl radical is delocalized over C1, C3 positions with the help of resonance structures is to be stated.

Concept introduction:

Most of the organic structures cannot be represented using a single Lewis structure. Therefore, there exists more than one Lewis structure for representing a molecule or ion. These structures are known as resonance structures. The delocalization of electrons results in the formation of resonance structure.

Answer 7

Chapter 28, Problem 28.5P

Interpretation Introduction

(a)

Interpretation:

The reason as to why the unpaired electron in the allyl radical is delocalized over C1, C3 positions with the help of resonance structures is to be stated.

Concept introduction:

Most of the organic structures cannot be represented using a single Lewis structure. Therefore, there exists more than one Lewis structure for representing a molecule or ion. These structures are known as resonance structures. The delocalization of electrons results in the formation of resonance structure.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The reason as to why the unpaired electron in the allyl radical is delocalized over C1, C3 positions with the help of molecular orbital arguments is to be stated.

Concept introduction:

The molecular orbital is a combination of two atomic orbitals. It is used to represent the regions in a molecule where the electron is likely to be present in an orbital. It represents the wave-like nature of an electron in a molecule.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The reason as to why the unpaired electron in the allyl radical is delocalized over C1, C3 positions with the help of molecular orbital arguments is to be stated.

Concept introduction:

The molecular orbital is a combination of two atomic orbitals. It is used to represent the regions in a molecule where the electron is likely to be present in an orbital. It represents the wave-like nature of an electron in a molecule.

Answer 10

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Answer 13

Ch. 28 - Prob. 28.1P Ch. 28 - Prob. 28.2P Ch. 28 - Prob. 28.3P Ch. 28 - Prob. 28.4P Ch. 28 - Prob. 28.5P Ch. 28 - Prob. 28.6P Ch. 28 - Prob. 28.7P Ch. 28 - Prob. 28.8P Ch. 28 - Prob. 28.9P Ch. 28 - Prob. 28.10P

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