Organic Chemistry (8th Edition)
Organic Chemistry (8th Edition)
8th Edition
ISBN: 9780134042282
Author: Paula Yurkanis Bruice
Publisher: PEARSON
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Chapter 24.5, Problem 5P

Why does the OH group add to the β-carbon rather than to the α-carbon in the second reaction in the β-oxidation of fats? (Hint: See Section 16.15.)

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As seen at the end of Section 16.10, a deficiency in vitamin D can cause a bonesoftening disease called rickets, so many foods, including milk and cereals, are fortified with vitamin D. Our bodies synthesize vitamin D when our skin is exposed to sunlight, but the lack of outdoor exercise by today's children, in conjunction with regular use of sunscreen, may be contributing to a rise in the disease. The amount of vitamin D3 in fortified foods and fish can be measured by UV-Vis spectrometry. (J. Agric. Food Chem. 2009, 57, 2135-2146.) Using Woodward-Fieser rules, estimate the expected Amax for vitamin D3: HO.. Vitamin D3 CH3 nm H CH3 Select the number of each feature present in vitamin D3. Base value (conjugated diene) = 217 nm Number of additional double bonds: Number of auxochromic alkyl groups: Number of exocyclic double bonds: Number of homoannular dienes: Estimated Amax= ✓ (+30 each) ✓ (+5 each) ✓ (+5 each) (+39 each)
Using the following as possible steps in a pathway: 2 ClF (g) + O2 (g) → Cl2O (g) + OF2 (g) ΔH° = 167.5 kJ 2 OF2 (g) → 2 F2 (g) + O2 (g) ΔH° = 43.5 kJ 2 ClF3 (l) + 2 O2 (g) → Cl2O (g) + 3 OF2 (g) ΔH° = 394.1 kJ Determine a ΔH° for the reaction of gaseous chlorine monofluoride with gaseous fluorine to produce liquid chlorine trifluoride. Balance with the lowest whole number coefficients. Place your answer in the box provided.
19-16 Classify each of the fatty acids in Problem 19-14 using the omega classification system or indicate that the omega classification system does not apply to the fatty acid. 1 formula for the fatty acid

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Organic Chemistry (8th Edition)

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