Organic Chemistry (8th Edition)
8th Edition
ISBN: 9780134042282
Author: Paula Yurkanis Bruice
Publisher: PEARSON
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Question
Chapter 24.9, Problem 20P
Interpretation Introduction
Interpretation:
The steps for
Concept introduction:
Protein catabolism: It is defined as breakdown of proteins into smaller units that is into amino acids gets transported finally
Citric Acid Cycle: It involves 8 series reaction which converts acetyl group present in acetyl coenzyme A into 2
Substrate: The molecule where the reaction takes place with help of enzymes.
Enzyme: The proteins that helps
Oxidation: The oxidation is reaction that involves addition of oxygen atom or loss of electrons or removal of hydrogen atom present in the chemical compound.
Reduction: It involves removal of oxygen or addition of hydrogen to the chemical compound.
Coenzyme: They are non-proteins molecules which helps enzymes for catalyzing the reaction.
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Draw the steps for the conversion of a-ketoglutarate to succinyl-CoA.
In the first step of B-Oxidation,
R
Η Η Ο
B
HH
-S-COA
Acyl COA
In the third step of B-Oxidation,
ОНН О
T ||
R-C-C-C -S-COA
Acyl COA
dehydrogenase
L-B-Hydroxyacyl CoA
R-
B-Hydroxyacyl CoA
dehydrogenase
H
H
Η Ο
R-
trans-Enoyl COA
is the oxidizing agent.
-S-COA
is the oxidizing agent.
||
-CH₂-C S-CoA
B-Ketoacyl COA
Fatty acids and triglycerides are an important source of nutrition and a dense form
of stored energy. Digestion of fats yields more energy per gram than digestion of
carbohydrates.
Each turn on the B-oxidation spiral results in the formation of a new acetyl COA
molecule. This molecule can then be used to generate more energy in
A) fatty acid synthesis
B) ketolysis
C) glycolysis
D) tricarboxylic acid cycle
E) oxidative phosphorylation
Chapter 24 Solutions
Organic Chemistry (8th Edition)
Ch. 24.3 - Prob. 2PCh. 24.5 - Prob. 3PCh. 24.5 - Prob. 4PCh. 24.5 - Why does the OH group add to the -carbon rather...Ch. 24.5 - Prob. 6PCh. 24.5 - How many molecules of NADH are formed from the...Ch. 24.6 - Prob. 8PCh. 24.6 - The oxidation of glyceraldehyde-3-phosphate to...Ch. 24.6 - Prob. 10PCh. 24.7 - Prob. 11P
Ch. 24.7 - Prob. 12PCh. 24.7 - Prob. 13PCh. 24.7 - Propose a mechanism for the reduction of...Ch. 24.8 - Prob. 15PCh. 24.9 - Acid-catalyzed dehydration reactions are normally...Ch. 24.9 - Prob. 17PCh. 24.9 - Prob. 18PCh. 24.9 - Acid-catalyzed dehydration reactions are normally...Ch. 24.9 - Prob. 20PCh. 24.9 - Prob. 21PCh. 24.10 - Prob. 22PCh. 24.12 - a. What is the name of the enzyme that converts...Ch. 24.14 - Prob. 24PCh. 24 - Prob. 25PCh. 24 - Prob. 26PCh. 24 - Prob. 27PCh. 24 - S-Adenosylmethionine (SAM) is formed from the...Ch. 24 - Prob. 29PCh. 24 - Prob. 30PCh. 24 - Prob. 31PCh. 24 - Prob. 32PCh. 24 - Prob. 33PCh. 24 - Prob. 34PCh. 24 - Prob. 35PCh. 24 - Prob. 36PCh. 24 - Prob. 37PCh. 24 - Prob. 38PCh. 24 - Prob. 39PCh. 24 - Prob. 40PCh. 24 - Prob. 41PCh. 24 - Prob. 42PCh. 24 - Prob. 43PCh. 24 - Prob. 44PCh. 24 - Prob. 45PCh. 24 - Prob. 46PCh. 24 - Prob. 47PCh. 24 - Prob. 48PCh. 24 - Prob. 49PCh. 24 - Prob. 50PCh. 24 - Prob. 51PCh. 24 - UDP-galactose-4-epimerase converts UDP-galactose...Ch. 24 - A student is trying to determine the mechanism for...Ch. 24 - What would be the results of the experiment in...
