Organic Chemistry
7th Edition
ISBN: 9780321803221
Author: Paula Y. Bruice
Publisher: Prentice Hall
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Textbook Question
Chapter 2.5, Problem 17P
Which of the following bases can remove a proton from acetic add in a reaction that favors products?
HO–
CH3NH2
CH3OH
H2O
Cl–
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Chapter 2 Solutions
Organic Chemistry
Ch. 2.1 - Which of the following are not acids? CH3COOH CO2...Ch. 2.1 - Draw the products of the addbase renc1 ion when a....Ch. 2.1 - a. What is the conjugate acid of each or the...Ch. 2.2 - a. Which is a stronger acid: one with a pKa of 5.2...Ch. 2.2 - An acid has a Ka of 4.53 106 in water. What is...Ch. 2.2 - Prob. 6PCh. 2.2 - Antacids are compounds that neutralize stomach...Ch. 2.2 - Are the following body fluids acidic or basic? a....Ch. 2.3 - Draw the conjugate acid of each of the following:...Ch. 2.3 - a. Write an equation showing CH3OH reacting as an...
Ch. 2.3 - Estimate the pKa values of the following...Ch. 2.3 - a. Which is a stronger base: CH3COO or HCOO? (The...Ch. 2.3 - Using the pKa values in Section 2.3, rank the...Ch. 2.4 - Prob. 14PCh. 2.5 - a. For each of the acid-base reactions in Section...Ch. 2.5 - Ethyne has a pKa value of 25, water has a pKa...Ch. 2.5 - Which of the following bases can remove a proton...Ch. 2.5 - Calculate the equilibrium constant for the...Ch. 2.6 - Rank the ions (CH3, NH2, HO, and F) from most...Ch. 2.6 - Rank the carbanions shown in the margin from most...Ch. 2.6 - Which is the stronger acid?Ch. 2.6 - Prob. 22PCh. 2.6 - Rank the halide ions (F, Cl, Br, and l) from...Ch. 2.6 - a. Which is more electronegative, oxygen or...Ch. 2.6 - Which is a stronger acid? a. HCl or HBr b....Ch. 2.6 - a. Which of the halide ions (F, Cl, Br, and l) is...Ch. 2.6 - Prob. 27PCh. 2.7 - What is a stronger acid? a. CH3OCH2CH2OH or...Ch. 2.7 - Prob. 29PCh. 2.7 - What is a stronger base?Ch. 2.8 - Fosamax (shown on the previous page) has six...Ch. 2.8 - Which is a stronger acid? Why?Ch. 2.8 - Prob. 34PCh. 2.9 - Using the table of pKa values given in Appendix I,...Ch. 2.10 - Prob. 36PCh. 2.10 - As long as the pH is not less than _______, at...Ch. 2.10 - A naturally occurring amino acid such as alanine...Ch. 2.10 - For each of the following compounds, indicate the...Ch. 2.11 - Write the equation that shows how a buffer made by...Ch. 2.12 - Draw the products of the following react ions. Use...Ch. 2.12 - What product are formed when each of the following...Ch. 2 - a. Rank the following alcohols from strongest to...Ch. 2 - Which is a stronger base? a. HS or HO b. CH3O or...Ch. 2 - According to the explanations by Lewis, if a...Ch. 2 - a. Rank the following carboxylic acids from...Ch. 2 - Prob. 51PCh. 2 - For the following compound. a. draw its conjugate...Ch. 2 - Rank the following compounds from strongest to...Ch. 2 - Prob. 54PCh. 2 - Prob. 55PCh. 2 - a. Rank the following alcohols from strongest to...Ch. 2 - For each compound, indicate the atom that is most...Ch. 2 - a. Given the Ka values, estimate the pKa value of...Ch. 2 - A single bond between two carbons with different...Ch. 2 - Tenormin, a member of the group of drugs known as...Ch. 2 - From which of the following compounds can HO...Ch. 2 - a. For each of the following pairs of reactions,...Ch. 2 - Prob. 63PCh. 2 - Which is a stronger acid? a. b. c. d.Ch. 2 - Prob. 65PCh. 2 - Given that pH+ pOH = 14 and that the concentration...Ch. 2 - How could you separate a mixture of the following...Ch. 2 - Prob. 68PCh. 2 - a. If an add with a pKa of 5.3 is in an aqueous...Ch. 2 - Calculate the pH values of the following...Ch. 2 - Prob. 1PCh. 2 - Prob. 2PCh. 2 - Prob. 3PCh. 2 - Which of the reactions in Problem 3 favor...Ch. 2 - Prob. 5PCh. 2 - Prob. 6PCh. 2 - Prob. 7PCh. 2 - Which is the stronger acid? a. ClCH2CH2OH or...Ch. 2 - Prob. 9PCh. 2 - Prob. 10PCh. 2 - Which is a more stable base? Remembering that the...Ch. 2 - Which is the Stronger acid?Ch. 2 - Prob. 13PCh. 2 - a. Draw the structure of (CH3COOH (pKa = 4.7) at...
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- Which has the larger numerical value? (a) The pKa of a strong acid or the pKa of a weak acid (b) The Ka of a strong acid or the Ka of a weak acidarrow_forwardGive the major product of the following reaction. HBr Ph-C C-Ph НООН There is no reaction under these conditions or the correct product is not listed here. Br Ph Ph Br Br Ph Ph Br Br Ph Ph Br Br Ph Ph Br Br J Ph Ph Br Br Ph Ph Brarrow_forward18). The formulas and the structures of two acids are shown below. Which acid is a stronger acid? If the acid strength of the two acids is equal, say so. Cl2CHCOOH CH3COOH но но CI-C-C-OH н-с-с-он ČI Ką = 0.0324 Ką = 1.82 x 10-5 %3D a. Cl¿CHCOOH is a stronger acid than CH;COOH. b. CH;COOH is a stronger acid than CI½CHCOOH c. The two have equal acid strength. d. none of the abovearrow_forward
- Which is the conjugate base in this reaction? acetic acid Pyridine Pyridinium H ion Lot -oH pka =4.76 pKa= 5,25 A acetic acid B) acetate ion pyridine D pyridinium ionarrow_forwardWhich compound in the following pair is the stronger acid? Select the single best answer. Br OH Br Br- OH Brarrow_forwardWhat is the role of ammonium ion in the following reaction? NH3 H;0 H20 NHA + Select one: Conjugate acid Acid Conjugate base Basearrow_forward
- Which of the two acid has a conjugate base that is more stable? And which of the two is the stronger acid?arrow_forwardtu Please don't provide handwritten solutionarrow_forwardConsider the acid-base reaction below: Ba(HSO4)2 + Ba(OH)2 ----> Compound A + H2O (OR B a(H S O4)2 + Ba left parenthesis O H right parenthesis 2 ----> Compound A + H2O) One of the single ions that is used to form compound A is ____.arrow_forward
- Indicate, by letter, the strongest acid and the weakest acid of those below. CH₂ COOH The strongest acid is The weakest acid is (CH₂)₂N COOH сarrow_forwardthese reactions can be written as a Lewis acid-Lewis base reaction. Label the Lewis acid and the Lewis base; use curved arrows to show the flow of electrons in each reaction. In doing this problem, it is essential that you show valence electrons for all atoms participating in each reactionarrow_forwardConsider the acid-base reaction below: Ca(HCO3)2 + Ca(OH)2 ----> Compound A + H2O (OR Ca(HCO3)2 + Ca left parenthesis OH right parenthesis 2 ----> Compound A + H2O) One of the single ions that is used to form compound A is ____.arrow_forward
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