Introduction to General, Organic and Biochemistry
11th Edition
ISBN: 9781285869759
Author: Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
Publisher: Cengage Learning
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Chapter 25, Problem 25.45P
Interpretation Introduction
Interpretation:
Interpret difference between lnc rna and mrna.
Concept Introduction:
RNA is known as ribonucleic acid and it consist of ribose sugar which is attached with nitrogenous bases and phosphate group.
Genetic information gets transferred from RNA to protein by linking the amino acids. Several steps take place where mRNA helps in connecting various amino acids into a peptide chain to form a protein molecule.
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Part VII. The H-NMR of a compound with molecular formula C5 H 10 O2 is given below.
Find the following:
(a) The no. of protons corresponding to each signal in the spectra
(6) Give the structure of the compound and assign the signals to each
proton in the compound.
a
70.2
Integration Values
C5H10O2
b
47.7
C
46.5
d
69.5
3.6 3.5
3.4 3.3 3.2 3.1 3.0
2.9 2.8
2.7
2.6 2.5
2.4 2.3 2.2 2.1 2.0
Chemical Shift (ppm)
1.9
1.8
1.7 1.6
1.5
1.4 1.3 1.2
1.1 1.0
0.9 0.8
Part 111. 1 H-NMR spectrum of a compound with integration values in red is given below.
Answer the following:
(a) write the signals in the 'H-NMR spectrum to the corresponding protons on the structure
of the molecule below.
(b) Identify the theoretical multiplicities for each proton in the compound. Also give the possible.
complex splitting patterns assuming J values are not similar.
там
Br
22
2
3
6
4 7.2 7.0 6.8 6.6 6.4 6.2 6.0 5.8 5.6 5.4 5.2 5.0 4.8 4.6 4.4 4.2 4.0 3.8 3.6 3.4 3.2 3.0 2.8 2.6 2.4 2.2 2.0 1.8 1.6 1.4 1.2 1.0 0.8 0
Chemical Shift (ppm)
ra.
Br
2
3
6
6
2.5
2.4
2.3
2.2
2.1
2.0
1.9
1.8
1.7
1.6
1.5
1.4
1.3
1.2
1.1
1.0
0.9
0.8
Chemical Shift (ppm)
2
2
Br
7.3
7.2
7.1
7.0 6.9
6.7 6.6 6.5
6.4
6.3
6.2
6.1
6.0
Chemical Shift (ppm)
5.9
5.8 5.7
5.5 5.4 5.3 5.2
5.0 4.9
1600°
1538°C
1493°C
In the diagram, the letter L indicates
that it is a liquid. Indicate its
components in the upper region
where only L is indicated.
The
iron-iron carbide phase
diagram.
Temperature (°C)
1400
8
1394°C
y+L
1200
2.14
y, Austenite
10000
912°C
800a
0.76
0.022
600
400
(Fe)
a, Ferrite
Composition (at% C)
15
1147°C
a + Fe3C
2
3
Composition (wt% C)
L
2500
4.30
2000
y + Fe3C
727°C
1500
Cementite (Fe3C)
1000
4
5
6
6.70
Temperature (°F)
Chapter 25 Solutions
Introduction to General, Organic and Biochemistry
Ch. 25.2 - Problem 25-1 Draw the structure of UMP.Ch. 25 - 25-2 What structures Of the cell, visible in a...Ch. 25 - 25-3 Name one hereditary disease.Ch. 25 - 25-4 What is the basis unit of heredity?Ch. 25 - 25-5 (a) Where in a cell is the DNA located? (b)...Ch. 25 - 25-6 What are the components of (a) a nucleotide...Ch. 25 - 25-7 What are the differences between DNA and RNA?Ch. 25 - 25-8 Draw the structures of ADP and GDP. Are these...Ch. 25 - Prob. 25.9PCh. 25 - 25-10 Which DNA and RNA bases contain a carbonyl...
