(a) Interpretation: The reaction shown in Fig. P25.24(a) by drawing the structures of the products is to be complete and the reasoning is to be explained. Concept Introduction: Amines serves as nucleophiles and can undergo nucleophilic substitution reactions.

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Answer 1

Question

Chapter 25, Problem 25.24AP

Interpretation Introduction

(a)

Interpretation:

The reaction shown in Fig. P25.24(a) by drawing the structures of the products is to be complete and the reasoning is to be explained.

Concept Introduction:

Amines serves as nucleophiles and can undergo nucleophilic substitution reactions.

Interpretation Introduction

(b)

Interpretation:

The reaction shown in Fig. P25.24(b) by drawing the structures of the products is to be complete and the reasoning is to be explained.

Concept Introduction:

Reactions of thionyl chloride with alcohols yield thionyl esters. The OTs group will be replaced by the chlorine atom via nucleophilic substitution reactions. Oxygen ion serves as a nucleophile and replaces chlorine atom.

Interpretation Introduction

(c)

Interpretation:

The reaction shown in Fig. P25.24(c) by drawing the structures of the products is to be complete and the reasoning is to be explained.

Concept Introduction:

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What would be the best choices for the missing reagents 1 and 3 in this synthesis? 1. PPh3 3 2. n-BuLi • Draw the missing reagents in the drawing area below. You can draw them in any arrangement you like. • Do not draw the missing reagent 2. If you draw 1 correctly, we'll know what it is. • Note: if one of your reagents needs to contain a halogen, use bromine. Click and drag to start drawing a structure.

Answer 2

Question

Chapter 25, Problem 25.24AP

Interpretation Introduction

(a)

Interpretation:

The reaction shown in Fig. P25.24(a) by drawing the structures of the products is to be complete and the reasoning is to be explained.

Concept Introduction:

Amines serves as nucleophiles and can undergo nucleophilic substitution reactions.

Interpretation Introduction

(b)

Interpretation:

The reaction shown in Fig. P25.24(b) by drawing the structures of the products is to be complete and the reasoning is to be explained.

Concept Introduction:

Reactions of thionyl chloride with alcohols yield thionyl esters. The OTs group will be replaced by the chlorine atom via nucleophilic substitution reactions. Oxygen ion serves as a nucleophile and replaces chlorine atom.

Interpretation Introduction

(c)

Interpretation:

The reaction shown in Fig. P25.24(c) by drawing the structures of the products is to be complete and the reasoning is to be explained.

Concept Introduction:

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Answer 3

Question

Chapter 25, Problem 25.24AP

Interpretation Introduction

(a)

Interpretation:

The reaction shown in Fig. P25.24(a) by drawing the structures of the products is to be complete and the reasoning is to be explained.

Concept Introduction:

Amines serves as nucleophiles and can undergo nucleophilic substitution reactions.

Interpretation Introduction

(b)

Interpretation:

The reaction shown in Fig. P25.24(b) by drawing the structures of the products is to be complete and the reasoning is to be explained.

Concept Introduction:

Reactions of thionyl chloride with alcohols yield thionyl esters. The OTs group will be replaced by the chlorine atom via nucleophilic substitution reactions. Oxygen ion serves as a nucleophile and replaces chlorine atom.

Interpretation Introduction

(c)

Interpretation:

The reaction shown in Fig. P25.24(c) by drawing the structures of the products is to be complete and the reasoning is to be explained.

Concept Introduction:

Expert Solution & Answer

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Answer 4

Question

Chapter 25, Problem 25.24AP

Interpretation Introduction

(a)

Interpretation:

The reaction shown in Fig. P25.24(a) by drawing the structures of the products is to be complete and the reasoning is to be explained.

Concept Introduction:

Amines serves as nucleophiles and can undergo nucleophilic substitution reactions.

Interpretation Introduction

(b)

Interpretation:

The reaction shown in Fig. P25.24(b) by drawing the structures of the products is to be complete and the reasoning is to be explained.

Concept Introduction:

Reactions of thionyl chloride with alcohols yield thionyl esters. The OTs group will be replaced by the chlorine atom via nucleophilic substitution reactions. Oxygen ion serves as a nucleophile and replaces chlorine atom.

Interpretation Introduction

(c)

Interpretation:

The reaction shown in Fig. P25.24(c) by drawing the structures of the products is to be complete and the reasoning is to be explained.

Concept Introduction:

Expert Solution & Answer

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Answer 5

Chapter 25, Problem 25.24AP

Interpretation Introduction

(a)

Interpretation:

The reaction shown in Fig. P25.24(a) by drawing the structures of the products is to be complete and the reasoning is to be explained.

Concept Introduction:

Amines serves as nucleophiles and can undergo nucleophilic substitution reactions.

