Organic Chemistry
Organic Chemistry
8th Edition
ISBN: 9781305580350
Author: William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher: Cengage Learning
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Chapter 26, Problem 26.30P
Interpretation Introduction

Interpretation:

The hydrophobic and hydrophilic regions of a lecithin have to be identified.  Also, the region with which oils interact in making mayonnaise and interaction of water has to be identified.

Concept-Introduction:

Hydrophobic:

  • Hydrophobic means repelling of water molecules. Hydrophobic molecules are insoluble in water and non-polar in nature.
  • Due to its non-solvation, hydrophobic molecules aggregate in polar solvents like water.
  • This aggregation of hydrophobic molecules leads to membrane formation, surfactant action, protein folding, and protein-protein recognition.

Hydrophilic:

Hydrophilic molecules tend to attract water molecules. These are water soluble and mostly polar in nature.

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f) The unusual molecule [2.2.2] propellane is pictured. 1) Given the bond length and bond angles in the image, what hybridization scheme best describes the carbons marked by the askerisks? 2) What types of orbitals are used in the bond between the two carbons marked by the askerisks? 3) How does this bond compare to an ordinary carbon-carbon bond (which is usually 1.54 Å long)? CH2 1.60Å H₂C * H₂C CH2 C H2C * C Of H₂ 120°
e) Determine the hybridization and geometry around the indicated carbon atoms. H3C CH3 B HC CH2 A C C C CH3
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