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- Most fatty acids have an even number of carbons and, therefore, are completely metabolized to acetyl-CoA. A fatty acid with an odd number of carbons is metabolized to acetyl-CoA and one equivalent of propionyl-CoA. The following two reactions convert propionyl-CoA into succinyl-CoA, a citric acid cycle intermediate, so it can be further metabolized. Each of the reactions requires a coenzyme. Identify the coenzyme for each step. From what vitamins are the coenzymes derived?arrow_forwardMost fatty acids have an even number of carbons and, therefore, are completely metabolized to acetyl-CoA. A fatty acid with an odd number of carbons is metabolized to acetyl-CoA and one equivalent of propionyl-CoA. The following two reactions convert propionyl-CoA into succinyl-CoA, a citric acid cycle intermediate, so it can be further metabolized. Each of the reactions requires a coenzyme. Identify the coenzyme for each step. From what vitamins are the coenzymes derived?arrow_forwardStep 7 of the citric acid cycle is shown. Which statement best describes what occurs in this step? CO₂ 1 CH || CH + H₂O CO₂ fumarate CO₂™ fumarase HO C-H CH₂ CO₂ malate A) Fumarate undergoes hydrogenation with hydrogens and electrons provided by the enzyme fumarase. B) Fumarate undergoes hydration with the aid of the enzyme fumarase. C) Fumarate undergoes hydrolysis with the aid of the enzyme fumarase. D) Fumarate undergoes reduction with the aid of the cofactor fumarase.arrow_forward
- Place the steps of glycolysis in the order that they occur. Last step Answer Bank Glucose is phosphorylated by hexokinase. Glyceraldehyde-3-phosphate is converted to 1,3-bisphosphoglycerate. Aldolase cleaves the six-carbon sugar into two three-carbon sugars. Phosphoenolpyruvate is converted to pyruvate. 3-Phosphoglycerate is formed. Fructose-6-phosphate is phosphorylated by phosphofructokinase. First steparrow_forwardHow many molecules of NADH and FADH2 are obtained from the β-oxidation of one molecule of a 16-carbon saturated fatty acyl-CoA?arrow_forwardHow many molecules of acetyl-CoA are obtained from the beta-oxidation of one molecule of a 16-carbon saturated fatty acyl-CoA?arrow_forward
- Pyruvate CoA NAD+ → acetyl CoA + CO2 + NADH + H+arrow_forwardThe rate-limiting step is a metabolic pathway is the slowest step which determines the overall rate of the other reactions in the pathway. In glycolysis, the rate limiting step is a phosphorylation reaction where phosphofructokinase (PFK-1) catalyzes the reaction fructose-6-bisphosphate -> fructose-1,6-bisphosphate, the same step in gluconeogenesis. Select one: The statement is FALSE. The statement is TRUE.arrow_forwardMark any/all processes that are reductions. O FADH2 → FAD O hydrogenation of fats FAD FADH2 NAD* NADH NADH NAD*arrow_forward
- Under conditions of starvation, acetyl-CoA, instead of being degraded in the citric acid cycle, is converted to acetone and 3-hydroxybutyrate, compounds called ketone bodies that the brain can use as a temporary fuel. Show how the ketone bodies are formed.arrow_forwardThe enzyme that catalyzes reaction below can be classified as: NAD* NADH + H* Но- H-Ć- Н—с—н H- malate dehydrogenase Oxaloacetate Malatearrow_forwardConsider the docosanoic acid, C21H43CO2H Label the alpha and beta Carbons. Draw each acyl CoA derived from this fatty acid. How many acetyl Co A molecules are formed by complete beta-oxidation? How many cycles of beta-oxidation are needed for complete oxidation? How many molecules of ATP are formed from the complete catabolism of this fatty acid? Show the complete computation. How many moles of ATP per gram of fatty acid is formed from the complete catabolism of the given fatty acid? What is the molar mass of the given fatty acid?arrow_forward
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