Organic Chemistry
Organic Chemistry
8th Edition
ISBN: 9781305580350
Author: William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher: Cengage Learning
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Chapter 26, Problem 26.2P
Interpretation Introduction

Interpretation:

The term hydrophobic has to be defined.

Expert Solution & Answer
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Explanation of Solution

  • Hydrophobic means repelling of water molecules. Hydrophobic molecules are insoluble in water and non-polar in nature.
  • Due to its non-solvation, hydrophobic molecules aggregate in polar solvents like water.
  • This aggregation of hydrophobic molecules leads to membrane formation, surfactant action, protein folding, and protein-protein recognition.

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(a) Show that the lattice energies are inversely proportional to the distance between ions in MX (M = alkali metal, X = halide ions) by plotting the lattice energies of KF, KCl, and KI against the internuclear distances, dMX. The lattice energies of KF, KCl, and KI are 826, 717, and 645 kJ/mol, respectively. Does the correlation obtained correlate well? You will need to use a standard graphing program to construct the graph (such as a spreadsheet program). It will generate an equation for the line and calculate a correlation coefficient. (b) Estimate the lattice energy of KBr from your graph. (c) Find an experimental value for the lattice energy of KBr in the literature, and compare this value with the one calculated in (b). Do they agree?
Show the curved arrow mechanism and both products for the reaction between methyl iodide and propoxide. 1st attempt NV H 10: H H 1 Add the missing curved arrow notation. H + See Periodic Table
First I wanted to see if you would mind checking my graphs behind me. (They haven't been coming out right)? Second, could you help me explain if the rate of reaction is proportional to iodide and persulfate of each graph. I highlighted my answer and understanding but I'm not sure if I'm on the right track. Thank you in advance.
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