Ch. 25 - Prob. 25.11PCh. 25 - Prob. 25.12PCh. 25 - Prob. 25.13PCh. 25 - Prob. 25.14PCh. 25 - Prob. 25.15PCh. 25 - Prob. 25.16PCh. 25 - Prob. 25.17PCh. 25 - 25-18 What type of bond connects the base to the...Ch. 25 - Prob. 25.19PCh. 25 - 25-20 What constitutes the backbone of DNA?Ch. 25 - Prob. 25.21PCh. 25 - 25-22 In DNA, which carbon atoms of...Ch. 25 - 25-23 The sequence Of a short DNA segment is...Ch. 25 - Prob. 25.24PCh. 25 - Prob. 25.25PCh. 25 - Prob. 25.26PCh. 25 - Prob. 25.27PCh. 25 - Prob. 25.28PCh. 25 - 25-29 What constitutes the superstructure of...Ch. 25 - 25-30 What is the primary structure of DNA?Ch. 25 - 25-31 What is the secondary structure of DNA?Ch. 25 - 25-32 What is the major groove of a DNA helix?Ch. 25 - 25-33 What are the higher-order structures of DNA...Ch. 25 - 25-34 Which type Of RNA has enzyme activity? Where...Ch. 25 - 25-35 Which has the longest chains: tRNA, mRNA, or...Ch. 25 - 25-36 Which type of RNA contains modified...Ch. 25 - 25-37 Which type Of RNA has a sequence exactly...Ch. 25 - 25-38 Where is rRNA located in the cell?Ch. 25 - Prob. 25.39PCh. 25 - Prob. 25.40PCh. 25 - Prob. 25.41PCh. 25 - Prob. 25.42PCh. 25 - Prob. 25.43PCh. 25 - 25-44 What is IncRNA and what does it do?Ch. 25 - Prob. 25.45PCh. 25 - Prob. 25.46PCh. 25 - Prob. 25.47PCh. 25 - Prob. 25.48PCh. 25 - Prob. 25.49PCh. 25 - 25-50 Define: (a) Intron (b) ExonCh. 25 - 25-51 Does mRNA also have introns and exons?...Ch. 25 - Prob. 25.52PCh. 25 - Prob. 25.53PCh. 25 - 25-54 Do all genes code for a protein? If not,...Ch. 25 - 25-55 A DNA molecule normally replicates itself...Ch. 25 - 25-56 Which functional groups on the bases form...Ch. 25 - Prob. 25.57PCh. 25 - 25-58 Draw the structures of cytosine and guanine...Ch. 25 - 25-59 How many different bases are present in a...Ch. 25 - Prob. 25.60PCh. 25 - 25-61 Why is replication called semiconservative?Ch. 25 - 25-62 How does the removal of some positive...Ch. 25 - 25-63 Write the chemical reaction for the...Ch. 25 - Prob. 25.64PCh. 25 - 25-65 What are helicases? What is their function?Ch. 25 - 25-66 Can dATP Serve as a source for a primer?Ch. 25 - Prob. 25.67PCh. 25 - Prob. 25.68PCh. 25 - 25-69 In which direction is the DNA molecule...Ch. 25 - Prob. 25.70PCh. 25 - Prob. 25.71PCh. 25 - Prob. 25.72PCh. 25 - 25-73 From the perspective of the chain being...Ch. 25 - Prob. 25.74PCh. 25 - Prob. 25.75PCh. 25 - 25-76 When cytosine is deaminated, uracil is...Ch. 25 - Prob. 25.77PCh. 25 - 25-78 What are AP sites? Which enzyme creates...Ch. 25 - Prob. 25.79PCh. 25 - Prob. 25.80PCh. 25 - Prob. 25.81PCh. 25 - Prob. 25.82PCh. 25 - Prob. 25.83PCh. 25 - Prob. 25.84PCh. 25 - Prob. 25.85PCh. 25 - Prob. 25.86PCh. 25 - Prob. 25.87PCh. 25 - 25-88 (Chemical Connections 25B) How does...Ch. 25 - Prob. 25.89PCh. 25 - Prob. 25.90PCh. 25 - Prob. 25.91PCh. 25 - Prob. 25.92PCh. 25 - Prob. 25.93PCh. 25 - 25-94 (Chemical Connection 25D) What would be some...Ch. 25 - Prob. 25.95PCh. 25 - (Chemical Connection 25D) Why might a person make...Ch. 25 - Prob. 25.97PCh. 25 - Prob. 25.98PCh. 25 - Prob. 25.99PCh. 25 - Prob. 25.100PCh. 25 - Prob. 25.101PCh. 25 - Prob. 25.102PCh. 25 - Prob. 25.103PCh. 25 - -104 Why is it important that a DNA molecule be...Ch. 25 - Prob. 25.105PCh. 25 - Prob. 25.106PCh. 25 - Prob. 25.107PCh. 25 - Prob. 25.108PCh. 25 - -109 In sheep DNA, the mol% of adenine (A) was...Ch. 25 - Prob. 25.110PCh. 25 - Prob. 25.111PCh. 25 - Prob. 25.112PCh. 25 - Prob. 25.113PCh. 25 - -114 How could life have evolved if DNA leads to...Ch. 25 - Prob. 25.115PCh. 25 - Prob. 25.116PCh. 25 - Prob. 25.117P
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Nucleic acids - DNA and RNA structure; Author: MEDSimplified;https://www.youtube.com/watch?v=0lZRAShqft0;License: Standard YouTube License, CC-BY