
Concept explainers
(a)
Interpretation:
The stronger base among
Concept introduction:
If a base receives one proton, then the formed species is a conjugate acid whereas an acid lose one proton, then the formed species is a conjugated base.
If an acid lose one proton, then the formed species is a conjugated base. Weak base forms stronger conjugated acid.
Electronegativity: The chemical behavior of an atom where it attracts the shared electron pair to itself. Down the group, electronegativity decreases as the number of energy levels increases.
(b)
Interpretation:
The stronger base among
Concept introduction:
If a base receives one proton, then the formed species is a conjugate acid whereas an acid lose one proton, then the formed species is a conjugated base.
If an acid lose one proton, then the formed species is a conjugated base. Weak base forms stronger conjugated acid.
Electronegativity: The chemical behavior of an atom where it attracts the shared electron pair to itself. Down the group, electronegativity decreases as the number of energy levels increases.
(c)
Interpretation:
The stronger base among
Concept introduction:
If a base receives one proton, then the formed species is a conjugate acid whereas an acid lose one proton, then the formed species is a conjugated base.
If an acid lose one proton, then the formed species is a conjugated base. Weak base forms stronger conjugated acid.
Electronegativity: The chemical behavior of an atom where it attracts the shared electron pair to itself. Down the group, electronegativity decreases as the number of energy levels increases.
Electronegativity depends on the acidity of a species. Order of electronegativity of hybridization is
(d)
Interpretation:
The stronger base among
Concept introduction:
If a base receives one proton, then the formed species is a conjugate acid whereas an acid lose one proton, then the formed species is a conjugated base.
If an acid lose one proton, then the formed species is a conjugated base. Weak base forms stronger conjugated acid.
Electronegativity: The chemical behavior of an atom where it attracts the shared electron pair to itself. Down the group, electronegativity decreases as the number of energy levels increases.
Electronegativity depends on the acidity of a species. Order of electronegativity of hybridization is
(e)
Interpretation:
The strongest base among
Concept introduction:
If a base receives one proton, then the formed species is a conjugate acid whereas an acid lose one proton, then the formed species is a conjugated base.
If an acid lose one proton, then the formed species is a conjugated base. Weak base forms stronger conjugated acid.
Electronegativity: The chemical behavior of an atom where it attracts the shared electron pair to itself. Down the group, electronegativity decreases as the number of energy levels increases.
In carbohydrate, if hydrogen atoms are replaced by electronegative atoms, it causes inductive electron withdrawal. It stabilizes its conjugate base thus increases the strength of the acid.
(f)
Interpretation:
The strongest base among
Concept introduction:
If a base receives one proton, then the formed species is a conjugate acid whereas an acid lose one proton, then the formed species is a conjugated base.
If an acid lose one proton, then the formed species is a conjugated base. Weak base forms stronger conjugated acid.
Electronegativity: The chemical behavior of an atom where it attracts the shared electron pair to itself. Down the group, electronegativity decreases as the number of energy levels increases.
In carbohydrate, if hydrogen atoms are replaced by electronegative atoms, it causes inductive electron withdrawal. It stabilizes its conjugate base thus increases the strength of the acid.

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Chapter 2 Solutions
Organic Chemistry
- Understanding the general acid-base properties of amino acids O Proteins Imagine each of the molecules shown below was found in an aqueous solution. Can you tell whether the solution is acidic, basic, or neutral? molecule The solution is... 010 H3N-CH-C-OH CH HO CH3 O acidic O basic neutral O (unknown) H3N HO 0 O acidic O basic neutral ○ (unknown) H3N-CH-C-O CH2 CH3-CH-CH3 O acidic O basic Oneutral ○ (unknown) O= X H2N-CH-C-O CH3 CH CH3 acidic O basic O neutral ○ (unknown) ? 000arrow_forwardImagine each of the molecules shown below was found in an aqueous solution. Can you tell whether the solution is acidic, basic, or neutral? molecule 0=0 H3N-CH-C-o HO CH2 OH The solution is... O acidic O basic O neutral O (unknown) H₂N acidic O basic O neutral ○ (unknown) + H3N O OH O acidic O basic O neutral O (unknown) H2N-CH-C-O CH3 O acidic O basic neutral ○ (unknown) X ? olo HEarrow_forwardRecognizing ampli Draw an a amino acid with a methyl (-CH3) side chain. Explanation Check Click and drag to start drawing a structure. X Carrow_forward
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- theres 2 productsarrow_forwardDraw the major product of this solvolysis reaction. Ignore any inorganic byproducts. + CH3CH2OH Drawing Q Atoms, Bonds and Rings OCH2CH3 || OEt Charges OH 00-> | Undo Reset | Br Remove Done Drag To Pan +arrow_forwardDraw the major product of this SN1 reaction. Ignore any inorganic byproducts. CH3CO2Na CH3CO2H Drawing + Br Q Atoms, Bonds and Rings OAC Charges OH ОАс Na ဂ Br Undo Reset Remove Done Drag To Pan +arrow_forward
- Organic Functional Groups entifying positions labeled with Greek letters in acids and derivatives 1/5 ssible, replace an H atom on the a carbon of the molecule in the drawing area with a ce an H atom on the ẞ carbon with a hydroxyl group substituent. ne of the substituents can't be added for any reason, just don't add it. If neither substi er the drawing area. O H OH Oneither substituent can be added. Check D 1 Accessibility ado na witharrow_forwardDifferentiate between electrophilic and nucleophilic groups. Give examples.arrow_forwardAn aldehyde/ketone plus an alcohol gives a hemiacetal, and an excess of alcohol gives an acetal. The reaction is an equilibrium; in aldehydes, it's shifted to the right and in ketones, to the left. Explain.arrow_forward
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