ORGANIC CHEMISTRY-PACKAGE >CUSTOM<
ORGANIC CHEMISTRY-PACKAGE >CUSTOM<
10th Edition
ISBN: 9781260028355
Author: Carey
Publisher: MCG CUSTOM
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Chapter 26, Problem 37P
Interpretation Introduction

Interpretation:

The five amino acids which are contained in given synthetic peptide are to be identified.

Concept Introduction:

A peptide bond is an amide bond. A dipeptide contains two amino acids linked by a peptide bond.

It is formed between the amino group of one amino acid and the carboxyl group of the other amino acid.

The peptide structures are written, such that the amino group is at the left side and the carboxyl group is at the right side.

The left end of the peptide is called the N terminus and the right end is called the C terminus.

Each amino acid contains an amino group and a carboxylic acid group attached to the same carbon atom.

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Predict the reactants used in the formation of the following compounds using Acid-Catalyzed dehydration reaction
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.. Give the major organic product(s) for each of the following reactions or sequences of reactions. Show ll relevant stereochemistry [3 ONLY]. A H Br 1. NaCN 2 NaOH, H₂O, heat 3. H3O+ B. CH₂COOH 19000 1. LiAlH4 THF, heat 2 H₂O* C. CH Br 1. NaCN, acetone 2 H3O+, heat D. Br 1. Mg. ether 3. H₂O+ 2 CO₂ E. CN 1. (CH) CHMgBr, ether 2 H₂O+
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