Organic Chemistry
7th Edition
ISBN: 9780321803221
Author: Paula Y. Bruice
Publisher: Prentice Hall
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Textbook Question
Chapter 2.10, Problem 37P
As long as the pH is not less than _______, at least 50% of a protonated
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As long as the pH is not less than ___________, at least 50% of a protonated amine with a pKa value of 10.4 will be in its neutral, nonprotonated form.
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Chapter 2 Solutions
Organic Chemistry
Ch. 2.1 - Which of the following are not acids? CH3COOH CO2...Ch. 2.1 - Draw the products of the addbase renc1 ion when a....Ch. 2.1 - a. What is the conjugate acid of each or the...Ch. 2.2 - a. Which is a stronger acid: one with a pKa of 5.2...Ch. 2.2 - An acid has a Ka of 4.53 106 in water. What is...Ch. 2.2 - Prob. 6PCh. 2.2 - Antacids are compounds that neutralize stomach...Ch. 2.2 - Are the following body fluids acidic or basic? a....Ch. 2.3 - Draw the conjugate acid of each of the following:...Ch. 2.3 - a. Write an equation showing CH3OH reacting as an...
Ch. 2.3 - Estimate the pKa values of the following...Ch. 2.3 - a. Which is a stronger base: CH3COO or HCOO? (The...Ch. 2.3 - Using the pKa values in Section 2.3, rank the...Ch. 2.4 - Prob. 14PCh. 2.5 - a. For each of the acid-base reactions in Section...Ch. 2.5 - Ethyne has a pKa value of 25, water has a pKa...Ch. 2.5 - Which of the following bases can remove a proton...Ch. 2.5 - Calculate the equilibrium constant for the...Ch. 2.6 - Rank the ions (CH3, NH2, HO, and F) from most...Ch. 2.6 - Rank the carbanions shown in the margin from most...Ch. 2.6 - Which is the stronger acid?Ch. 2.6 - Prob. 22PCh. 2.6 - Rank the halide ions (F, Cl, Br, and l) from...Ch. 2.6 - a. Which is more electronegative, oxygen or...Ch. 2.6 - Which is a stronger acid? a. HCl or HBr b....Ch. 2.6 - a. Which of the halide ions (F, Cl, Br, and l) is...Ch. 2.6 - Prob. 27PCh. 2.7 - What is a stronger acid? a. CH3OCH2CH2OH or...Ch. 2.7 - Prob. 29PCh. 2.7 - What is a stronger base?Ch. 2.8 - Fosamax (shown on the previous page) has six...Ch. 2.8 - Which is a stronger acid? Why?Ch. 2.8 - Prob. 34PCh. 2.9 - Using the table of pKa values given in Appendix I,...Ch. 2.10 - Prob. 36PCh. 2.10 - As long as the pH is not less than _______, at...Ch. 2.10 - A naturally occurring amino acid such as alanine...Ch. 2.10 - For each of the following compounds, indicate the...Ch. 2.11 - Write the equation that shows how a buffer made by...Ch. 2.12 - Draw the products of the following react ions. Use...Ch. 2.12 - What product are formed when each of the following...Ch. 2 - a. Rank the following alcohols from strongest to...Ch. 2 - Which is a stronger base? a. HS or HO b. CH3O or...Ch. 2 - According to the explanations by Lewis, if a...Ch. 2 - a. Rank the following carboxylic acids from...Ch. 2 - Prob. 51PCh. 2 - For the following compound. a. draw its conjugate...Ch. 2 - Rank the following compounds from strongest to...Ch. 2 - Prob. 54PCh. 2 - Prob. 55PCh. 2 - a. Rank the following alcohols from strongest to...Ch. 2 - For each compound, indicate the atom that is most...Ch. 2 - a. Given the Ka values, estimate the pKa value of...Ch. 2 - A single bond between two carbons with different...Ch. 2 - Tenormin, a member of the group of drugs known as...Ch. 2 - From which of the following compounds can HO...Ch. 2 - a. For each of the following pairs of reactions,...Ch. 2 - Prob. 63PCh. 2 - Which is a stronger acid? a. b. c. d.Ch. 2 - Prob. 65PCh. 2 - Given that pH+ pOH = 14 and that the concentration...Ch. 2 - How could you separate a mixture of the following...Ch. 2 - Prob. 68PCh. 2 - a. If an add with a pKa of 5.3 is in an aqueous...Ch. 2 - Calculate the pH values of the following...Ch. 2 - Prob. 1PCh. 2 - Prob. 2PCh. 2 - Prob. 3PCh. 2 - Which of the reactions in Problem 3 favor...Ch. 2 - Prob. 5PCh. 2 - Prob. 6PCh. 2 - Prob. 7PCh. 2 - Which is the stronger acid? a. ClCH2CH2OH or...Ch. 2 - Prob. 9PCh. 2 - Prob. 10PCh. 2 - Which is a more stable base? Remembering that the...Ch. 2 - Which is the Stronger acid?Ch. 2 - Prob. 13PCh. 2 - a. Draw the structure of (CH3COOH (pKa = 4.7) at...
