Organic Chemistry
8th Edition
ISBN: 9781305580350
Author: William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher: Cengage Learning
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Question
Chapter 25, Problem 25.23P
(a)
Interpretation Introduction
Interpretation:
The specific rotation of α-L-glucose has to be given.
Concept Introduction:
The carbohydrates have D-monosaccharide and L-monosaccharide, which shows specific rotation based on their rotations. The D-monosaccharide shows specific rotation with the sign +. Whereas, the L-monosaccharide shows specific rotation with the sign −.
(b)
Interpretation Introduction
Interpretation:
If α-L-glucose is dissolved in water, the specific rotation value will change or not and if changes, to what value has to be given.
Concept Introduction:
When carbohydrates are dissolved in water, the anomeric forms are interconverted (α-form to β-form) to attain equilibrium. This interconversion of the anomers is said to be mutarotation.
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Chapter 25 Solutions
Organic Chemistry
Ch. 25.1 - Prob. 25.1PCh. 25.2 - Prob. 25.2PCh. 25.2 - Prob. 25.3PCh. 25.3 - Prob. 25.4PCh. 25.3 - Prob. 25.5PCh. 25.3 - Prob. AQCh. 25.3 - Prob. BQCh. 25.3 - Prob. CQCh. 25.3 - Prob. DQCh. 25.3 - How many stereoisomers would result from the...
Ch. 25.4 - Prob. 25.6PCh. 25 - Prob. 25.7PCh. 25 - Prob. 25.8PCh. 25 - Prob. 25.9PCh. 25 - Prob. 25.10PCh. 25 - Prob. 25.11PCh. 25 - Prob. 25.12PCh. 25 - Prob. 25.13PCh. 25 - Prob. 25.14PCh. 25 - Prob. 25.15PCh. 25 - Prob. 25.16PCh. 25 - Prob. 25.17PCh. 25 - Prob. 25.18PCh. 25 - Prob. 25.19PCh. 25 - Prob. 25.20PCh. 25 - Prob. 25.21PCh. 25 - Prob. 25.22PCh. 25 - Prob. 25.23PCh. 25 - Prob. 25.24PCh. 25 - Prob. 25.25PCh. 25 - Prob. 25.26PCh. 25 - Prob. 25.27PCh. 25 - Prob. 25.28PCh. 25 - Prob. 25.29PCh. 25 - Prob. 25.30PCh. 25 - Prob. 25.31PCh. 25 - Prob. 25.32PCh. 25 - Prob. 25.33PCh. 25 - Prob. 25.34PCh. 25 - In making candy or sugar syrups, sucrose is boiled...Ch. 25 - Prob. 25.36PCh. 25 - Prob. 25.37PCh. 25 - Prob. 25.38PCh. 25 - Prob. 25.39PCh. 25 - Prob. 25.40PCh. 25 - Prob. 25.41PCh. 25 - Prob. 25.42PCh. 25 - Prob. 25.43PCh. 25 - Digitalis is a preparation made from the dried...Ch. 25 - Prob. 25.45PCh. 25 - Prob. 25.46PCh. 25 - Prob. 25.47PCh. 25 - Prob. 25.48PCh. 25 - Prob. 25.49PCh. 25 - Prob. 25.50P
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- Cellulose, the major structural material of wood and plants, consists of a chain of B-D-glucose molecules connected by B-1,4-glycosidic bonds. In comparison, the amylose component of starch consists of a-D-glucose molecules connected by a-1,4-glycosidic bonds. Identify the following structures, denoted A and B, as the structures of cellulose or amylose. A В 0 Н CH2OH H . н Н OH H Н CH₂OH 0 Н ОН Н ОН Н Н ОН О О Н Н CH₂OH -0 Н OH H Н CH₂OH 0 Н ОН Н ОН Н Н ОН OB is the structure of cellulose, while A is the structure of amylose. O A and B both represent the structure of amylose. O A is the structure of cellulose, while B is the structure of amylose. O A and B both represent the structure of cellulose. Н 0 0 H Н CH₂OH до Н ОН Н Н H OH CH₂OH 0 Н ОН Н Н Н ОН Н О Н H CH₂OH -о Н ОН Н Н ОН CH₂OH 0 H OH HA Н ОН Н H 0arrow_forwardWhich of the following statements about the monosaccharide shown below is correct?arrow_forwardThe specific rotation, [a]p, for (-)-2-butanol is +14. What is the observed rotation for a solution of 1.0 g of (-)-2-butanol in 10 mL of water in a sample tube having a pathlength of 10 cm? 1.4 degrees . The observed rotation of a solution of 1.1 g of a compound in 10 mL of water is -10 degrees. If the pathlength is 10 cm, what is the specific rotation of the compound?arrow_forward
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