Introduction to General, Organic and Biochemistry
11th Edition
ISBN: 9781285869759
Author: Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
Publisher: Cengage Learning
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Textbook Question
Chapter 25, Problem 25.55P
25-55 A DNA molecule normally replicates itself millions
Of times, with almost no errors. What single fact
about the structure is most responsible for this fidel-
ity of replication?
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Draw the major substitution products you would expect for the reaction shown below. If substitution would not occur at a significant
rate under these conditions, check the box underneath the drawing area instead.
Be sure you use wedge and dash bonds where necessary, for example to distinguish between major products.
Note for advanced students: you can assume that the reaction mixture is heated mildly, somewhat above room temperature, but
strong heat or reflux is not used.
Cl
C
O Substitution will not occur at a significant rate.
Explanation
Check
+
O-CH3
Х
Click and drag to start
drawing a structure.
✓ aw the major substitution products you would expect for the reaction shown below. If substitution would not occur at a significant
rate under these conditions, check the box underneath the drawing area instead.
Be sure you use wedge and dash bonds where necessary, for example to distinguish between major products.
Note for advanced students: you can assume that the reaction mixture is heated mildly, somewhat above room temperature, but
strong heat or reflux is not used.
C
Cl
HO–CH
O Substitution will not occur at a significant rate.
Explanation
Check
-3
☐ :
+
D
Click and drag to start
drawing a structure.
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Chapter 25 Solutions
Introduction to General, Organic and Biochemistry
Ch. 25.2 - Problem 25-1 Draw the structure of UMP.Ch. 25 - 25-2 What structures Of the cell, visible in a...Ch. 25 - 25-3 Name one hereditary disease.Ch. 25 - 25-4 What is the basis unit of heredity?Ch. 25 - 25-5 (a) Where in a cell is the DNA located? (b)...Ch. 25 - 25-6 What are the components of (a) a nucleotide...Ch. 25 - 25-7 What are the differences between DNA and RNA?Ch. 25 - 25-8 Draw the structures of ADP and GDP. Are these...Ch. 25 - Prob. 25.9PCh. 25 - 25-10 Which DNA and RNA bases contain a carbonyl...
Ch. 25 - Prob. 25.11PCh. 25 - Prob. 25.12PCh. 25 - Prob. 25.13PCh. 25 - Prob. 25.14PCh. 25 - Prob. 25.15PCh. 25 - Prob. 25.16PCh. 25 - Prob. 25.17PCh. 25 - 25-18 What type of bond connects the base to the...Ch. 25 - Prob. 25.19PCh. 25 - 25-20 What constitutes the backbone of DNA?Ch. 25 - Prob. 25.21PCh. 25 - 25-22 In DNA, which carbon atoms of...Ch. 25 - 25-23 The sequence Of a short DNA segment is...Ch. 25 - Prob. 25.24PCh. 25 - Prob. 25.25PCh. 25 - Prob. 25.26PCh. 25 - Prob. 25.27PCh. 25 - Prob. 25.28PCh. 25 - 25-29 What constitutes the superstructure of...Ch. 25 - 25-30 What is the primary structure of DNA?Ch. 25 - 25-31 What is the secondary structure of DNA?Ch. 25 - 25-32 What is the major groove of a DNA helix?Ch. 25 - 25-33 What are the higher-order structures of DNA...Ch. 25 - 25-34 Which type Of RNA has enzyme activity? Where...Ch. 25 - 25-35 Which has the longest chains: tRNA, mRNA, or...Ch. 25 - 25-36 Which type of RNA contains modified...Ch. 25 - 25-37 Which type Of RNA has a sequence exactly...Ch. 25 - 25-38 Where is rRNA located in the cell?Ch. 25 - Prob. 25.39PCh. 25 - Prob. 25.40PCh. 25 - Prob. 25.41PCh. 25 - Prob. 25.42PCh. 25 - Prob. 25.43PCh. 25 - 25-44 What is IncRNA and what does it do?Ch. 25 - Prob. 25.45PCh. 25 - Prob. 25.46PCh. 25 - Prob. 25.47PCh. 25 - Prob. 25.48PCh. 25 - Prob. 25.49PCh. 25 - 25-50 Define: (a) Intron (b) ExonCh. 25 - 25-51 Does mRNA also have introns and exons?...Ch. 25 - Prob. 25.52PCh. 25 - Prob. 25.53PCh. 25 - 25-54 Do all genes code for a protein? If not,...Ch. 25 - 25-55 A DNA molecule normally replicates itself...Ch. 25 - 25-56 Which functional groups on the bases form...Ch. 25 - Prob. 25.57PCh. 25 - 25-58 Draw the structures of cytosine and guanine...Ch. 25 - 25-59 How many different bases are present in a...Ch. 25 - Prob. 25.60PCh. 25 - 25-61 Why is replication called semiconservative?Ch. 25 - 25-62 How does the removal of some positive...Ch. 25 - 25-63 Write the chemical reaction for the...Ch. 25 - Prob. 25.64PCh. 25 - 25-65 What are helicases? What is their function?Ch. 25 - 25-66 Can dATP Serve as a source for a primer?Ch. 25 - Prob. 25.67PCh. 25 - Prob. 25.68PCh. 25 - 25-69 In which direction is the DNA molecule...Ch. 25 - Prob. 25.70PCh. 25 - Prob. 25.71PCh. 25 - Prob. 25.72PCh. 25 - 25-73 From the perspective of the chain being...Ch. 25 - Prob. 25.74PCh. 25 - Prob. 25.75PCh. 25 - 25-76 When cytosine is deaminated, uracil is...Ch. 25 - Prob. 25.77PCh. 25 - 25-78 What are AP sites? Which enzyme creates...Ch. 25 - Prob. 25.79PCh. 25 - Prob. 25.80PCh. 25 - Prob. 25.81PCh. 25 - Prob. 25.82PCh. 25 - Prob. 25.83PCh. 25 - Prob. 25.84PCh. 25 - Prob. 25.85PCh. 25 - Prob. 25.86PCh. 25 - Prob. 25.87PCh. 25 - 25-88 (Chemical Connections 25B) How does...Ch. 25 - Prob. 25.89PCh. 25 - Prob. 25.90PCh. 25 - Prob. 25.91PCh. 25 - Prob. 25.92PCh. 25 - Prob. 25.93PCh. 25 - 25-94 (Chemical Connection 25D) What would be some...Ch. 25 - Prob. 25.95PCh. 25 - (Chemical Connection 25D) Why might a person make...Ch. 25 - Prob. 25.97PCh. 25 - Prob. 25.98PCh. 25 - Prob. 25.99PCh. 25 - Prob. 25.100PCh. 25 - Prob. 25.101PCh. 25 - Prob. 25.102PCh. 25 - Prob. 25.103PCh. 25 - -104 Why is it important that a DNA molecule be...Ch. 25 - Prob. 25.105PCh. 25 - Prob. 25.106PCh. 25 - Prob. 25.107PCh. 25 - Prob. 25.108PCh. 25 - -109 In sheep DNA, the mol% of adenine (A) was...Ch. 25 - Prob. 25.110PCh. 25 - Prob. 25.111PCh. 25 - Prob. 25.112PCh. 25 - Prob. 25.113PCh. 25 - -114 How could life have evolved if DNA leads to...Ch. 25 - Prob. 25.115PCh. 25 - Prob. 25.116PCh. 25 - Prob. 25.117P
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Nucleic acids - DNA and RNA structure; Author: MEDSimplified;https://www.youtube.com/watch?v=0lZRAShqft0;License: Standard YouTube License, CC-BY