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- Part A The chemical 5-amino-2,3-dihydro-1,4-phthalazinedione, better known as luminol, is used by forensic scientists in analyzing crime scenes for the presence of washed-away blood. Luminol is so sensitive that it can detect blood that has been diluted 10,000 times. A basic solution of luminol is often sprayed onto surfaces that are suspected of containing minute amounts of blood. The forensic technician at a crime scene has just prepared a luminol stock solution by adding 15.0 g of luminol into a total volume of 75.0 mL of H2O. What is the molarity of the stock solution of luminol? Express your answer with the appropriate units. Luminol has a molecular weight of 177 g/mol. • View Available Hint(s) HẢ molarity of luminol solution = Value Units Submit Part B Before investigating the scene, the technician must dilute the luminol solution to a concentration of 6.00x10-2 M. The diluted solution is then placed in a spray bottle for application on the desired surfaces. How many moles of…arrow_forwardFill in the left side of this equilibrium constant equation for the reaction of diethylmethylamine (C,H13N), a weak base, with water. Ü - K,arrow_forwardAt what pH are the concentrations of morpholine and morpholinium ion equalarrow_forward
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- Drive-Google X Logout Successhil X O- Mail- Mariin, And X e Kegistration-Lifer X Sign pw.com/iln/takeAssignment/takeCovalentActivity.do?locator=assignment-take Clear All (C,H3),NH, Stronger Bronsted-Lowry acid Weaker Bronsted-Lowry acid NO, (C;H3)½NH Stronger Bronsted-Lowry base HNO2 Weaker Bronsted-Lowry base Cengage Learning | Cengage Technical Support a Warrow_forwardThe structure of a particular drug is provided below. The acid form is shown, and its pk, is 4.8. Mark any/all that apply. HO O The conjugate base of this acid is charged. O The acid form will predominate at pH 7.40. The acid form of this drug is charged. The conjugate base will predominate at pH 7.40. The acid form of this drug will diffuse through the cell membrane more easily than the conjugate base will diffuse through the cell membrane.arrow_forwardUsing the table of the weak base below, you have chosen Ethylamine as your weak base in the buffer solution. You have already added enough of the conjugate acid salt to make the buffer solution concentration at 0.52 M in this salt. The desired pH of the buffer should be equal to 10.1. Values of K, for Some Common Weak Bases Conjugate Acid Name Formula NH3 CH;NH2 C2H§NH2 CgH;NH2 C3H;N NH,+ CH;NH3* CH;NH3* CH;NH;* C3H;NH+ 1.8 × 10-5 4.38 × 10–4 5.6 × 10-4 3.8 × 10-10 Ammonia Methylamine Ethylamine Aniline Pyridine 1.7 x 10-9 3. Compute the concentration of the weak base in Molarity. (Write your answer in 4 decimal places without the unit).arrow_forward
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