Interpretation Introduction

(b)

Interpretation:

The reaction shown in Fig. P25.24(b) by drawing the structures of the products is to be complete and the reasoning is to be explained.

Concept Introduction:

Reactions of thionyl chloride with alcohols yield thionyl esters. The OTs group will be replaced by the chlorine atom via nucleophilic substitution reactions. Oxygen ion serves as a nucleophile and replaces chlorine atom.

Interpretation Introduction

(c)

Interpretation:

The reaction shown in Fig. P25.24(c) by drawing the structures of the products is to be complete and the reasoning is to be explained.

Concept Introduction:

Answer 6

Chapter 25, Problem 25.24AP

Interpretation Introduction

(a)

Interpretation:

The reaction shown in Fig. P25.24(a) by drawing the structures of the products is to be complete and the reasoning is to be explained.

Concept Introduction:

Amines serves as nucleophiles and can undergo nucleophilic substitution reactions.

Answer 7

Chapter 25, Problem 25.24AP

Interpretation Introduction

(a)

Interpretation:

The reaction shown in Fig. P25.24(a) by drawing the structures of the products is to be complete and the reasoning is to be explained.

Concept Introduction:

Amines serves as nucleophiles and can undergo nucleophilic substitution reactions.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The reaction shown in Fig. P25.24(b) by drawing the structures of the products is to be complete and the reasoning is to be explained.

Concept Introduction:

Reactions of thionyl chloride with alcohols yield thionyl esters. The OTs group will be replaced by the chlorine atom via nucleophilic substitution reactions. Oxygen ion serves as a nucleophile and replaces chlorine atom.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The reaction shown in Fig. P25.24(b) by drawing the structures of the products is to be complete and the reasoning is to be explained.

Concept Introduction:

Reactions of thionyl chloride with alcohols yield thionyl esters. The OTs group will be replaced by the chlorine atom via nucleophilic substitution reactions. Oxygen ion serves as a nucleophile and replaces chlorine atom.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The reaction shown in Fig. P25.24(c) by drawing the structures of the products is to be complete and the reasoning is to be explained.

Concept Introduction:

Answer 11

Interpretation Introduction

(c)

Interpretation:

The reaction shown in Fig. P25.24(c) by drawing the structures of the products is to be complete and the reasoning is to be explained.

Concept Introduction:

Answer 12

Expert Solution & Answer

Answer 13

Expert Solution & Answer

Answer 14

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Answer 15

Ch. 25 - Prob. 25.1P Ch. 25 - Prob. 25.2P Ch. 25 - Prob. 25.3P Ch. 25 - Prob. 25.4P Ch. 25 - Prob. 25.5P Ch. 25 - Prob. 25.6P Ch. 25 - Prob. 25.7P Ch. 25 - Prob. 25.8P Ch. 25 - Prob. 25.9P Ch. 25 - Prob. 25.10P

(a) Interpretation: The reaction shown in Fig. P25.24(a) by drawing the structures of the products is to be complete and the reasoning is to be explained. Concept Introduction: Amines serves as nucleophiles and can undergo nucleophilic substitution reactions.

Solution Summary: The author explains that amine acts as a nucleophile and replaces the chlorides in phosphorus oxychloride.

Concept explainers

(a)

Interpretation:

The reaction shown in Fig. P25.24(a) by drawing the structures of the products is to be complete and the reasoning is to be explained.

Concept Introduction:

Amines serves as nucleophiles and can undergo nucleophilic substitution reactions.

(c)

Interpretation:

The reaction shown in Fig. P25.24(c) by drawing the structures of the products is to be complete and the reasoning is to be explained.

Concept Introduction:

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Chapter 25 Solutions

(a) Interpretation: The reaction shown in Fig. P25.24(a) by drawing the structures of the products is to be complete and the reasoning is to be explained. Concept Introduction: Amines serves as nucleophiles and can undergo nucleophilic substitution reactions.

Solution Summary: The author explains that amine acts as a nucleophile and replaces the chlorides in phosphorus oxychloride.

Concept explainers

(a) Interpretation: The reaction shown in Fig. P25.24(a) by drawing the structures of the products is to be complete and the reasoning is to be explained. Concept Introduction: Amines serves as nucleophiles and can undergo nucleophilic substitution reactions.

(c) Interpretation: The reaction shown in Fig. P25.24(c) by drawing the structures of the products is to be complete and the reasoning is to be explained. Concept Introduction:

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Chapter 25 Solutions

(a)

Interpretation:

The reaction shown in Fig. P25.24(a) by drawing the structures of the products is to be complete and the reasoning is to be explained.

Concept Introduction:

Amines serves as nucleophiles and can undergo nucleophilic substitution reactions.

(c)

Interpretation:

The reaction shown in Fig. P25.24(c) by drawing the structures of the products is to be complete and the reasoning is to be explained.

Concept Introduction: