Organic Chemistry
Organic Chemistry
8th Edition
ISBN: 9781305580350
Author: William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher: Cengage Learning
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Chapter 26, Problem 26.12P
Interpretation Introduction

Interpretation:

The detergent properties of benzyldimethyloctylammonium chloride and pentaerythrityl palmitate have to be accounted.

Concept-Introduction:

Properties of detergent:

  • A combination of long hydrocarbon tail and very large polar head at one end is ideal for good synthetic detergent. 
  • This combination leads to formation of micelle structures in aqueous solution, which dissolves hydrophobic dirt like grease and oil.
  • The polar end group does not form insoluble salts in ions generally found in hard water such as Ca2+,Mg2+,andFe3+

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f) The unusual molecule [2.2.2] propellane is pictured. 1) Given the bond length and bond angles in the image, what hybridization scheme best describes the carbons marked by the askerisks? 2) What types of orbitals are used in the bond between the two carbons marked by the askerisks? 3) How does this bond compare to an ordinary carbon-carbon bond (which is usually 1.54 Å long)? CH2 1.60Å H₂C * H₂C CH2 C H2C * C Of H₂ 120°
e) Determine the hybridization and geometry around the indicated carbon atoms. H3C CH3 B HC CH2 A C C C CH3
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